公开(公告)号：DE3568051D1

公开(公告)日：1989-03-09

申请号：DE3568051

申请日：1985-10-23

Applicant: BASF AG

Inventor： GOUSETIS CHARALAMPOS DR ,  OPPENLAENDER KNUT DR ,  LIEBOLD GERT DR ,  PFITZNER KLAUS DR

IPC: C08G77/02 ,  C08G77/30 ,  C09K5/20

Abstract: Organosilane/silicate copolymers obtainable by reacting an organic phosphosilicon compound of the formula I (I) where n, X, Y, R1 and R2 have the meanings stated in the description, with an alkali metal silicate, radiator antifreezes containing these compounds, their use as corrosion inhibitors in radiator antifreezes based on glycol, a method of inhibiting corrosion of aluminum by aqueous cooling media, containing radiator antifreeze based on glycol, during the cooling of internal combustion engines, and the use of organic phosphosilicon compounds for stabilizing silicates.

公开(公告)号：DE3708298A1

公开(公告)日：1988-09-22

申请号：DE3708298

申请日：1987-03-14

Applicant: BASF AG

Inventor： GOUSETIS CHARALAMPOS DR ,  OPPENLAENDER KNUT DR ,  LIEBOLD GERT DR ,  FREY GUENTER DR

IPC: C09K5/00 ,  C09K5/20

Abstract: 1. A glycol-based coolant mixture which is free of nitrites and phosphates, containing a) 1 - 5% by weight of an alkali metal salt of acid II see diagramm : EP0283806,P7,F1 where R is a -CH2 -, see diagramm : EP0283806,P7,F2 see diagramm : EP0283806,P7,F3 or CH2 CH2 CH2 group, b) 0.1 - 1% by weight of a silicate of the general formula III (MO)q SiO4-q/2 where M is an alkali metal and q is from 0.4 to 4, c) 0.01 - 0.2% by weight of a silicate stabilizer, d) 0 - 0.5% by weight of an alkali nitrate, e) 0.05 - 0.2% by weight of benzotriazole or tolutriazole, f) 0.5 - 2% by weight of borax, and g) 0.05 - 1% by weight of NaOH, all the percentages being based on the glycol present in the coolant mixture.

公开(公告)号：ES2046408T5

公开(公告)日：1997-05-16

申请号：ES89115869

申请日：1989-08-29

Applicant: BASF AG

Inventor： BAUR RICHARD DR ,  GOUSETIS CHARALAMPOS DR ,  TRIESELT WOLFGANG DR ,  BOCHNITSCHEK WERNER DR ,  OFTRING ALFRED DR

IPC: C07C227/14 ,  C07C227/06 ,  C07C227/18 ,  C07C229/16

Abstract: Preparation of beta -alaninediacetic acid (Ia) or its alkali metal or ammonium salts (Ib) by reacting iminodiacetic acid and acrylic acid a) with one another in non-basic aqueous medium for the preparation of Ia and b) with one another in alkaline or nigrogen-basic aqueous medium for the preparation of Ib or converting the Ia formed in non-basic medium into Ib using an alkali metal base, ammonia or an amine.

公开(公告)号：ES2063408T3

公开(公告)日：1995-01-01

申请号：ES91110522

申请日：1989-12-27

Applicant: BASF AG

Inventor： OPPENLAENDER KNUT DR ,  SCHWEN ROLAND DR ,  BAUR RICHARD DR ,  GOUSETIS CHARALAMPOS DR ,  MOHR JURGEN DR ,  MACH HELMUT DR

IPC: C10M145/32 ,  C08G65/26 ,  C08G65/28 ,  C10M105/62 ,  C10M107/34 ,  C10M133/08 ,  C10M145/36 ,  C10M149/12 ,  C10M159/12 ,  C10M169/04 ,  C10N30/02 ,  C10N30/06 ,  C10N30/08 ,  C10N40/04 ,  C10N40/25

Abstract: 1,2-Butylene oxide adducts (I) of alcohols (II) is produced by reacting (II) with 1,2-butylene oxide (III) in the presence of an alkali, using a (III):(II) molar ratio of more than 20:1. The reaction is effected at 120-160 (esp. 140-150) deg.C and 5-30 bar in the presence of 0.01-1 (esp. 0.05-0.5)wt.% KOH. The (III):(II) molar ratio is 20-500:1.

公开(公告)号：ES2053942T3

公开(公告)日：1994-08-01

申请号：ES89123922

申请日：1989-12-27

Applicant: BASF AG

Inventor： OPPENLAENDER KNUT DR ,  SCHWEN ROLAND DR ,  BAUR RICHARD DR ,  GOUSETIS CHARALAMPOS DR ,  MOHR JUERGEN DR ,  MACH HELMUT DR

IPC: C10M145/32 ,  C08G65/26 ,  C08G65/28 ,  C10M105/62 ,  C10M107/34 ,  C10M133/08 ,  C10M145/36 ,  C10M149/12 ,  C10M159/12 ,  C10M169/04 ,  C10N30/02 ,  C10N30/06 ,  C10N30/08 ,  C10N40/04 ,  C10N40/25

Abstract: 1,2-Butylene oxide adducts (I) of alcohols (II) is produced by reacting (II) with 1,2-butylene oxide (III) in the presence of an alkali, using a (III):(II) molar ratio of more than 20:1. The reaction is effected at 120-160 (esp. 140-150) deg.C and 5-30 bar in the presence of 0.01-1 (esp. 0.05-0.5)wt.% KOH. The (III):(II) molar ratio is 20-500:1.

公开(公告)号：DE58906358D1

公开(公告)日：1994-01-20

申请号：DE58906358

申请日：1989-08-29

Applicant: BASF AG

Inventor： BAUR RICHARD DR ,  GOUSETIS CHARALAMPOS DR ,  TRIESELT WOLFGANG DR ,  BOCHNITSCHEK WERNER DR ,  OFTRING ALFRED DR

IPC: C07C227/06 ,  C07C227/14 ,  C07C227/18 ,  C07C229/16

Abstract: Preparation of beta -alaninediacetic acid (Ia) or its alkali metal or ammonium salts (Ib) by reacting iminodiacetic acid and acrylic acid a) with one another in non-basic aqueous medium for the preparation of Ia and b) with one another in alkaline or nigrogen-basic aqueous medium for the preparation of Ib or converting the Ia formed in non-basic medium into Ib using an alkali metal base, ammonia or an amine.

公开(公告)号：DE3844222A1

公开(公告)日：1990-07-05

申请号：DE3844222

申请日：1988-12-29

Applicant: BASF AG

Inventor： OPPENLAENDER KNUT DR ,  SCHWEN ROLAND DR ,  BAUR RICHARD DR ,  GOUSETIS CHARALAMPOS DR ,  MOHR JUERGEN DR ,  MACH HELMUT DR

IPC: C10M145/32 ,  C08G65/26 ,  C08G65/28 ,  C10M105/62 ,  C10M107/34 ,  C10M133/08 ,  C10M145/36 ,  C10M149/12 ,  C10M159/12 ,  C10M169/04 ,  C10N30/02 ,  C10N30/06 ,  C10N30/08 ,  C10N40/04 ,  C10N40/25

Abstract: 1,2-Butylene oxide adducts (I) of alcohols (II) is produced by reacting (II) with 1,2-butylene oxide (III) in the presence of an alkali, using a (III):(II) molar ratio of more than 20:1. The reaction is effected at 120-160 (esp. 140-150) deg.C and 5-30 bar in the presence of 0.01-1 (esp. 0.05-0.5)wt.% KOH. The (III):(II) molar ratio is 20-500:1.

公开(公告)号：DE3829847A1

公开(公告)日：1990-03-15

申请号：DE3829847

申请日：1988-09-02

Applicant: BASF AG

Inventor： BAUR RICHARD DR ,  GOUSETIS CHARALAMPOS DR ,  TRIESELT WOLFGANG DR ,  BOCHNITSCHEK WERNER DR ,  OFTRING ALFRED DR

IPC: C11D3/30 ,  C11D3/00 ,  C11D3/33 ,  C11D7/32

Abstract: Cleaning and washing compositions for aqueous uses which contain as hardness remover 2 to 25% by weight, based on the total weight of the compositions, of beta -alanine-N,N-diacetic acid or the alkali metal or ammonium salts thereof.

公开(公告)号：DE3732908A1

公开(公告)日：1989-04-13

申请号：DE3732908

申请日：1987-09-30

Applicant: BASF AG

Inventor： FRANZ DIETER DR ,  GOUSETIS CHARALAMPOS DR ,  JAKOB CLAUS PETER ,  MACH HELMUT DR ,  RATH HANS PETER DR ,  STARKE KLAUS

IPC: C10L1/234 ,  C10L1/22 ,  C10L1/222

公开(公告)号：DE3708293A1

公开(公告)日：1988-09-22

申请号：DE3708293

申请日：1987-03-14

Applicant: BASF AG

Inventor： GOUSETIS CHARALAMPOS DR ,  OPPENLAENDER KNUT DR ,  LIEBOLD GERT DR ,  FREY GUENTER DR

IPC: C07F7/18 ,  C07F7/20

Abstract: Alkoxysilanes containing low levels of chlorine compounds are prepared by stepwise etherification of chlorosilanes with alcohols in liquid phase and removal of the resulting hydrogen chloride by reacting the alkoxysilane obtained, which still contains a small amount of chlorine compound, with a metal alkoxide in an amount which corresponds to a small stoichiometric excess based on the proportion of chlorine compound, and freeing the reaction product from the resulting salt.