公开(公告)号：DE10323818A1

公开(公告)日：2004-12-09

申请号：DE10323818

申请日：2003-05-23

Applicant: BASF AG

Inventor： STORCK SEBASTIAN ,  ZUEHLKE JUERGEN ,  NETO SAMUEL ,  ROSOWSKI FRANK

IPC: B01J23/00 ,  B01J23/22 ,  B01J27/198 ,  B01J35/00 ,  B01J35/10 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89 ,  B01J21/06

Abstract: Catalyst systems for preparing phthalic anhydride by means of gas-phase oxidation of o-xylene and/or naphthalene, and a process for preparing phthalic anhydride using the catalyst systems.

公开(公告)号：BRPI0612702A2

公开(公告)日：2016-11-29

申请号：BRPI0612702

申请日：2006-06-30

Applicant: BASF AG

Inventor： ROSOWSKI FRANK ,  ALLMANN HANS-MARTIN ,  ZÜHLKE JÜRGEN ,  STEEG RAINER ,  NETO SAMUEL ,  STORCK SEBASTIAN ,  LAUTENSACK THOMAS

IPC: B01J23/00 ,  C07C51/21 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89

公开(公告)号：BRPI0410759B1

公开(公告)日：2014-03-04

申请号：BRPI0410759

申请日：2004-05-21

Applicant: BASF AG

Inventor： ZUEHLKE JUERGEN ,  NETO SAMUEL ,  ROSOWSKI FRANK ,  STORCH SEBASTIAN

IPC: C07C51/265 ,  C07C51/31 ,  C07C63/16

Abstract: A description is given of a process for preparing aldehydes, carboxylic acids and/or carboxylic anhydrides, in particular phthalic anhydride, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed at elevated temperature over a bed of a first catalyst and a bed which is made up of a second catalyst having a higher activity than the first catalyst and is located downstream of the first catalyst in the flow direction of the gaseous stream, wherein the catalytically active composition of the first catalyst comprises at least vanadium oxide, titanium dioxide and antimony oxide and the ratio of vanadium, calculated as V 2 O 5 , to antimony, calculated as Sb 2 O 3 , in the first catalyst is from 3.5:1 to 5:1. The source of antimony oxide used for the first catalyst is preferably particulate antimony trioxide having a mean particle size of from 0.5 to 5 mum. The process allows the desired oxidation products to be obtained in high yield over longer periods of time.

公开(公告)号：ZA200510405B

公开(公告)日：2008-06-25

申请号：ZA200510405

申请日：2005-12-22

Applicant: BASF AG

Inventor： ROSOWSKI FRANK ,  STORCK SEBASTIAN ,  ZUHLKE JURGEN ,  NETO SAMUEL

IPC: C07C20090101 ,  C07C51/265 ,  C07C51/31

Abstract: A description is given of a process for preparing aldehydes, carboxylic acids and/or carboxylic anhydrides, in particular phthalic anhydride, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed at elevated temperature over a bed of a first catalyst and a bed which is made up of a second catalyst having a higher activity than the first catalyst and is located downstream of the first catalyst in the flow direction of the gaseous stream, wherein the catalytically active composition of the first catalyst comprises at least vanadium oxide, titanium dioxide and antimony oxide and the ratio of vanadium, calculated as V 2 O 5 , to antimony, calculated as Sb 2 O 3 , in the first catalyst is from 3.5:1 to 5:1. The source of antimony oxide used for the first catalyst is preferably particulate antimony trioxide having a mean particle size of from 0.5 to 5 mum. The process allows the desired oxidation products to be obtained in high yield over longer periods of time.

公开(公告)号：PL1628763T3

公开(公告)日：2008-02-29

申请号：PL04733250

申请日：2004-05-15

Applicant: BASF AG

Inventor： STORCK SEBASTIAN ,  ZÜHLKE JÜRGEN ,  NETO SAMUEL ,  ROSOWSKI FRANK

IPC: B01J35/02 ,  B01J23/00 ,  B01J23/22 ,  B01J27/198 ,  B01J35/00 ,  B01J35/10 ,  C07C51/265 ,  C07C51/31

公开(公告)号：ES2290712T3

公开(公告)日：2008-02-16

申请号：ES04733250

申请日：2004-05-15

Applicant: BASF AG

Inventor： STORCK SEBASTIAN ,  ZUHLKE JURGEN ,  NETO SAMUEL ,  ROSOWSKI FRANK

IPC: B01J35/02 ,  B01J23/00 ,  B01J23/22 ,  B01J27/198 ,  B01J35/00 ,  B01J35/10 ,  C07C51/265 ,  C07C51/31

Abstract: Sistema catalizador para la producción de anhídrido del ácido ftálico, que presenta al menos tres capas de catalizador dispuestas una sobre otra en el tubo de reacción, cuya actividad catalizadora aumenta de capa en capa y cuya masa activa contiene del 70 al 99% en peso de dióxido de titanio en la modificación anatasa, (i) presentando el catalizador menos activo sobre el material de soporte del 7 al 10% en peso, con respecto al catalizador total, de masa activa, que contiene del 6 al 11% en peso de V2O5, del 0 al 3% en peso de Sb2O3, del 0, 1 al 1% en peso de álcali (calculado como metal alcalino) y como resto TiO2 en forma anatasa con una superficie BET de desde 5 hasta 30 m2/g, (ii) presentando el siguiente catalizador más activo sobre el material de soporte del 7 al 12% en peso, con respecto al catalizador total, de masa activa, que contiene del 5 al 13% en peso de V2O5, del 0 al 3% en peso de Sb2O3, del 0 al 0, 4% en peso de P, del 0 al 0, 4% en peso de álcali (calculado como metal alcalino) y como resto TiO2 en forma anatasa con una superficie BET de desde 10 hasta 40 m2/g, (iii) presentando el catalizador más activo sobre el material de soporte del 8 al 12% en peso, con respecto al catalizador total, de masa activa, que contiene del 5 al 30% en peso de V2O5, del 0 al 3% en peso de Sb2O3, del 0, 05 al 0, 4% en peso de P, del 0 al 0, 3% en peso de álcali (calculado como metal alcalino) y como resto TiO2 en forma anatasa con una superficie BET de desde 15 hasta 50 m2/g, con la condición de que la superficie BET del dióxido de titanio en la capa (i) superior sea menor que la superficie BET del dióxido de titanio en la o las capa(s) (ii) intermedia(s) y la superficie BET del dióxido de titanio en la capa (iii) inferior sea mayor que la superficie BET del dióxido de titanio en la o las capa(s) intermedia(s).

公开(公告)号：DE102005061383A1

公开(公告)日：2007-06-28

申请号：DE102005061383

申请日：2005-12-21

Applicant: BASF AG

Inventor： NETO SAMUEL ,  HIBST HARTMUT ,  ROSOWSKI FRANK ,  STORCK SEBASTIAN ,  ZUEHLKE JUERGEN

IPC: C01G1/02 ,  B01J23/68 ,  C01G5/00 ,  C01G31/02

公开(公告)号：BRPI0413184A

公开(公告)日：2006-10-03

申请号：BRPI0413184

申请日：2004-07-30

Applicant: BASF AG

Inventor： NETO SAMUEL ,  ZUEHLKE JUERGEN ,  STORCK SEBASTIAN ,  ROSOWSKI FRANK

IPC: B01J21/06 ,  B01J23/22 ,  B01J27/198 ,  B01J37/02 ,  C07C51/265 ,  B01J31/06 ,  C07C51/215

Abstract: A catalyst for gas-phase oxidations which comprises an inert support and a catalytically active composition comprising transition metal oxides applied thereto, or a precatalyst, is described. The (pre)catalyst is obtained by treating the inert support with an aqueous suspension or solution of the transition metal oxides or their precursor compounds, where the suspension contains a binder dispersion and the binder is a copolymer of an alpha-olefin and a vinyl-C 2 -C 4 -carboxylate whose vinyl C 2 -C 4 -carboxylate content is at least 62 mol %.

公开(公告)号：BRPI0412840A

公开(公告)日：2006-09-26

申请号：BRPI0412840

申请日：2004-07-23

Applicant: BASF AG

Inventor： NETO SAMUEL ,  HIBST HARTMUT ,  ROSOWSKI FRANK ,  STORCK SEBASTIAN

IPC: B01J23/00 ,  B01J23/68 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C01G31/00 ,  C07C51/265 ,  C07C51/31 ,  B01J23/22 ,  B01J23/50

Abstract: A multimetal oxide of the formula I, Aga-cQbMcV2Od*e H2O, I where a is from 0.3 to 1.9, Q is an element selected from among P, As, Sb and/or Bi, is from 0 to 0.3, M is a metal selected from among Nb, Ce, W, Mn, Ta, Pd, Pt, Ru and/or Rh, c is from 0.001 to 0.5, with the proviso that (a-c)>=0.1, d is a number which is determined by the valence and abundance of the elements other than oxygen in the formula I and e is from 0 to 20, and also precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are described.

公开(公告)号：BRPI0410551A

公开(公告)日：2006-06-20

申请号：BRPI0410551

申请日：2004-05-15

Applicant: BASF AG

Inventor： NETO SAMUEL ,  ZUEHLKE JUERGEN ,  STORCK SEBASTIAN ,  ROSOWSKI FRANK

IPC: C07C51/265 ,  C07C51/31 ,  C07D307/89 ,  C07C51/21

Abstract: The invention relates to a process for preparing phthalic anhydride, in which the catalytic gas-phase oxidation of o-xylene and/or naphthalene is carried out over at least three zones of catalysts of increasing activity, with only the last zone of the catalyst system containing phosphorus and the last zone also comprising at least 10% by weight of vanadium (calculated as V 2 O 5 ) based on the active composition of the catalyst and having a ratio of vanadium (calculated as V 2 O 5 ) to phosphorus of greater than 35.