公开(公告)号：WO2005073157A3

公开(公告)日：2006-04-27

申请号：PCT/EP2005000867

申请日：2005-01-28

Applicant: BASF AG ,  WALSDORFF CHRISTIAN ,  JOHANN THORSTEN ,  ROESSLER BEATRICE ,  HIBST HARTMUT ,  TELES JOAQUIM H ,  STORCK SEBASTIAN ,  KLEIN JENS

Inventor： WALSDORFF CHRISTIAN ,  JOHANN THORSTEN ,  ROESSLER BEATRICE ,  HIBST HARTMUT ,  TELES JOAQUIM H ,  STORCK SEBASTIAN ,  KLEIN JENS

IPC: B01J19/00 ,  B01J23/644 ,  B01J23/652 ,  B01J23/68 ,  B01J23/89 ,  B01J37/02 ,  B01J37/03 ,  C07C45/32 ,  C07C45/65 ,  B01J23/44

CPC classification number: C07C45/65 ,  B01J23/6445 ,  B01J23/6447 ,  B01J23/6522 ,  B01J23/681 ,  B01J23/8973 ,  B01J35/008 ,  B01J37/0201 ,  B01J37/0221 ,  B01J37/03 ,  C07C47/21 ,  C07C49/603

Abstract: The invention relates to a catalytically active composition containing Pd and Bi as active constituents, and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba; or Pd, Rh and Bi, and optionally an element selected from the group (a') consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The invention also relates to a method for dehydrating hydrocarbons, preferably oxofunctionalised hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, by means of the catalytically active composition.

Abstract translation: 本发明涉及一种作为活性组分的Pd和Bi的至少一种元素，从（a）由铑，金，锑，钒，铬，钨，锰，铁，钴，镍组成的组中选择的催化活性组合物 钠，具有Cs和Ba或钯，铑和铋和从由Au，锑，钒，铬，钨，锰，铁，钴，镍，铂，Cu构成的组（A“）中选择任选的一个元件， 银，钠，铯，镁，钙和钡，其特征在于。 此外，本发明涉及用于烃的Deyhdrierung一个方法中，优选烃oxofunktionalisierten如环戊酮，环己酮和异戊醛，用催化活性的组合物。

公开(公告)号：WO03078310A8

公开(公告)日：2004-11-11

申请号：PCT/EP0302502

申请日：2003-03-12

Applicant: BASF AG ,  WEIGUNY JENS ,  STORCK SEBASTIAN ,  DUDA MARK ,  DOBNER CORNELIA ,  FELDER RAIMUND

Inventor： WEIGUNY JENS ,  STORCK SEBASTIAN ,  DUDA MARK ,  DOBNER CORNELIA ,  FELDER RAIMUND

IPC: C07D307/60 ,  B01J27/198 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08 ,  B01J37/14 ,  B01J37/18 ,  C07C51/215 ,  C07C51/25 ,  C07C57/145

CPC classification number: B01J8/10 ,  B01J8/067 ,  B01J19/22 ,  B01J27/198 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1038 ,  B01J37/0009 ,  B01J37/08 ,  B01J37/14 ,  B01J37/18 ,  B01J2208/00849 ,  B01J2208/00876 ,  B01J2219/182 ,  C07C51/215 ,  C07C51/252 ,  C07C57/145

Abstract: Disclosed is a method for producing a catalyst containing vanadium, phosphorus, and oxygen, which is used for oxidizing the gas phase of a hydrocarbon having at least four carbon atoms to maleic anhydride. According to the inventive method, a corresponding catalyst precursor which contains vanadium, phosphorus, and oxygen and is provided with particles having an average diameter of at least 2 mm is converted into a catalytically active form by means of calcination, and a flow of the catalyst precursor is transported on a conveyor belt across at least one calcination area over a distance ln at an essentially steady speed in order to be calcinated. The variation over time of the gas temperature in relation to the set point value amounts to

Abstract translation: 一种用于生产一种适用于具有至少四个碳原子的烃的非均相催化气相氧化马来酸酐，含有钒，磷和氧的催化剂，其中含有相应的钒，磷，和具有氧的催化剂前体的方法，其中具有至少2mm的平均直径的颗粒 ，换算通过煅烧成催化活性形式，其中通过至少一个煅烧区，长度LN N，进行在传送带上以基本上恒定的速度进行煅烧的催化剂前体的电流，其中在该范围内的任何点与设定值的气体温度的时间变化 催化剂前体的煅烧区的LN / 2在每种情况下的长度的一半后的流<= 5℃，并在气体温度的任何点之间在催化剂前体的流的区域中的局部差异 s为煅烧LN / 2的每个<= 5°C后一半的长度。

公开(公告)号：WO2005011862A8

公开(公告)日：2006-11-16

申请号：PCT/EP2004008596

申请日：2004-07-30

Applicant: BASF AG ,  NETO SAMUEL ,  ZUEHLKE JUERGEN ,  STORCK SEBASTIAN ,  ROSOWSKI FRANK

Inventor： NETO SAMUEL ,  ZUEHLKE JUERGEN ,  STORCK SEBASTIAN ,  ROSOWSKI FRANK

IPC: B01J31/06 ,  B01J21/06 ,  B01J23/22 ,  B01J27/198 ,  B01J37/02 ,  C07C51/215 ,  C07C51/265

CPC classification number: B01J23/22 ,  B01J21/063 ,  B01J23/002 ,  B01J27/198 ,  B01J37/0219 ,  B01J37/0221 ,  B01J37/0232 ,  B01J2523/00 ,  C07C51/265 ,  C07C63/16 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55

Abstract: Disclosed is a catalyst for gas phase oxidations, comprising an inert carrier and a catalytically active material that is applied thereupon and contains transition metal oxides, or a precatalyst. Said (pre)catalyst is obtained by processing the inert carrier with an aqueous suspension or solution of the transition metal oxides or the precursor compounds thereof. The suspension contains a binder dispersion while the binder is a copolymer of an a-olefin and a vinyl-C 2 -C 4 -carboxylate, the vinyl-C 2 -C 4 -carboxylate content of which amounts to at least 62 mole percent.

Abstract translation: 公开的是用于在惰性载体的气相氧化催化剂和包含施加于其上的含有催化活性物质5，或预催化剂的过渡金属氧化物。 （预）催化剂通过治疗惰性载体获得的，用含水悬浮液或上或它们的前体化合物的溶液，其中所述悬浮液包含粘合剂分散液和粘合剂的过渡金属氧化物是α-烯烃和乙烯基-C _{2 <的共聚物 / SUB> -C 4 - 羧酸叔丁酯，其乙烯基ç 2 -C 4 - 羧酸叔丁酯为至少62摩尔％。}

公开(公告)号：WO2005030380A2

公开(公告)日：2005-04-07

申请号：PCT/EP2004010748

申请日：2004-09-24

Applicant: BASF AG ,  NETO SAMUEL ,  RUMMEL WOLFGANG ,  STORCK SEBASTIAN ,  ZUEHLKE JUERGEN ,  ROSOWSKI FRANK

Inventor： NETO SAMUEL ,  RUMMEL WOLFGANG ,  STORCK SEBASTIAN ,  ZUEHLKE JUERGEN ,  ROSOWSKI FRANK

IPC: B01J2/16 ,  B01J8/18 ,  B01J23/00 ,  B01J23/22 ,  B01J27/199 ,  B01J35/02 ,  B01J37/02 ,  F26B3/08 ,  F26B3/092 ,  B01J

CPC classification number: B01J23/002 ,  B01J2/16 ,  B01J23/22 ,  B01J27/199 ,  B01J35/023 ,  B01J37/0219 ,  B01J37/0221 ,  B01J37/0232 ,  B01J2523/00 ,  F26B3/0926 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55

Abstract: The invention relates to a device for the mixing, drying and coating of powdered, granular or moulded bulk material in a fluid bed, in particular, a method for the production of supported catalysts for gas phase oxidations, with a container (10), for holding the bulk goods, whereby a dished recess (17) is provided in a lower region (13) of the container (10), a central tube (27) for the introduction of a gas, whereby the central tube enters in an upper region (12) of the container (10), extending essentially axially downwards into the container (10) and opens out in the recess (17), an essentially annular deflector screen (29), fixed to the central tube (27) in the upper region (12) of the container (10), a guide ring (31), arranged in the lower region (13) of the container (10), which surrounds the central tube (27) over a part of the length thereof essentially concentrically with a separation (L) such that a first passage (34) is formed between the wall of the container (10) at the upper edge of the recess and the lower end (33) of the guide ring (31) and a second outlet (36) is formed between the deflector screen (29) and the upper edge (35) of the guide ring (31) and means for introduction of a fluid into the container (10), such as, for example, nozzles (21). Said device is characterised in that the external wall of the central tube (27) is at least partly provided with a non-stick coating (38). In a preferred embodiment the separation (L) between the wall of the central tube (27) and the wall of the guide ring (27) is greater than the open height (H3) of the first passage (34). The invention further relates to a method for the production of supported catalysts using such a device.

Abstract translation: 本发明涉及一种用于一过程混合，干燥和涂层的粉状，粒状或成形松散物料在流化床中，特别是用于气相氧化的负载型催化剂的制备方法，包括容器（10），用于接收散装材料，其中，（在其下部13 ）的容器（10）的具有用于供给气体，其中，所述中心管（在该容器的上部12）（10）进入所述容器中的碗状凹部（17）在前置式所看到的，中心管（27），位于所述 一个容器（10）基本上延伸轴向向下并进入凹槽（17）打开时，基本上环形的偏转防护罩（29）在容器（10）的上部区域（12）至所述中心管（27）是固定的， 布置成一个在所述容器的下部部分（13）的中心管（27）（10）导向环（31）在其长度的一部分基本上以一定距离（L），以便COLL同心 IBT，在凹部的上边缘（22）的容器（10）的壁和所述导向环（31），第一通路（34）的下端（33）（29）35之间以及Abweisschirrn之间和顶边（ ）所述导向环（31）的第二通道（36）的形成，以及用于将流体引入所述容器（10），例如喷嘴（21）。 本发明的装置的特征在于，所述中心管（27）的外壁至少部分地设置有减少附着的涂层（38）。 在一个优选的实施例中，中心管（27）和导向环（27）的所述壁的所述壁之间的距离（L）大于所述第一通道（34）的净高（H3）更大。 本发明还涉及一种使用这种装置的负载型催化剂的制备方法。

公开(公告)号：WO03078310A2

公开(公告)日：2003-09-25

申请号：PCT/EP0302502

申请日：2003-03-12

Applicant: BASF AG ,  WEIGUNY JENS ,  STORCK SEBASTIAN ,  DUDA MARK ,  DOBNER CORNELIA ,  FELDER RAIMUND

Inventor： WEIGUNY JENS ,  STORCK SEBASTIAN ,  DUDA MARK ,  DOBNER CORNELIA ,  FELDER RAIMUND

IPC: C07D307/60 ,  B01J27/198 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08 ,  B01J37/14 ,  B01J37/18 ,  C07C51/215 ,  C07C51/25 ,  C01B3/38

CPC classification number: B01J8/10 ,  B01J8/067 ,  B01J19/22 ,  B01J27/198 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1038 ,  B01J37/0009 ,  B01J37/08 ,  B01J37/14 ,  B01J37/18 ,  B01J2208/00849 ,  B01J2208/00876 ,  B01J2219/182 ,  C07C51/215 ,  C07C51/252 ,  C07C57/145

Abstract: Disclosed is a method for producing a catalyst containing vanadium, phosphorus, and oxygen, which is used for oxidizing the gas phase of a hydrocarbon having at least four carbon atoms to maleic anhydride. According to the inventive method, a corresponding catalyst precursor which contains vanadium, phosphorus, and oxygen and is provided with particles having an average diameter of at least 2 mm is converted into a catalytically active form by means of calcination, and a flow of the catalyst precursor is transported on a conveyor belt across at least one calcination area over a distance ln at an essentially steady speed in order to be calcinated. The variation over time of the gas temperature in relation to the set point value amounts to

Abstract translation: 一种用于生产一种适用于具有至少四个碳原子的烃的非均相催化气相氧化马来酸酐，含有钒，磷和氧的催化剂，其中含有相应的钒，磷，和具有氧的催化剂前体的方法，其中具有至少2mm的平均直径的颗粒 ，换算通过煅烧成催化活性形式，其中通过至少一个煅烧区，长度LN N，进行在传送带上以基本上恒定的速度进行煅烧的催化剂前体的电流，其中在该范围内的任何点与设定值的气体温度的时间变化 催化剂前体的煅烧区的LN / 2在每种情况下的长度的一半后的流<= 5℃，并在气体温度的任何点之间在催化剂前体的流的区域中的局部差异 s为煅烧LN / 2的每个<= 5°C后一半的长度。

公开(公告)号：WO0234387A8

公开(公告)日：2002-05-23

申请号：PCT/EP0112445

申请日：2001-10-26

Applicant: BASF AG ,  STORCK SEBASTIAN ,  WEIGUNY JENS ,  DUDA MARK ,  COX GERHARD

Inventor： STORCK SEBASTIAN ,  WEIGUNY JENS ,  DUDA MARK ,  COX GERHARD

IPC: C07D307/60 ,  B01J27/198 ,  B01J35/02 ,  B01J37/08 ,  C07B61/00 ,  C07C51/215 ,  C07C51/225 ,  C07C57/145

CPC classification number: B01J37/08 ,  B01J27/198 ,  B01J35/026 ,  C07C51/215 ,  C07C57/145

Abstract: The invention relates to a vanadium-, phosphorus- and oxygen-containing catalyst that is used for producing maleic anhydride by heterogeneous catalytic gas phase oxidation of a hydrocarbon carrying at least four carbon atoms in which the ratio of phosphorus/vanadium is 0.9 to 1.5. Said catalyst comprises particles with an average diameter of at least 2 mm and the composition has a x-ray powder diffraction pattern, obtained by irradiation with CuK alpha radiation ( lambda = 1.54 10 m), that produces in the 2 theta range of 10 DEG to 70 DEG a signal/noise ratio of

Abstract translation: Vnadium，磷和催化剂用于通过具有至少四个碳原子的烃，其中所述磷/钒比为0.9〜1.5的非均相催化气相氧化制备马来酸酐，具有含氧，其具有至少2mm的平均直径的颗粒 且其中使用CuKα辐射的组合物（拉姆达= 1.54。10- <10>米）的粉末XRöntgenbeugungsdiagram结果的θ2在10°〜70°时，信号/背景比 将含有钒和磷相位所有衍射线可以归因，包括

公开(公告)号：MX2007016471A

公开(公告)日：2008-03-04

申请号：MX2007016471

申请日：2006-06-30

Applicant: BASF AG

Inventor： ROSOWSKI FRANK ,  STORCK SEBASTIAN ,  NETO SAMUEL ,  ZUHLKE JURGEN ,  ALLMANN HANS-MARTIN ,  LAUTENSACK THOMAS ,  STEEG RAINER

IPC: B01J23/00 ,  C07C51/21 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89

Abstract: La invencion se relaciona con un metodo para poner en funcionamiento catalizadores de oxidacion, caracterizado en que el catalizador se pone en funcionamiento a una temperatura de 360 degree C a 400 degree C, con un suministro de aire de 1.0 a 3.5 Nm3/h y una carga de hidrocarburos de 20 a 65 g/Nm3 con formacion de una zona activa en el primer 7 a 20 % del lecho del catalizador a una temperatura de 390 degree C a menos de 450 degree C.

公开(公告)号：BRPI0511970A

公开(公告)日：2008-01-22

申请号：BRPI0511970

申请日：2005-06-14

Applicant: BASF AG

Inventor： NETO SAMUEL ,  HIBST HARTMUT ,  ROSOWSKI FRANK ,  STORCK SEBASTIAN ,  ZUEHLKE JUERGEN

IPC: C01G31/00 ,  B01J23/00 ,  B01J23/68 ,  B01J27/198

Abstract: Multimetal oxides corresponding to the general formula (I), processes for their preparation, precatalysts containing such oxides and catalysts made therefrom for gas phase partial oxidation of hydrocarbons: Ag a-c Q b M c V 12 O d .eH 2 O (I) wherein a represents a number having a value of 5 to 9; Q represents an element selected from the group consisting of P, As, Sb, Bi and mixtures thereof; b represents a number having a value of 0.2 to 3; M represents a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni, Ce, Mn, Nb, W, Ta, Mo and mixtures thereof; c represents a number having a value of less than 1; d represents a number having a value of which is determined by the valency and frequency of Ag, Q, M and V in the formula (I); and e represents a number having a value of 0 to 20; wherein the multimetal oxide has a crystal structure wherein its powder X-ray diffractogram includes reflections at at least 5 interplanar spacings selected from the group of 7.13 Å, 5.52 Å, 5.14 Å, 3.57 Å, 3.25 Å, 2.83 Å, 2.79 Å, 2.73 Å, 2.23 Å and 1.71 Å, each interplanar spacing value±0.04 Å.

公开(公告)号：UA80765C2

公开(公告)日：2007-10-25

申请号：UAA200512406

申请日：2004-05-15

Applicant: BASF AG

Inventor： NETO SAMUEL ,  ZUEHLKE JUERGEN ,  STORCK SEBASTIAN ,  ROSOWSKI FRANK

IPC: C07C51/21 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89

Abstract: The invention relates to a method for producing phthalic anhydride during which the catalytic gas phase oxidation of o-xylol and/or naphthalene is carried out over at least three layers of catalysts of increasing activity, whereby only the last layer of the catalyst system contains phosphorous, and the last layer contains at least 10% by weight of vanadium (expressed as V2O5) with regard to the active mass of the catalyst and has a ratio of vanadium (expressed as V2O5) to phosphorous of greater than 35.

公开(公告)号：DE502004004958D1

公开(公告)日：2007-10-25

申请号：DE502004004958

申请日：2004-05-15

Applicant: BASF AG

Inventor： STORCK SEBASTIAN ,  ZUEHLKE JUERGEN ,  NETO SAMUEL ,  ROSOWSKI FRANK

IPC: B01J35/02 ,  B01J23/00 ,  B01J23/22 ,  B01J27/198 ,  B01J35/00 ,  B01J35/10 ,  C07C51/265 ,  C07C51/31

Abstract: Catalyst systems for preparing phthalic anhydride by means of gas-phase oxidation of o-xylene and/or naphthalene, and a process for preparing phthalic anhydride using the catalyst systems.