Fast-penetrating solns. of amino resin, esp. for paper impregnation - contain low-mol. wt. quat. ammonium cpds. with hydroxy-alkyl or amido-alkyl gp.

    公开(公告)号:DE4117841A1

    公开(公告)日:1992-12-03

    申请号:DE4117841

    申请日:1991-05-31

    Applicant: BASF AG

    Abstract: Aq. soln. (I) of amino resin (II) are claimed, contg. 1-35 wt.% low-mol. wt. quat. ammonium cpd. of formula Rn(R')4-nN+ X- (III) (w.r.t. solids content of I); R = 1-8C alkyl substd. with an 0H or amido gp.; R' = 1-8C alkyl or benzyl; X = anion; n = 0, 1, 2, 3 or 4. Pref., n = 1, 2, 3 or 4, and solids content of (I) is 40-70 wt.%. Pref, (III) is N-(2-hydroxyethyl)-trimethyl -ammonium-chloride (IIIA) or -methyl sulphate, in amt. of 5-20 wt.% w.r.t. solids content; (II) are, e.g. UF or MF resins obtd. by known methods. USE/ADVANTAGE - (I) are useful as fast-penetrating impregnating resins for the prodn. of resin-impregnated paper for coating timber materials (claimed). The invention provides resin solns. which penetrate paper rapidly without dilution (contrast prior-art resin solns.), thus enabling increased prodn. rates (for chipboard etc.,); solns. (I) has viscosity 15-150 mPa.s and are stable for 2-20 weeks.

    40.
    发明专利
    未知

    公开(公告)号:DE59209518D1

    公开(公告)日:1998-11-12

    申请号:DE59209518

    申请日:1992-07-03

    Applicant: BASF AG

    Abstract: Crosslinked copolymers containing crosslinkable groups based on acrylic acid or methacrylic acid which are obtainable by copolymerisation of (a) from 50 to 99 parts by weight of acrylic acid and/or methacrylic acid, (b) from 1 to 50 parts by weight of at least one N-methylol(meth)acrylamide, or derivatives thereof, (c) from 50 to 10000 ppm, based on monomers (a) and (b), of an at least bifunctional crosslinking agent and (d) from 0 to 49 parts by weight of other monoethylenically unsaturated monomers, in the presence of polymerisation initiators which form free radicals, a process for the preparation of the crosslinkable copolymers by copolymerising the monomers (a), (b), (c) and, if used, (d) in the aqueous phase of a water-in-oil emulsion, and the use of the copolymers as thickeners for textile printing pastes.

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