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公开(公告)号:ES2183469T3
公开(公告)日:2003-03-16
申请号:ES99122636
申请日:1999-11-13
Applicant: BASF AG
Inventor: OOST CARSTEN , STROEZEL MANFRED , ETZRODT HEINZ , WELLER DIETMAR , RHEUDE UDO , KAIBEL GERD
IPC: B01J31/14 , C07B61/00 , C07C45/67 , C07C45/74 , C07C49/203
Abstract: Preparation of unsaturated ketones by reaction of the corresponding alpha , beta -unsaturated alcohol with an alkyl acetoacetate compound in the presence an organo-aluminum catalyst at constant temperature, with separation and continuous removal of CO2 and alcohol formed. Preparation of unsaturated ketones of formula (I) by reaction of the corresponding alpha , beta -unsaturated alcohol of formula (II) with an alkyl acetoacetate compound of formula (III) in the presence of 0.1-5 mole% (based on (III)) of an organo-aluminum catalyst with separation and continuous distillative removal of CO2 and alcohol of formula R3OH formed during reaction, in a reactor containing a fractionation column, where: (A) (II) is added to the reaction mixture together with the organic catalyst without additional solvent and (III) is then added to this mixture; (B) the reaction temperature is kept constant between 175-220 degrees C; (C) the content of (III) is kept at a constant level between 0.1-10 wt.% during the reaction. R1, R3 = 1-4C alkyl; R2 = 4-30C aliphatic, cycloaliphatic or cycloaliphatic-aliphatic; a, b = optional additional bonds.
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公开(公告)号:DE59902990D1
公开(公告)日:2002-11-14
申请号:DE59902990
申请日:1999-02-10
Applicant: BASF AG
Inventor: SCHWAB PETER , BREITSCHEIDEL BORIS , OOST CARSTEN , SCHULZ RALF , SCHULZ MICHAEL
IPC: B01J23/36 , B01J23/46 , C07B61/00 , C07C2/10 , C07C4/10 , C07C6/04 , C07C11/06 , C07C11/08 , C08F2/00
Abstract: Preparation of propene and optionally 1-butene comprises converting butene isomers to propene isomers using metathesis catalyst and converting formed 2-pentene to propene and 1-butene, isolating and recycling the 2-butene fraction. Preparation of propene and optionally 1-butene comprises: (a) converting 1-butene and 2-butene in the presence of a metathesis catalyst containing group VIb, VIIb or VIII metals; (b) removing propene and 2-pentene formed; (c) converting the 2-pentene using ethene to propene and 1-butene in the presence of the metathesis catalyst in (a); (d) removing propene and 1-butene formed; and (e) discharging the 1-butene and partially isomerizing 1-butene to 2-butene in the presence of a catalyst and recycling the 1-butene and 2-butene with a part of the unreacted 4C-fraction from (a) to (a). An Independent claim is also included for the apparatus for carrying out the preparation of propene and 1-butene comprising a metathesis reactor (R01) connected to a distillation column (K101) for removing 2/3C low boiling, 4C middle boiling and 5C+ high boiling phases; column (K301) for removing ethene and propene; and reactor (R02) for reacting 2-pentene with ethene.
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公开(公告)号:DE10015855A1
公开(公告)日:2001-10-11
申请号:DE10015855
申请日:2000-03-30
Applicant: BASF AG
Inventor: OOST CARSTEN , DOMSCHKE THOMAS
Abstract: Apparatus part has a self-cleaning micro-structured surface with protrusions and recesses. An Independent claim is also included for a process for vaporizing solutions in a vaporizer having a self-cleaning micro-structured heat exchanger surface. Preferred Features: The micro-structured surface is produced by a powder coating.
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公开(公告)号:DE19853908A1
公开(公告)日:2000-06-08
申请号:DE19853908
申请日:1998-12-07
Applicant: BASF AG
Inventor: OOST CARSTEN , STROEZEL MANFRED , ETZRODT HEINZ , WELLER DIETMAR , KAIBEL GERD , JAEDICKE HAGEN
Abstract: Preparation of unsaturated methyl ketones(I), from an unsaturated alcohol(II) and alkyl acetoacetate(III) in the presence of an organo-aluminum catalyst(IV) comprises: (a) supplying (II) and (IV) to a reactor with a distillation column, (b) making temperature to be 170-250 degrees C under elevated pressure, (c) dosing the mixture with (III) and (d) maintaining a constant (III) content of 0.1-10 wt.% during the reaction. Preparation of unsaturated ketones of formula (I) involves reaction of an unsaturated alcohol of formula (II) with an alkyl acetoacetate of formula (III), in presence of 0.1-5 mol. % (based on (II)) of an organo-aluminum compound catalyst (IV), with elimination and distillative separation of the alcohol R3OH formed in the reaction, in a reactor system provided with a distillation column. Reaction is carried out by: (a) supplying (I (which boils at less than 140 degrees C), without a solvent, and (IV) to the reaction vessel, (b) adjusting the temperature to a value as constant as possible in the range 170-250 degrees C under elevated pressure, (c) dosing the mixture with (III) and (d) maintaining a (III) content as constant as possible in the range 0.1-10 wt. % during the reaction. Dotted line = optional bond; R1 = Me or Et; R2, R3 = 1-4C alkyl.
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公开(公告)号:SA1471B1
公开(公告)日:2006-10-29
申请号:SA01220446
申请日:2001-10-13
Applicant: BASF AG
Inventor: BOTTCHER ARND , OOST CARSTEN , HAAKE MATHIAS
IPC: C07B61/00 , C07C5/10 , C07C13/18 , C07C209/72 , C07C211/35
Abstract: الملخص: فيطريقةلهدرجة hydrogenating مركباتأرومانية aromatics أحاديةالحلقة mono cyclic أومتعددةالحلقات polycyclic غيرمستبدلةأومركباتأرومانية aromatics أحاديةالحلقةأومتعددةالحلقاتمستبدلةبمجموعةالكيل alkyl،مجموعةأمينو amino،أومجموعةهيدروكسيل hydroxyl واحدةعلىالأقلأومجموعةمتحدةمناثنينأوأكثرمنهالتكوينالمركباتالأليفانيةالمناظرةبواسطةهيدروجين hydrogen غازيفيوجودحفازواحدعلىالأقلفيعمودالتفاعل (٤) الذييتمفيهإمرارالموادالمتفاعلةفوقالعاملالحفاز (العواملالحفارة) (٥) المثبتةفيعمودالتفاعل (٤)،ويتمسحبالموادالأليفاتيةالحلقية cycloaliphatics منفتحةشريبجانبية (14) أومنقاعالعمود (٦) خلالالخط (٨) أوعندفتحةالتسريبالجانبي (١٤) ومنقاعالعمود (٦) خلالالخط (٨).
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公开(公告)号:ES2243585T3
公开(公告)日:2005-12-01
申请号:ES01989492
申请日:2001-11-21
Applicant: BASF AG
Inventor: OOST CARSTEN , KAIBEL GERD , LAAS HARALD , SCHMITT PETER , VON ERDEN JENS
IPC: B01D1/22 , B01D3/00 , B01D3/14 , B01D3/32 , C07D311/72
Abstract: Procedimiento para la obtención en continuo de derivados del éster de cromanol de la fórmula I en la que R1, R2, R3, R4, R5, R6, R7 y R8 significan, independientemente entre sí, hidrógeno o un resto alquilo con 1 a 10 átomos de carbono en caso dado substituido, ramificado o no ramificado y los enlaces en trazos discontinuos significan, en caso dado, un enlace adicional C-C, según el cual se hacen reaccionar, derivados del cromanol, alimentados de manera continua, de la fórmula II con agentes de acilación, alimentados de manera continua, elegidos entre el grupo de los ácidos carboxílicos de la fórmula IIIa R8-COOH IIIa y de los anhídridos de los ácidos carboxílicos de la fórmula IIIb donde R9 significa hidrógeno o un resto alquilo con 1 a 10 átomos de carbono en caso dado substituido, ramificado o no ramificado, en presencia de un catalizador, en una columna de reacción a modo de reactor, los productos de la reacción se descargan de manera continua del reactor y se separa de la mezcla de la reacción, al menos, un producto de la reacción durante la conversión.
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公开(公告)号:DE50106594D1
公开(公告)日:2005-07-28
申请号:DE50106594
申请日:2001-11-21
Applicant: BASF AG
Inventor: OOST CARSTEN , KAIBEL GERD , LAAS HARALD , SCHMITT PETER , VON ERDEN JENS
IPC: B01D1/22 , B01D3/00 , B01D3/14 , B01D3/32 , C07D311/72
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公开(公告)号:DE50007399D1
公开(公告)日:2004-09-16
申请号:DE50007399
申请日:2000-08-29
Applicant: BASF AG
Inventor: THERRE JOERG , OOST CARSTEN
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公开(公告)号:AT273263T
公开(公告)日:2004-08-15
申请号:AT00964055
申请日:2000-08-29
Applicant: BASF AG
Inventor: THERRE JOERG , OOST CARSTEN
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公开(公告)号:AU2793402A
公开(公告)日:2002-06-03
申请号:AU2793402
申请日:2001-11-21
Applicant: BASF AG
Inventor: OOST CARSTEN , KAIBEL GERD , LAAS HARALD , SCHMITT PETER , ERDEN JENS VON
IPC: B01D1/22 , B01D3/00 , B01D3/14 , B01D3/32 , C07D311/72
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