公开(公告)号：CA996556A

公开(公告)日：1976-09-07

申请号：CA159510

申请日：1972-12-20

Applicant: BASF AG

Inventor： PETERSEN HARRO ,  ERHARDT KLAUS

IPC: D06M15/423 ,  C07D273/04 ,  D06M13/02 ,  D06M13/322 ,  D06M13/35 ,  D06M13/355

公开(公告)号：DE2260719A1

公开(公告)日：1974-06-20

申请号：DE2260719

申请日：1972-12-12

Applicant: BASF AG

Inventor： PETERSEN HARRO ,  SCHARWAECHTER PETER DR

IPC: C07F9/40 ,  C07F9/6533 ,  C07F9/6571 ,  C08K5/53 ,  D06M13/288 ,  D06M13/44

Abstract: Title esters have formula R1-CZ-NR2-CH2-PO(Or3)2 (in which R1 and R2 independently are (cyclo- or ar-)aliphatic or aromatic gps. or H which together with the adjacent carbonamido gp can form a heterocycle; or R1 can be -ZR4, -NR5R6 r -NR6-CH2-PO(OR3)3; the R3 gps. independently or together are aliphatic gps; R4, R5 and R6 independently are aliphatic or aromatic gps, or R5 and R6 can also be H,R4 and R2 and the adjacent carbamate gp. or R6 and R2 and the adjacent ureido gp. can form a heterocycle; Z is O or S). A large no. of these esters can be obtd in better yield and purity than in the reaction of urea derivs. with dialkyl phosphites and the reaction proceeds very smoothly.

公开(公告)号：AU4999572A

公开(公告)日：1974-06-13

申请号：AU4999572

申请日：1972-12-13

Applicant: BASF AG

Inventor： PETERSEN HARRO ,  ERHARDT KLAUS ,  RUEMENS WILHELM ,  BILLE HEINZ ,  REUSS GUENTER

IPC: D06M1/00

公开(公告)号：CA856835A

公开(公告)日：1970-11-24

申请号：CA856835D

Applicant: BASF AG

Inventor： PETERSEN HARRO

公开(公告)号：GB1141254A

公开(公告)日：1969-01-29

申请号：GB4253266

申请日：1966-09-23

Applicant: BASF AG

Inventor： BRANDEIS HANS ,  FEINAUER ANTON ,  PETERSEN HARRO ,  RUEMENS WILHELM

IPC: D06M15/423

Abstract: 1,141,254. Textile-treating composition. BADISCHE ANILIN- & SODA-FABRIK A.G. 23 Sept.; 1966, No. 42532/66. Headings C3P and C3R. [Also in Division Dl] A composition suitable for treating textiles comprises an aqueous solution containing a tetramethylol derivative of a diurethane of a glycol having 2-6 carbon atoms in the glycol radical which is etherified on the methylol groups by alkyl radicals having 1-6 carbon atoms, e.g. N,N,N1,N 1 -tetramethoxy methyl butane diol- (1,4)-diurethane, and an acid curing catalyst, e.g. sodium hydrogen sulphate, ammonium dihydrogen phosphate, ammonium nitrate, ammonium chloride, 2-amino-2-methyl-1-propanol hydrochloride, magnesium chloride and zinc nitrate, and may also contain wetting agents, e.g. alkali metal salts of alkylnaphthalene sulphonic acids or of sulphonated dioctyl succinate, water repellants, e.g. paraffin wax emulsions containing aluminium or zirconium compounds, silicones or perfluorinated aliphatic compounds, softening agents, e.g. ethenoxylation products of high molecular weight fatty acids, fatty alcohols or fatty amides, high molecular weight polyglycol ethers and their esters, high molecular weight fatty acids, fatty alcohol sulphonates, stearyl-N,N-ethylenurea or stearylamidomethyl pyridinium chloride, finishes, e.g. cellulose ethers or esters, alginates, polyamides, polyvinyl ethers, polyvinyl alcohols, polyacrylic or methacrylic acid or esters or amides thereof, polyvinyl propionate, polyvinylpyrrolidone, copolymers of vinyl chloride and acrylic esters, of butadiene and styrene or acrylonitrile, of α-dichloroethylene, #-chloroalkyl acrylic esters or vinyl-#-ethyl ether and acrylamide or the amides of crotonic or maleic acid, or of N-methylolmethacrylamide and other polymerizable compounds, isocyanates, diisocyanates, polyethylene imines, polyamines, ether-oxylated polyamides or silicic esters, acrylamide or methacrylamide polymers containing free and/or etherified N-methylol groups, the condensation product of triethanolamine and stearic acid quaternized with dimethyl sulphate water soluble metal complex dyes, e.g. azo compounds containing combined metal such as chromium, cobalt or copper, or dyes obtained by the reaction of dyes containing reactive hydrogen atoms with formaldehyde, the methylol groups of which may be etherified.

公开(公告)号：GB1032379A

公开(公告)日：1966-06-08

申请号：GB1511465

申请日：1965-04-09

Applicant: BASF AG

Inventor： PETERSEN HARRO ,  GRASSHOFF HANS JOACHIM ,  BRANDRIS HANS

IPC: C07D233/40

Abstract: Dimethylolglyoxalmonoureine is made by reacting urea with an equimolar amount of glyoxal in an aqueous medium at pH of 3.8 to 4.2 at 25-60 DEG C. and reacting the intermediate thus obtained, without isolation, with two molar equivalents of formaldehyde at a pH of 7 to 7.5 at 25-60 DEG C. As glyoxal in aqueous solution shows an acid reaction it is usually necessary to adjust the pH at both stages with an alkaline reagent, preferably sodium carbonate or sodium hydrogen carbonate. The glyoxal is preferably used as a 40% by wt. aqueous solution and the formaldehyde as a 30-40% by wt. aqueous solution.

公开(公告)号：AT81348T

公开(公告)日：1992-10-15

申请号：AT86109185

申请日：1986-07-04

Applicant: BASF AG

Inventor： GOECKEL ULRICH ,  PETERSEN HARRO ,  OSTERLOH ROLF ,  SCHUPP EBERHARD ,  LOCH WERNER ,  SCHWERZEL THOMAS

IPC: C07D239/10 ,  C08G12/02 ,  C08G12/10 ,  C08G12/40 ,  C08G14/06 ,  C08G18/38 ,  C08G18/54 ,  C09D5/44 ,  C09D161/34

公开(公告)号：CA1270977A

公开(公告)日：1990-06-26

申请号：CA474938

申请日：1985-02-22

Applicant: BASF AG

Inventor： FISCHER KURT ,  PETERSEN HARRO ,  LOCH WERNER ,  KASCH HELLMUTH ,  WISTUBA ECKEHARDT

IPC: C08L61/24 ,  C08G12/00 ,  C08G12/02 ,  C08G12/12 ,  C08J3/02 ,  C08J3/03 ,  C08L61/00 ,  C08L61/20 ,  C09D161/24 ,  C09D3/52

Abstract: In a process for the preparation of stable aqueous aldehyde resin dispersions and for the production of surface coating binders, a melt or highly concentrated solution of a polycondensate of urea and a CH-acidic aldehyde, with or without formaldehyde, is dispersed in water in the presence of an organic protective colloid and, if required, an emulsifier. These aqueous resin dispersions can be used, in combination with other film formers, as surface coating binders.

公开(公告)号：CA1234446A

公开(公告)日：1988-03-22

申请号：CA486358

申请日：1985-07-05

Applicant: BASF AG

Inventor： PETERSEN HARRO ,  IMMEL GUENTHER ,  WEISS WOLFRAM ,  SCHMIDT HORST ,  BUSSE GERD

IPC: C08G12/00 ,  C08G12/12 ,  C08G12/40 ,  C08G12/42 ,  C09D161/20 ,  C09D161/32

Abstract: A process for the preparation of curable etherified aminoplast resins based on urea/ aldehyde polycondensates, and the preparation of surface coating resins. Urea is first reacted with an .alpha.,.alpha.-dialkylaldehyde, as much as 50 mol% of which may be replaced by formaldehyde, in a molar ratio urea/aldehyde of about 1-2, at from 50 to 120.degree.C, in the presence of an acid and in the presence or absence of an alcohol or of other organic solvents, and the 2-oxohexahydropyrimidine derivative obtained in this cyclocondensation is then condensed with formaldehyde in the presence of one or more alcohols and an acid. These aminoplast resins are useful as both acidcurable resins and as resins for baking finishes.

公开(公告)号：BR8502880A

公开(公告)日：1986-02-25

申请号：BR8502880

申请日：1985-06-17

Applicant: BASF AG

Inventor： KEMPTER FRITZ ERDMANN ,  PETERSEN HARRO ,  SCHUPP EBERHARD ,  SABELUS GUENTHER ,  SCHMIDT HORST

IPC: C08G59/00 ,  C08G59/10 ,  C08G59/28 ,  C08G59/32 ,  C08L63/00 ,  C09D5/44 ,  C09D163/00 ,  C09D3/49 ,  C09D5/46

Abstract: The heat-curable coating agent according to the invention contains a combination of a binder, which possesses basic nitrogen groups and is rendered water-dilutable by protonation with an acid, and a crosslinking agent and, if required, pigments, fillers, corrosion inhibitors, surface coating assistants and catalysts, and the binder used is a reaction product of a dicarboxylic acid or of a dicarboxylate or of a (meth)acrylate oligomer or polymer with an adduct of a di- or triglycidyl ether and a polyamine, the polyamine containing 2 or more amine nitrogen atoms per molecule and one or more alkylene chains of 3 or more carbon atoms between the amino groups, and has an NH amine number of from 50 to 150 mg of KOH/g and is combined with aminoplasts and/or phenoplasts as crosslinking agents. The novel coating agent is useful as a binder for the cathodic electrocoating of metal articles.