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公开(公告)号:AT192766T
公开(公告)日:2000-05-15
申请号:AT97943883
申请日:1997-09-23
Applicant: BASF AG
Inventor: SIGWART CHRISTOPH , ELLER KARSTEN , BECKER RAINER , PLITZKO KLAUS-DIETER , FISCHER ROLF , STEIN FRANK , MUELLER ULRICH , HESSE MICHAEL
Abstract: PCT No. PCT/EP97/05204 Sec. 371 Date Apr. 1, 1999 Sec. 102(e) Date Apr. 1, 1999 PCT Filed Sep. 23, 1997 PCT Pub. No. WO98/15589 PCT Pub. Date Apr. 16, 1998Polytetrahydrofuran, copolymers of tetrahydrofuran and 2-butyne-1,4-diol, diesters of these polymers with C2-C20-monocarboxylic acids or monoesters of these polymers with C1-C10-monocarboxylic acids are prepared by polymerization of tetrahydrofuran in the presence of one of the telogens water, 1,4-butanediol, 2-butyne-1,4-diol, polytetrahydrofuran having a molecular weight of from 200 to 700 Dalton, a C1-C10-monocarboxylic acid or an anhydride of a C2-C20-monocarboxylic acid or a mixture of these telogens over a heterogeneous supported catalyst which comprises a catalytically active amount of an oxygen-containing molybdenum and/or tungsten compound on an oxidic support material and which has been calcined at from 5OO DEG C. to 1OOO DEG C. after application of the precursor compounds of the oxygen-containing molybdenum and/or tungsten compounds onto the support material precursor, wherein the catalyst is activated by treatment with a reducing agent before it is used as a polymerization catalyst.
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公开(公告)号:ES2141525T3
公开(公告)日:2000-03-16
申请号:ES96927609
申请日:1996-07-26
Applicant: BASF AG
Inventor: SIGWART CHRISTOPH , FISCHER ROLF , ELLER KARSTEN , BECKER RAINER , PLITZKO KLAUS-DIETER , HEILEN GERD
Abstract: PCT No. PCT/EP96/03297 Sec. 371 Date Jan. 22, 1998 Sec. 102(e) Date Jan. 22, 1998 PCT Filed Jul. 26, 1996 PCT Pub. No. WO97/05188 PCT Pub. Date Feb. 13, 1997In a process for the preparation of copolymers of tetrahydrofuran and but-2-yne-1,4-diol by catalytic polymerization of tetrahydrofuran, the polymerization is carried out over a heterogeneous acidic catalyst which has acid centers of acidity pKa
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公开(公告)号:ES2139438T3
公开(公告)日:2000-02-01
申请号:ES97901074
申请日:1997-01-22
Applicant: BASF AG
Inventor: SIGWART CHRISTOPH , HEINEKE DANIEL , FLICK KLEMENS
IPC: B01J23/36 , B01J23/44 , B01J23/46 , B01J37/16 , C07B61/00 , C07D301/00 , C07D303/04
Abstract: PCT No. PCT/EP97/00281 Sec. 371 Date Jul. 15, 1998 Sec. 102(e) Date Jul. 15, 1998 PCT Filed Jan. 22, 1997 PCT Pub. No. WO97/27182 PCT Pub. Date Jul. 31, 1997A process for preparing 1,2-butylene oxide by catalytic hydrogenation of vinyloxirane over a heterogeneous catalyst comprises using a catalyst prepared by applying at least one element of groups 7 to 11 of the Periodic Table in the form of a sol to an inert support.
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公开(公告)号:AT187184T
公开(公告)日:1999-12-15
申请号:AT96927609
申请日:1996-07-26
Applicant: BASF AG
Inventor: SIGWART CHRISTOPH , FISCHER ROLF , ELLER KARSTEN , BECKER RAINER , PLITZKO KLAUS-DIETER , HEILEN GERD
Abstract: PCT No. PCT/EP96/03297 Sec. 371 Date Jan. 22, 1998 Sec. 102(e) Date Jan. 22, 1998 PCT Filed Jul. 26, 1996 PCT Pub. No. WO97/05188 PCT Pub. Date Feb. 13, 1997In a process for the preparation of copolymers of tetrahydrofuran and but-2-yne-1,4-diol by catalytic polymerization of tetrahydrofuran, the polymerization is carried out over a heterogeneous acidic catalyst which has acid centers of acidity pKa
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公开(公告)号:DE59601883D1
公开(公告)日:1999-06-17
申请号:DE59601883
申请日:1996-02-21
Applicant: BASF AG
Inventor: SIGWART CHRISTOPH , FISCHER ROLF , BECKER RAINER , PLITZKO KLAUS-DIETER , HEILEN GERD , PALM CHRISTOF , GROLL PETER
Abstract: PCT No. PCT/EP96/00702 Sec. 371 Date Aug. 26, 1997 Sec. 102(e) Date Aug. 26, 1997 PCT Filed Feb. 21, 1996 PCT Pub. No. WO96/27626 PCT Pub. Date Sep. 12, 1996Tetrahydrofuran/but-2-yne-1,4-diol copolymers containing C-C triple bonds and having an average molecular weight Mn of from 500 to 3500 Dalton and a content of from 0.5 to 3 mol of triple bonds/mol of copolymer and blends of these copolymers with polytetrahydrofuran having an average molecular weight Mn of from 500 to 3500 Dalton, processes for their preparation and their use.
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公开(公告)号:AU8732498A
公开(公告)日:1999-03-01
申请号:AU8732498
申请日:1998-07-23
Applicant: BASF AG
Inventor: SIGWART CHRISTOPH , NARBESHUBER THOMAS , ARNOLD HEIKO , BARL MANFRED , FISCHER ROLF HARTMUTH , GEHRER EUGEN
IPC: C08F4/22 , C08F4/78 , C08F10/10 , C08F110/10
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公开(公告)号:ES2122645T3
公开(公告)日:1998-12-16
申请号:ES95924255
申请日:1995-06-16
Applicant: BASF AG
Inventor: LINGELBACH PETER , ROSER JOACHIM , SIGWART CHRISTOPH , SCHNURR WERNER , WEYER HANS-JURGEN
IPC: B01J23/44 , B01J23/656 , B01J27/053 , C07D301/00 , C07D303/04
Abstract: PCT No. PCT/EP95/02337 Sec. 371 Date Dec. 27, 1996 Sec. 102(e) Date Dec. 27, 1996 PCT Filed Jun. 16, 1995 PCT Pub. No. WO96/00222 PCT Pub. Date Jan. 4, 1996A process for the preparation of 1,2-butylene oxide by the catalytic hydrogenation of vinyl oxirane, in which use is made of a palladium catalyst on a support of barium sulfate, zirconium oxide or titanium dioxide or a rhenium-containing supported palladium catalyst.
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公开(公告)号:CA2278835A1
公开(公告)日:1998-08-13
申请号:CA2278835
申请日:1998-01-17
Applicant: BASF AG
Inventor: NARBESHUBER THOMAS , SIGWART CHRISTOPH , BARL MANFRED , ELLER KARSTEN , FISCHER ROLF , GEHRER EUGEN
Abstract: The invention relates to a method for producing halogen-free, reactive polyisobutene with a terminal double-bond content of over 50 mol % and an average molecular weight of 2,800 - 10,000 Dalton by cationic polymerization of isobutene or isobutene-containing hydrocarbon mixtures in a liquid phase, wherein polmerization is carried out at a temperature of -30 ~C to +40 ~C in the presence of a heterogeneous polymerization catalyst from one or several oxides of the elements of the 5th and 6th subgroup of the periodic table of elements or in the presence of a heterogeneous polymerization catalyst containing one or more oxidic compounds of one or more elements of the 5th and 6th subgroup of the periodic table of elements on an oxygen-containing zircon compound of various non-zeolitic oxidic supporting material, wherein said catalyst contains no technically active quantities of halogen.
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公开(公告)号:ES2109100T3
公开(公告)日:1998-01-01
申请号:ES95911255
申请日:1995-02-23
Applicant: BASF AG
Inventor: SIGWART CHRISTOPH , BROCKER FRANZ JOSEF , FISCHER ROLF , LINGELBACH PETER
IPC: B01J23/44 , B01J23/46 , B01J23/52 , B01J23/62 , B01J23/63 , B01J37/02 , B01J37/34 , C07D301/00 , C07D303/04
Abstract: A process for preparing 1,2-butylene oxide by catalytic hydrogenation of vinyloxirane over a heterogeneous catalyst comprises using a catalyst comprising an element of subgroup I, VII or VIII of the periodic table, or mixtures of a plurality of these elements, in the presence or absence of one or more promoter elements, these elements and promoters having been applied by means of a vacuum vapor deposition technique to a support of metal foil or metal wire fabric.
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公开(公告)号:DE59500687D1
公开(公告)日:1997-10-23
申请号:DE59500687
申请日:1995-02-23
Applicant: BASF AG
Inventor: SIGWART CHRISTOPH , BROECKER FRANZ , FISCHER ROLF , LINGELBACH PETER
IPC: B01J23/44 , B01J23/46 , B01J23/52 , B01J23/62 , B01J23/63 , B01J37/02 , B01J37/34 , C07D301/00 , C07D303/04
Abstract: A process for preparing 1,2-butylene oxide by catalytic hydrogenation of vinyloxirane over a heterogeneous catalyst comprises using a catalyst comprising an element of subgroup I, VII or VIII of the periodic table, or mixtures of a plurality of these elements, in the presence or absence of one or more promoter elements, these elements and promoters having been applied by means of a vacuum vapor deposition technique to a support of metal foil or metal wire fabric.
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