公开(公告)号：CZ146797A3

公开(公告)日：1998-02-18

申请号：CZ146797

申请日：1995-11-14

Applicant: BASF AG

Inventor： ISAK HEINZ DR ,  KEIL MICHAEL DR ,  WOLF BERND DR ,  WINGERT HORST DR ,  WETTLING THOMAS DR

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40

Abstract: PCT No. PCT/EP95/04463 Sec. 371 Date May 6, 1997 Sec. 102(e) Date May 6, 1997 PCT Filed Nov. 14, 1995 PCT Pub. No. WO96/16023 PCT Pub. Date May 30, 1996Halomethylbenzoyl cyanides I PH-CO-CN (I) where Ph is phenyl which is substituted by chloromethyl or bromomethyl and may cary 1-4 other rradicals, are prepared from halomethylbenzoyl chlorides II PH-CO-Cl (II), by reacting II with a cyanide-donating compound in the presence of a Lewis acid, if required in an inert organic solvent or diluent, and then isolating the product. The halomethylbenzoyl cyanides I are important intermediates for synthesizing crop protection agents.

公开(公告)号：DE59108861D1

公开(公告)日：1997-10-30

申请号：DE59108861

申请日：1991-12-10

Applicant: BASF AG

Inventor： WINGERT HORST DR ,  WOLF BERND DR ,  BENOIT REMY DR ,  SAUTER HUBERT DR ,  HEPP MICHAEL DR ,  GRAMMENOS WASSILIOS DR ,  KUEKENHOEHNER THOMAS DR

IPC: C07C69/736 ,  C07C20060101 ,  C07C51/09 ,  C07C51/367 ,  C07C59/68 ,  C07C65/21 ,  C07C65/24 ,  C07C67/22 ,  C07C69/738 ,  C07C69/76 ,  C07C235/34 ,  C07C235/78 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C255/40 ,  C07C317/24

Abstract: Prepn. of 2-phenoxymethyl benzoic acid derivs. of formula (I) comprises (a) converting a phenol of formula (II) to the phenolate in the presence of a basic diluent; (b) mixing the mixt. with a lactone of formula (III); (c) distilling off the diluent; (d) reacting the mixt. at 50-250 degrees C in the melt; and (e) dissolving the liq. melt with water and acidifying. X, Y = halogen, 1-4C alkyl, 1-4C alkoxy or CF3; m = 0-4; n = 0-3.

公开(公告)号：DK0619300T3

公开(公告)日：1997-02-24

申请号：DK94104664

申请日：1994-03-24

Applicant: BASF AG

Inventor： ISAK HEINZ DR ,  WETTLING THOMAS DR ,  KEIL MICHAEL DR ,  WOLF BERND DR ,  DOETZER REINHARD DR

IPC: C07C253/14 ,  C07C255/32 ,  C07C255/40

Abstract: A process for preparing halomethylbenzoyl cyanides I Ph-CO-CNI (Ph=phenyl radical substituted by chloromethyl or bromomethyl which, if desired, can additionally carry 1-4 further radicals) by reacting halomethylbenzoyl chlorides II Ph-CO-ClII with an alkali metal cyanide or transition metal cyanide, if appropriate in an organic diluent, and novel halomethylbenzoyl cyanides I' I' (X=halogen, C1-C4-alkyl, C1-C4-alkoxy, CF3, C1-C5-alkyl-(C1-C5-alkyl)hydroxyimino or C1-C5-alkyl-(C2-C5-alkenyl)hydroxyimino; m=0 to 4 and Y=chloromethyl or bromomethyl) are described. The halomethylbenzoyl cyanides I are important intermediates for the synthesis of plant protection agents.

公开(公告)号：DK0493711T3

公开(公告)日：1996-11-11

申请号：DK91121148

申请日：1991-12-10

Applicant: BASF AG

Inventor： KUEKENHOEHNER THOMAS DR ,  SAUTER HUBERT DR ,  WINGERT HORST DR ,  WOLF BERND DR ,  BENOIT REMY DR ,  HEPP MICHAEL DR ,  GRAMMENOS WASSILIOS DR

IPC: C07C69/736 ,  C07C20060101 ,  C07C51/09 ,  C07C51/367 ,  C07C59/68 ,  C07C65/21 ,  C07C65/24 ,  C07C67/22 ,  C07C69/738 ,  C07C69/76 ,  C07C235/34 ,  C07C235/78 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C255/40 ,  C07C317/24

Abstract: Prepn. of 2-phenoxymethyl benzoic acid derivs. of formula (I) comprises (a) converting a phenol of formula (II) to the phenolate in the presence of a basic diluent; (b) mixing the mixt. with a lactone of formula (III); (c) distilling off the diluent; (d) reacting the mixt. at 50-250 degrees C in the melt; and (e) dissolving the liq. melt with water and acidifying. X, Y = halogen, 1-4C alkyl, 1-4C alkoxy or CF3; m = 0-4; n = 0-3.

公开(公告)号：ES2091278T3

公开(公告)日：1996-11-01

申请号：ES91121148

申请日：1991-12-10

Applicant: BASF AG

Inventor： WINGERT HORST DR ,  WOLF BERND DR ,  BENOIT REMY DR ,  SAUTER HUBERT DR ,  HEPP MICHAEL DR ,  GRAMMENOS WASSILIOS DR

IPC: C07C69/736 ,  C07C20060101 ,  C07C51/09 ,  C07C51/367 ,  C07C59/68 ,  C07C65/21 ,  C07C65/24 ,  C07C67/22 ,  C07C69/738 ,  C07C69/76 ,  C07C235/34 ,  C07C235/78 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C255/40 ,  C07C317/24

Abstract: Prepn. of 2-phenoxymethyl benzoic acid derivs. of formula (I) comprises (a) converting a phenol of formula (II) to the phenolate in the presence of a basic diluent; (b) mixing the mixt. with a lactone of formula (III); (c) distilling off the diluent; (d) reacting the mixt. at 50-250 degrees C in the melt; and (e) dissolving the liq. melt with water and acidifying. X, Y = halogen, 1-4C alkyl, 1-4C alkoxy or CF3; m = 0-4; n = 0-3.

公开(公告)号：GR3020376T3

公开(公告)日：1996-09-30

申请号：GR960401747

申请日：1996-06-27

Applicant: BASF AG

Inventor： ISAK HEINZ DR ,  KEIL MICHAEL DR ,  WOLF BERND DR ,  WINGERT HORST DR

IPC: C07C67/313 ,  C07B61/00 ,  C07C59/68 ,  C07C59/84 ,  C07C67/31 ,  C07C69/708 ,  C07C69/716 ,  C07C249/04 ,  C07C249/08 ,  C07C249/12 ,  C07C251/48

Abstract: The present invention relates to a process for the preparation of E-oxime ethers of phenylglyoxylic esters of the general formula I in which X and Y denote halogen, alkyl, alkoxy, CF3, C(=NOR)R (R = alkyl and alkenyl), by reacting oximes of the formula II with a methylating agent in an organic diluent, and process for the preparation of E-oximes of phenylglyoxylic esters of the formula II by isomerising the E/Z oximes.

公开(公告)号：ES2067083T3

公开(公告)日：1995-03-16

申请号：ES91107586

申请日：1991-05-10

Applicant: BASF AG

Inventor： MUELLER STEFAN DR ,  THEOBALD HANS DR ,  WOLF BERND DR ,  HOFMEISTER PETER DR ,  KARDORFF UWE DR ,  KUENAST CHRISTOPH DR

IPC: A01N43/72 ,  A01N43/80 ,  A01N53/00 ,  A01N53/06 ,  C07D261/08 ,  C07D261/10 ,  C07D261/12 ,  C07D261/18 ,  C07D413/12

Abstract: 3-Isoxazolylbenzyl esters of the general formulae Ia and Ib Ia Ib where R is halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C2--C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C2-C4-haloalkynyl, unsubstituted or substituted phenylethenyl, C3-C8-cycloalkyl, aryl, hetaryl, CO2R3 or CONR4R5, R3, R4 and R5 are each hydrogen or C1-C6-alkyl, n is 0, 1 or 2, and the radicals R may be different when n is 2, R1 is halogen or C1-C4-alkyl, R2 is hydrogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl or cyano and A is the carbonyl radical of an acid component usually found in pyrethroids, are contained in pesticides.

公开(公告)号：DK0414059T3

公开(公告)日：1993-12-13

申请号：DK90115346

申请日：1990-08-10

Applicant: BASF AG

Inventor： THEOBALD HANS DR ,  HOFMEISTER PETER DR ,  KUENAST CHRISTOPH DR ,  WOLF BERND DR

IPC: C07D209/44 ,  A01N37/08 ,  A01N53/00 ,  A01N53/06 ,  C07C33/48 ,  C07C67/08 ,  C07C69/743 ,  C07C69/747 ,  C07C255/36 ,  C07C255/38 ,  C07C255/39

Abstract: Dihalogenovinylbenzyl esters of the general formula I in which R is hydrogen, cyano, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, X is chlorine, bromine or fluorine, X is chlorine, bromine or fluorine and A is the carboxylate radical of an acid component typical in pyrethroids, process and precursors for their preparation, and their use for controlling pests.

公开(公告)号：GR3002549T3

公开(公告)日：1993-01-25

申请号：GR900401121

申请日：1990-12-21

Applicant: BASF AG

Inventor： SCHUETZ FRANZ DR ,  SAUTER HUBERT DR ,  SCHIRMER ULRICH DR ,  WOLF BERND DR ,  AMMERMANN EBERHARD DR ,  POMMER ERNST-HEINRICH DR

IPC: C07C331/14 ,  A01N35/08 ,  A01N37/00 ,  A01N37/02 ,  A01N37/06 ,  A01N37/18 ,  A01N37/34 ,  A01N37/36 ,  A01N37/38 ,  A01N37/40 ,  A01N37/44 ,  A01N37/48 ,  A01N39/02 ,  A01N43/04 ,  A01N43/08 ,  A01N43/36 ,  A01N45/00 ,  A01N47/48 ,  A01N49/00 ,  A01N53/00 ,  A01N53/06 ,  A01N59/24 ,  C07C67/00 ,  C07C67/11 ,  C07C69/007 ,  C07C69/025 ,  C07C69/608 ,  C07C69/612 ,  C07C69/614 ,  C07C69/62 ,  C07C69/73 ,  C07C69/732 ,  C07C69/734 ,  C07C69/74 ,  C07C69/75 ,  C07C69/76 ,  C07C69/78 ,  C07C69/92 ,  C07C201/00 ,  C07C205/56 ,  C07C213/00 ,  C07C219/22 ,  C07C229/12 ,  C07C233/00 ,  C07C233/12 ,  C07C235/34 ,  C07C235/42 ,  C07C237/20 ,  C07C253/00 ,  C07C255/07 ,  C07C255/34 ,  C07C255/38 ,  C07C255/53 ,  C07C313/00 ,  C07C323/16 ,  C07C323/20 ,  C07C323/56 ,  C07C323/62 ,  C07C325/00 ,  C07D207/327 ,  C07D295/155 ,  C07D307/16 ,  C07D307/54 ,  C07D307/68

Abstract: Ortho-substituted benzyl carboxylates of the formula I where R1 is alkoxy, alkylthio, halogen or amino, R2 is alkoxycarbonyl, cyano or CONH2, R3 l is hydrogen, halogen, cyano, aryl, aryloxy, a saturated or unsaturated heterocyclic radical, cycloalkyl, or substituted cyclopropyl, X is alkylene, and n is 0 or 1, and fungicides containing these compounds.

公开(公告)号：DE58902490D1

公开(公告)日：1992-11-26

申请号：DE58902490

申请日：1989-06-10

Applicant: BASF AG

Inventor： HERMELING DIETER DR ,  DEGNER DIETER DR ,  HARREUS ALBRECHT DR ,  GOETZ NORBERT DR ,  WILD JOCHEN DR ,  THEOBALD HANS DR ,  WOLF BERND DR

IPC: C07C17/00 ,  C07C17/093 ,  C07C25/02 ,  C07C25/13 ,  C07C25/18 ,  C07C27/02 ,  C07C33/46 ,  C07C33/50 ,  C07C67/00 ,  C07C69/025 ,  C07C69/07 ,  C25B3/23 ,  C25B3/02

Abstract: Process for manufacturing benzene derivatives of the general formula in which Hal is a halogen atom, R is a hydrocarbon radical with 1 to 18 C atoms, R is a hydrogen atom or an alkyl radical with 1 to 6 C atoms and X is a hydrogen or halogen atom, in which toluene derivatives of the general formula are electrochemically oxidised in the presence of an acid of the formula R -COOH (III), and benzene derivatives of the general formula in which R is a hydrogen atom or a R -CO radical, but where R cannot be methyl when X is hydrogen, and benzene derivatives of the general formula in which R is a branched or cyclic alkyl radical with 3 to 12 C atoms, but where R cannot be isopropyl when X is hydrogen.