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    1-(PYRIDYL)-PYRAZOLE UND IHRE VERWENDUNG ALS HERBIZIDE
    31.
    发明公开
    1-(PYRIDYL)-PYRAZOLE UND IHRE VERWENDUNG ALS HERBIZIDE 失效
    1-（吡啶基）吡唑类及其作为除草剂

    公开(公告)号：EP0846113A1

    公开(公告)日：1998-06-10

    申请号：EP96927702.0

    申请日：1996-08-07

    Applicant: BASF AKTIENGESELLSCHAFT

    Inventor： HAMPRECHT, Gerhard ,  HEISTRACHER, Elisabeth ,  KLINTZ, Ralf ,  SCHÄFER, Peter ,  ZAGAR, Cyrill ,  SCHIFFER, Helmut ,  WESTPHALEN, Karl-Otto ,  MISSLITZ, Ulf ,  WALTER, Helmut

    IPC: A01N43 ,  C07D401 ,  C07D521

    CPC classification number: C07D231/12 ,  A01N43/56 ,  C07D233/56 ,  C07D249/08 ,  C07D401/04

    Abstract: The invention concerns substituted 1-(pyridyl)-pyrazols of general formula (I) in which the substituents have the following meanings: R1: hydrogen, C¿1?-C3 alkyl, halogen, C1-C3 alkyl halide; R?2: C¿1-C4 alkyl, C2-C4 alkenyl, C2-C4 alkinyl, C1-C4 alkoxy, C3-C4 alkenyloxy, C3-C4 alkinyloxy, which can be substituted by 1 to 6 halogen atoms, NO2, cyano, halogen, rhodano, amino, furthermore a C(=O)R7, S(O)¿nR?8 or NH-C(=O)R9 group; R3: amino, halogen, rhodano, cyano, nitro, hydroxy, C¿1?-C3 alkyl, C1-C3 alkyl halide, furthermore an S(O)nR?8, N(R10)R11, OR12, SR13, N=C(R14)-N(R15)R16¿ group or, if R1 = hydrogen, additionally N=C(R?17)R18; R4¿: halogen, an XR19 group or, if R3 = N=C(R?14)-N(R15)R16¿ and N(R?10)R11 when R10¿ = hydrogen or C(=O)R?7 and R11 = C¿3-C4 alkenyl or C3-C4 alkinyl or, if R6 = fluorine or trifluoromethyl, additionally hydrogen; and R5, R6: independently of each other, halogen or C¿1?-C3 alkyl halide. The invention further concerns the N-oxides and salts of compounds (I) which can be used for agricultural purposes, processes for their preparation and their use as herbicides.

    PYRAZOL-4-YL-BENZOYLDERIVATE UND IHRE VERWENDUNG ALS HERBIZIDE
    33.
    发明公开
    PYRAZOL-4-YL-BENZOYLDERIVATE UND IHRE VERWENDUNG ALS HERBIZIDE 失效
    吡唑-4-基苯甲酰及其作为除草剂

    公开(公告)号：EP0811007A1

    公开(公告)日：1997-12-10

    申请号：EP96902274.0

    申请日：1996-02-14

    Applicant: BASF AKTIENGESELLSCHAFT

    Inventor： VON DEYN, Wolfgang ,  HILL, Regina, Luise ,  KARDORFF, Uwe ,  ENGEL, Stefan ,  OTTEN, Martina ,  VOSSEN, Marcus ,  PLATH, Peter ,  RANG, Harald ,  HARREUS, Albrecht ,  KÖNIG, Hartmann ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto ,  MISSLITZ, Ulf

    IPC: C07D231 ,  A01N43 ,  C07D277 ,  C07D401 ,  C07D403 ,  C07D405 ,  C07D409 ,  C07D411 ,  C07D413 ,  C07D417

    CPC classification number: C07D401/10 ,  A01N43/56 ,  A01N43/74 ,  A01N43/80 ,  C07D231/24 ,  C07D403/10 ,  C07D405/10 ,  C07D409/10 ,  C07D411/10 ,  C07D413/10 ,  C07D417/10

    Abstract: Pyrazol-4-yl-benzoyl derivatives have the formula (I), in which the substituents have the following meanings: L, M are hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy, these groups being optionally substituted by 1 to 5 halogen atoms or C1-C4 alkoxy, halogen, cyano, nitro, a group -(Y)n-S(O)mR7 or a group -(Y)¿n-CO-R?8; Z is a 5 or 6-membered saturated or unsaturated heterocyclic rest, that contains 1 to 3 heteroatoms selected from the group that includes oxygen, sulphur or nitrogen, optionally substituted by halogen, cyano, nitro, a group -CO-R8, C1-C4 alkyl, C1-C4 halogen alkyl, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkylthio, C1-C4 halogen alkylthio, di-C1-C4-alkylamino, a phenyl optionally substituted by halogen, cyano, nitro C1-C4 alkyl or C1-C4 halogen alkyl or a twice bound oxygen that optionally in the tautomer form may also be a hydroxy group, or that forms a bicyclic system together with a condensed phenyl ring optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 halogen alkyl, with a condensed carbon cycle or with a second condensed heterocycle optionally substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4-alkylamino, C1-C4 alkoxy, C1-C4 halogen alkoxy or C1-C4 halogen alkyl; Y is O, NR9; n equals 0 or 1; m equals 0, 1 or 2; R7 is C1-C4 alkyl, C1-C4 halogen alkyl or NR?9R10; R8 is C¿1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy or NR?9R10; R9¿ is hydrogen or C¿1?-C4 alkyl; R?10 is C¿1-C4 alkyl; Q is a pyrazol ring linked at position 4 having the formula (II) in which R1 is C1-C4 alkyl; R2 is hydrogen or C¿1?-C4 alkyl; and R?3¿ is hydrogen, C¿1?-C4 alkyl sulphonyl, phenyl sulphonyl or alkyl phenyl sulphonyl. Also disclosed are the salts of compounds (I) usually utilized in agriculture.

    CYCLOHEXENONOXIMETHER, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ALS HERBIZIDE
    34.
    发明公开
    CYCLOHEXENONOXIMETHER, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ALS HERBIZIDE 失效
    环己，其制造方法相同，它们作为除草剂。

    公开(公告)号：EP0625975A1

    公开(公告)日：1994-11-30

    申请号：EP93917360.0

    申请日：1993-01-30

    Applicant: BASF Aktiengesellschaft

    Inventor： MISSLITZ, Ulf ,  MEYER, Norbert ,  KAST, Juergen ,  BOTT, Kaspar ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto ,  KARDORFF, Uwe ,  GERBER, Matthias

    IPC: A01N35 ,  A01N43 ,  C07C251 ,  C07C323 ,  C07D231 ,  C07D261 ,  C07D309 ,  C07D333 ,  C07D335

    CPC classification number: A01N43/18 ,  A01N35/10 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/56 ,  A01N43/80 ,  C07C251/54 ,  C07C323/47 ,  C07C2601/16 ,  C07D261/08 ,  C07D309/06 ,  C07D333/22 ,  C07D335/02

    Abstract: Ethers de cyclohexénone-oximes de formule (I), où: R1 = alkyle en C1-C6; W = chaîne alcylène en C2-C4 éventuellement substituée par un alkyle en C1-C3; X = NO2, CN, halogène, alkyle en C1-C4, halogénoalkyle en C1-C4; n = 0 à 3 ou 1 à 5, dans le cas où tous les X sont des halogènes; R2 = C1-C4-alkoxy-C1-C6-alkyle, C1-C4-alkylthio-C1-C6-alkyle, cycloalkyle en C3-C7 éventuellement substitué, cycloalcényle en C5-C7 éventuellement substitué, hétérocycle saturé à 5 chaînons, éventuellement substitué, portant 1 ou 2 atomes d'oxygène et/ou de soufre, hétéro-cycle à 6 ou 7 chaînons, éventuellement substitué, ayant 1 ou 2 atomes d'oxygène et/ou de soufre non voisins, pouvant être saturé ou une ou deux fois insaturé, groupe hétéro-aromatique à 5 chaînons, éventuellement substitué, renfermant 1 ou 2 atomes de N et un atome de 0 ou un atome de S, phényle ou pyridyle, les deux pouvant porter encore 1 à 3 substituants: halogène, NO2, CN, alkyle, alcoxy, alkylthio, halogénoalkyle, alcényloxy, alcinyloxy et/ou -NRaRb; Ra = H, alkyle, alcényle, ou alcinyle, et Rb = H, alkyle, alcényle, alcinyle, acyle, ou benzoyle éventuellement substitué; ainsi que les sels utilisables en agriculture et les esters d'acides carboxyliques en C1-C10 et d'acides anorganiques des composés (I).

    Abstract translation: PCT号 PCT / EP93 / 00215秒。 371 8月11日，1994年二段。 102（e）中的日期1994年8月11日提交的PCT 1993年1月30日的PCT公布。 号 WO93 / 16063的PCT公布。 日期8月19日1993.Cyclohexenone肟醚I I R1 = C1-C6烷基; W = unsubstituiertem或C1-C3烷基取代的C2-C4亚烷基链; X = NO 2，CN，卤素，C1-C4烷基，C1-C4卤代烷基; N = 0-3或1-5个，如果所有的X是卤素; R2 = C1-C4烷氧基C1-C6烷基，C1-C4烷硫基C1-C6烷基，substituiertem奥德unsubstituiertem C3-C7环烷基，substituiertem奥德unsubstituiertem C5-C7环烯基，substituiertem奥德unsubstituiertem 5- 元饱和杂环含有1或2个氧和/或硫原子，substituiertem奥德unsubstituiertem 6-或7-元杂环具有1个或2个非相邻的氧和/或硫原子间隔，且是饱和的或单 - 或多二不饱和，substituiertem奥德unsubstituiertem 5元杂芳族含1个或2个N原子和一个O或S原子，苯基或吡啶基，这两者都是unsubstituiertem或承担1-3个卤素，NO2，CN，烷基，烷氧基，烷基硫代，卤代烷基，链烯氧基，炔氧基和 /或-NRaRb的取代基; RA = H，烷基，烯基或炔基和R b = H，烷基，烯基，炔基，酰基或substituiertem奥德unsubstituiertem苯甲酰基; 及其农业利用的盐和式I化合物与C 1 -C 10羧酸和无机酸的酯。

    SUBSTITUIERTE PYRAZOL-3-YLBENZAZOLE
    37.
    发明授权
    SUBSTITUIERTE PYRAZOL-3-YLBENZAZOLE 失效
    取代的吡唑-3- YLBENZAZOLE

    公开(公告)号：EP0944623B1

    公开(公告)日：2004-09-01

    申请号：EP97954346.9

    申请日：1997-12-01

    Applicant: BASF AKTIENGESELLSCHAFT

    Inventor： ZAGAR, Cyrill ,  HAMPRECHT, Gerhard ,  MENGES, Markus ,  MENKE, Olaf ,  SCHÄFER, Peter ,  WESTPHALEN, Karl-Otto ,  MISSLITZ, Ulf ,  WALTER, Helmut

    IPC: C07D417/04 ,  A01N43/56 ,  C07D413/10 ,  C07D417/10 ,  C07D413/04

    CPC classification number: C07D413/04 ,  A01N43/74 ,  C07D417/04

    Abstract: The invention concerns substituted pyrazole-3-yl benzazoles of formula (I) and salts thereof, in the formula R1 designating H, C¿1?-C4 alkyl, C1-C4 alkyl halide; R?2¿ designating CN, C¿1?-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulphinyl, C1-C4-haloalkylsulphinyl, C1-C4-alkylsulphonyl, C1-C4-haloalkylsulphonyl; R?3¿ = H, CN, NO¿2?, halogen, C1-C4-alkyl, C1-C4-haloalkyl; R?4¿ designating H, halogen; R5 designating H, CN, halogen, C¿1?-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; Z designating -N=C(XR?6¿)-O- or -N=C(XR6)-S-, bonded to α by the nitrogen, oxygen or sulphur; X designating a chemical bond, oxygen, sulphur, -S(O)-, -SO¿2?-, -NH- or -N(R?7); R6, R7¿ designating C¿1?-C6-alkyl, C1-C6-haloalkyl, cyano-C1-C4-alkyl, hydroxy-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkinyl, cyano-C3-C6-alkinyl, C3-C6-haloalkinyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C8-cycloalkyloxy-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkylthio-C1-C4-alkyl, C3-C4-alkenylthio- C1-C4-alkyl, C3-C4-alkinylthio-C1-C4-alkyl, C1-C4-alkyl-sulphinyl-C1-C4-alkyl, C1-C4-haloalkylsulphinyl-C1-C4-alkyl, C3-C4-alkenylsulphinyl-C1-C4-alkyl, C3-C4-alkinylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphonyl-C1-C4-alkyl, C1-C4-haloalkylsulphonyl-C1-C4-alkyl, C3-C4-alkenylsulphonyl-C1-C4-alkyl, C3-C4-alkinylsulphonyl-C1-C4-alkyl, hydroxycarbonyl-C1-C4-alkyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl, which can carry a CN oder C1-C4-alkoxycarbonyl group, C1-C4-alkylthiocarbonyl-C1-C4-alkyl, aminocarbonyl-C1-C4-alkyl, C1-C4-alkylaminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)-phosphonyl-C1-C4-alkyl, C1-C4-alkoxyimino-C1-C4-alkyl, C3-C4-alkenyloxyimino-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-member heterocyclic or heterocyclyl-C1-C4-alkyl, wherein each cycloalkyl ring and each heterocyclyl ring contain a CO or CS ring member; if X is a chemical bond, -O-, -S-, -NH- or -N(R?7)-, R6¿ also being C¿1?-C4 alkylcarbonyl, C1-C4 haloalkylcarbonyl, C1-C4 alkoxycarbonyl, C1-C4 alkylsulphonyl or C1-C4 haloalkylsulphonyl; if X is a chemical bond, R?6¿ additionally designating CN, SH, NH¿2?, halogen, -CH2-CH(halogen)-R?8¿, -CH=CH-R8 or -CH=C(halogen)-R8, R8 designating COOH, C¿1?-C4 alkoxycarbonyl, C1-C4 alkylthiocarbonyl, CONH2, C1-C4 alkylaminocarbonyl, di(C1-C4 alkyl)aminocarbonyl or di(C1-C4 alkyl)phosphonyl; or R?6 plus R7¿ designating an optionally substituted 1,3-propylene, tetramethylene, pentamethylene or ethylene oxyethylene chain. The invention also concerns the use of these substances as herbicides and for the desiccation and/or defoliation of plants.

    VERFAHREN ZUR HERSTELLUNG VON PYRAZOLYLBENZOYLDERIVATEN SOWIE NEUE PYRAZOLYLBENZOYLDERIVATE
    38.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON PYRAZOLYLBENZOYLDERIVATEN SOWIE NEUE PYRAZOLYLBENZOYLDERIVATE 有权

    公开(公告)号：EP1135386B1

    公开(公告)日：2003-04-02

    申请号：EP99966912.0

    申请日：1999-12-02

    Applicant: BASF AKTIENGESELLSCHAFT

    Inventor： NEIDLEIN, Ulf ,  GÖTZ, Norbert ,  MISSLITZ, Ulf ,  BAUMANN, Ernst ,  VON DEYN, Wolfgang ,  KUDIS, Steffen ,  LANGEMANN, Klaus ,  MAYER, Guido ,  WITSCHEL, Matthias ,  OTTEN, Martina ,  WESTPHALEN, Karl-Otto ,  WALTER, Helmut

    IPC: C07D409/06 ,  C07D401/06 ,  C07D417/06 ,  A01N43/56

    CPC classification number: C07D409/06 ,  C07D409/14

    Abstract: The invention relates to a method for producing pyrazolylbenzoyl derivatives of formula (I), wherein the substituents have the following meanings: R1 represents hydrogen, C¿1?-C4-alkyl or C1-C4 alkyl halide; R?2¿ represents hydrogen, C¿1?-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, benzyl, benzoyl, C1-C4-alkylcarbonyl, hydroxycarbonyl-C1-C4-alkyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl, C1-C4-alkylsulfonyl or phenylsulfonyl, and these groups can be substituted by C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio, halogen, hydroxy, amino, nitro or cyano; A,B represent, independently of each other, hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C1-C4-alkoxy and these groups can be substituted by halogen, hydroxy, C1-C4-alkoxy or cyano, halogen, hydroxy, cyano; nitro, a group-(Y)n-S(O)mR?3¿ or a group-(Y)¿n-CO-R?4; Z represents a 5- or 6-membered heterocyclic, saturated or unsaturated fused ring; Y represents O, NR5; n represents zero or one; m represents zero, one or two; R3 represents C¿1?-C4-alkyl, C1-C4-alkyl halide or NR?5R6; R4¿ represents C¿1?-C4-alkyl, C1-C4-alkyl halide, C1-C4-alkoxy, or NR?5R6; R5¿ represents hydrogen or C¿1?-C4-alkyl; and R?6¿ represents C¿1?-C4-alkyl. The invention also relates to novel pyrazolylbenzoyl derivatives, to herbicidal agents containing these derivatives and to a method for combating unwanted vegetation.

    Abstract translation: 本发明涉及制备式（I）的吡唑基苯甲酰基衍生物的方法，其中取代基具有以下含义：R 1表示氢，C 1 -C 4烷基或C 1 -C 4烷基卤化物; R 2代表氢，C 1 -C 6烷基，C 2 -C 6烯基，C 2 -C 6炔基，苄基，苯甲酰基，C 1 -C 4烷基羰基，羟基羰基-C 1 -C 4烷基， 烷氧基羰基-C1-C4-烷基，C1-C4-烷基磺酰基或苯基磺酰基，并且这些基团可以被C1-C4-烷基，C1-C4-烷氧基，C1-C4-烷硫基，卤素，羟基，氨基，硝基或氰基 ; A，B彼此独立地表示氢，C 1 -C 6烷基，C 2 -C 6烯基，C 2 -C 6炔基，C 1 -C 4烷氧基，并且这些基团可以被卤素，羟基，C 1 -C 4 - 烷氧基或氰基，卤素，羟基，氰基; 硝基，基团 - （Y）n -S（O）mR 3 3或基团 - （Y）n -CO-R 4。 Z表示5或6元杂环饱和或不饱和稠环; Y代表O，NR 5; n代表零或1; m表示零个，一个或两个; R 3代表C 1 -C 4烷基，C 1 -C 4烷基卤或NR 5 R 6; R 4代表C 1 -C 4烷基，C 1 -C 4烷基卤化物，C 1 -C 4烷氧基或NR 5 R 6; R5代表氢或C1-C4烷基; R 6'代表C 1 -C 4烷基。 本发明还涉及新的吡唑基苯甲酰基衍生物，含有这些衍生物的除草剂以及用于防治不想要的植物的方法。

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