公开(公告)号：AU2017217911B2

公开(公告)日：2021-10-07

申请号：AU2017217911

申请日：2017-02-02

Applicant: BASF SE

Inventor： KATZ TORSTEN ,  NOTZ RALF ,  KERN ANDREAS

IPC: B01D53/14

Abstract: The invention relates to a method for separating C

公开(公告)号：ZA201802683B

公开(公告)日：2019-07-31

申请号：ZA201802683

申请日：2018-04-23

Applicant: BASF SE

Inventor： VORBERG GERALD ,  NOTZ RALF ,  INGRAM THOMAS ,  SIEDER GEORG ,  KATZ TORSTEN ,  GRUENANGER CHRISTIAN ,  DEGLMANN PETER

Abstract: An absorbent for selective removal of hydrogen sulfide from a fluid stream comprises an aqueous solution comprising a) a tertiary amine; b) an aminic pH promoter selected from the compounds mentioned in the description; where the molar ratio of b) to a) is in the range from 0.05 to 1.0; and c) an acid having a pKA of less than 6 in such an amount that the pH of the aqueous solution measured at 120° C. is 7.9 to less than 8.8. Also described is a process for removing acidic gases from a fluid stream, in which the fluid stream is contacted with the absorbent. The absorbent is notable for a low regeneration energy.

公开(公告)号：SG11201801360PA

公开(公告)日：2018-04-27

申请号：SG11201801360P

申请日：2016-09-28

Applicant: BASF SE

Inventor： VORBERG GERALD ,  NOTZ RALF ,  INGRAM THOMAS ,  SIEDER GEORG ,  KATZ TORSTEN ,  GRUENANGER CHRISTIAN ,  DEGLMANN PETER

IPC: B01D53/14

Abstract: An absorbent for selective removal of hydrogen sulfide from a fluid stream comprises an aqueous solution comprising a) a tertiary amine; b) an aminic pH promoter selected from the compounds mentioned in the description; where the molar ratio of b) to a) is in the range from 0.05 to 1.0; and c) an acid having a pKA of less than 6 in such an amount that the pH of the aqueous solution measured at 120° C. is 7.9 to less than 8.8. Also described is a process for removing acidic gases from a fluid stream, in which the fluid stream is contacted with the absorbent. The absorbent is notable for a low regeneration energy.

公开(公告)号：AU2015309019A1

公开(公告)日：2017-03-16

申请号：AU2015309019

申请日：2015-08-20

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  NOTZ RALF ,  VORBERG GERALD ,  SIEDER GEORG ,  LOZANO MARTINEZ GUSTAVO ADOLFO ,  GARCIA ANDARCIA HUGO RAFAEL

IPC: B01D53/14

Abstract: Disclosed is an absorbent for removing carbon dioxide from a fluid flow, said absorbent comprising an aqueous solution of: a) an amine of general formula (I), wherein R

公开(公告)号：ES2543313T3

公开(公告)日：2015-08-18

申请号：ES12712643

申请日：2012-03-30

Applicant: BASF SE

Inventor： SIEDER GEORG ,  NOTZ RALF ,  GARCIA ANDARCIA HUGO RAFAEL ,  SCHMIDT SANDRA ,  MOSER PETER

IPC: B01D53/14 ,  B01D53/62

Abstract: Procedimiento para la separación de gases ácidos de un flujo de fluido, en el que a) se trata el flujo de fluido en una zona de absorción con un agente de absorción que comprende una solución acuosa al menos de una amina, b) se conduce el flujo de fluido tratado por al menos dos zonas de lavado y se trata con una fase acuosa no ácida para transferir amina arrastrada y/o productos de descomposición de amina arrastrados al menos parcialmente a la fase acuosa, reciclándose la fase acuosa a través de al menos una zona de lavado y conduciéndose la fase acuosa sin reciclado por al menos una zona de lavado, en el que una primera zona de lavado está dispuesta por encima de la zona de absorción y una segunda zona de lavado está dispuesta por encima de la primera zona de lavado, en el que se recicla la fase acuosa a través de la segunda zona de lavado, se conduce un flujo parcial de la fase acuosa reciclada a través de la segunda zona de lavado por la primera zona de lavado y se combina la fase acuosa que sale de la primera zona de lavado con el agente de absorción en la zona de absorción y se enfría la fase acuosa reciclada a través de la segunda zona de lavado.

公开(公告)号：CA2764255A1

公开(公告)日：2010-12-29

申请号：CA2764255

申请日：2010-06-21

Applicant: BASF SE

Inventor： GARCIA ANDARCIA HUGO RAFAEL ,  NOTZ RALF ,  SIEDER GEORG ,  SPUHL OLIVER ,  HASSE HANS ,  TOENNIES INGA ,  HOCH SEBASTIAN ,  MANGALAPALLY HARI PRASAD

IPC: B01D53/14

Abstract: A process for removing acidic gases from a fluid stream, in which a) the fluid stream is treated with an absorption liquid which comprises at least one amine, a stripping aid and water, said stripping aid being selected from water-miscible liquids whose boiling temperature at standard pressure is lower than that of water, b) the treated fluid stream is treated with a liquid aqueous phase in order to transfer entrained stripping aid at least partly to the aqueous phase, c) the laden aqueous phase is heated in order to at least partly drive out the stripping aid, and d) the aqueous phase thus regenerated is cooled and recycled at least partly into step b). The stripping aid promotes the regeneration of the absorbent by stripping. Emissions of the stripping aid via the treated fluid stream are avoided by washing the treated fluid stream with a liquid aqueous phase.

公开(公告)号：CA2959095C

公开(公告)日：2022-08-09

申请号：CA2959095

申请日：2015-08-20

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  NOTZ RALF ,  VORBERG GERALD ,  SIEDER GEORG ,  LOZANO MARTINEZ GUSTAVO ADOLFO ,  GARCIA ANDARCIA HUGO RAFAEL

IPC: B01D53/14

Abstract: Disclosed is an absorbent for removing carbon dioxide from a fluid flow, said absorbent comprising an aqueous solution of: a) an amine of general formula (I), wherein R1, R2 and R3 are selected independently from one another from C1-4-alkyl and C1-4-hydroxyalkyl, R4 in each case is selected independently from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl, R5 in each case is selected independently from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl, X stands for OH or NH(CR1R2R3), m stands for 2, 3, 4 or 5, n stands for 2, 3, 4 or 5, and o stands for 0 or 1; and b) at least one activator selected from 5-, 6-, or 7-membered heterocycles with an NH group in the ring and one or to other heteroatoms in the ring, which are selected from nitrogen and oxygen. The absorbent enables a rapid absorption of carbon dioxide from fluid flows.

公开(公告)号：AU2015309019B2

公开(公告)日：2019-12-19

申请号：AU2015309019

申请日：2015-08-20

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  NOTZ RALF ,  VORBERG GERALD ,  SIEDER GEORG ,  LOZANO MARTINEZ GUSTAVO ADOLFO ,  GARCIA ANDARCIA HUGO RAFAEL

IPC: B01D53/14

Abstract: Disclosed is an absorbent for removing carbon dioxide from a fluid flow, said absorbent comprising an aqueous solution of: a) an amine of general formula (I), wherein R

公开(公告)号：ZA201802684B

公开(公告)日：2019-07-31

申请号：ZA201802684

申请日：2018-04-23

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  SIEDER GEORG ,  KATZ TORSTEN ,  VORBERG GERALD ,  NOTZ RALF

Abstract: The use of an amine of the formula (I)in which the R1 to R5 radicals are each as defined in the description, and an absorbent and a process for removing acidic gases from a fluid stream, especially for selectively removing hydrogen sulfide over carbon dioxide. The invention also relates to particular amines suitable for selective removal of hydrogen sulfide. Absorbents based on amines of the formula (I) have high selectivity, high loading capacity and good regeneration capacity.

公开(公告)号：UA118806C2

公开(公告)日：2019-03-11

申请号：UAA201702785

申请日：2015-08-20

Applicant: BASF SE

Inventor： VORBERG GERALD ,  NOTZ RALF ,  INGRAM THOMAS ,  SIEDER GEORG ,  KATZ TORSTEN

IPC: B01D53/14 ,  C10L3/10

Abstract: Абсорбентдляселективноговидаленнясірководнюізфлюїдногопотокуміститьводнийрозчин a) третинногоаміну, b) стеричноутрудненоговторинногоамінузагальноїформули (І) ,(І) вякій R1 і R2 вкожномувипадкунезалежноодинвідодноговибраніз-поміжС1-4-алкілуі С1-4-гідроксіалкілу; вкожномувипадкунезалежноодинвідодноговибраніз-поміжС1-4-алкілуі С1-4-гідроксіалкілу; R3, R4, R5 і R6 вкожномувипадкунезалежноодинвідодноговибраніз-поміжводню, С1-4-алкілуі С1-4-гідроксіалкілу, іззастереженням, щопринаймніодинзалишок R4 і/або R5 біляатомавуглецю, якийбезпосередньоприєднанийдоатомаазоту, означаєС1-4-алкілабоС1-4-гідроксіалкіл, якщо R3 означаєводень; хі уозначаютьцілічиславід 2 до 4, a z означаєцілечисловід 1 до 4; причомупричомумолярнеспіввідношенняміж b) таа) становитьвід 0,3 до 0,7, іс) кислотув кількості, розрахованійякеквівалентнейтралізаціївідносноздатнихдопротонуванняатомівазотув а) і b), від 1,0 до 9,0 %. ПереважнимаміномформулиІ є 2-(2-трет-бутиламіноетоксі)етанол. Абсорбентдозволяєвстановлювативизначенуселективністьвідносно H2S підтиском, якийзазвичайпануєприобробціприродногогазу.