METHOD FOR THE PRODUCTION OF LIGNOCELLULOSE MATERIALS

    公开(公告)号:CA2936607A1

    公开(公告)日:2015-07-16

    申请号:CA2936607

    申请日:2015-01-09

    Applicant: BASF SE

    Inventor: WEINKOTZ STEPHAN

    Abstract: The invention relates to a method for producing lignocellulose materials by mixing A) lignocellulose-containing particles or fibers with B) organic isocyanate comprising at least two isocyanate groups or mixtures thereof, optionally with C) binders selected from among the group comprising phenol formaldehyde resins, aminoplast resins, protein-based binders, and other polymer-based binders or mixtures thereof, D) additives or mixtures thereof, E) plastic particles or mixtures thereof. In said method, in step i.) the obtained mixture is spread to form a mat, ii.) the mat is pre-compact and heated during or following the pre-compacting process, and iii.) then the mat is hot-pressed by applying an increased temperature in method step ii.) during and/or following the pre-compacting process, the obtained mat reaching a minimum value of 4 cm in the push-off test.

    LIGNOCELLULOSIC MATERIALS COMPRISING DEFIBRILLATED CELLULOSE

    公开(公告)号:CA2926134A1

    公开(公告)日:2015-04-16

    申请号:CA2926134

    申请日:2014-09-29

    Applicant: BASF SE

    Abstract: The present invention relates to new and improved lignocellulosic materials containing (A) 30-98.99% wt. of one or more lignocellulose-containing materials; (B) 0.01-50% wt. microfibrillated cellulose; (C) 1-5% wt. binder selected from the group consisting of aminoplastic resin, phenolformaldehyde resin, organic isocyanate with at least two isocyanate groups, or mixtures thereof, optionally with a curing agent; (D) 0-25% wt. expanded plastic particles with a bulk density ranging from 10 to 150 kg/m3; and (E) 0-68% wt. additives.

    Multilayer lignocellulose-containing moldings having low formaldehyde emission

    公开(公告)号:AU2011298919B2

    公开(公告)日:2014-02-20

    申请号:AU2011298919

    申请日:2011-08-29

    Applicant: BASF SE

    Abstract: A multilayer lignocellulose-containing molding comprising A) a middle layer or a plurality of middle layers comprising lignocellulose-containing particles which is/are obtainable by using a binder (a) and B) a covering layer or a plurality of covering layers comprising lignocellulose-containing particles which is/are obtainable by using a binder (b), the binder (a) being selected from the group consisting of (a1) formaldehyde resins and (a2) an organic isocyanate having at least two isocyanate groups; the binder (b) comprising the following components: an aqueous component (I) comprising (i) a polymer A which is composed of the following monomers: a) from 70 to 100% by weight of at least one ethylenically unsaturated mono- and/or dicarboxylic acid (monomer(s) A1) and b) from 0 to 30% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers A1 (monomer(s) A2) optionally (ii) a low molecular weight crosslinking agent having at least two functional groups which are selected from the group consisting of hydroxyl, carboxyl and derivatives thereof, primary, secondary and tertiary amine, epoxy, aldehyde, an organic isocyanate having at least two isocyanate groups as component (II) and, optionally, a component (III), as an aqueous dispersion, comprising one or more polymer(s) M which is/are composed of the following monomers: a) from 0 to 50% by weight of at least one ethylenically unsaturated monomer which comprises at least one epoxide and/or at least one hydroxyalkyl group (monomer(s) M1) and b) from 50 to 100% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers M1 (monomer(s) M2) and, optionally, customary additives as component (IV), and the binder (b) optionally comprises a formaldehyde scavenger.

    MULTILAYER LIGNOCELLULOSE-CONTAINING MOLDINGS HAVING LOW FORMALDEHYDE EMISSION

    公开(公告)号:CA2821159A1

    公开(公告)日:2012-06-21

    申请号:CA2821159

    申请日:2011-12-14

    Applicant: BASF SE

    Abstract: The invention relates to a multi-layer molded body that contains lignocellulose, comprising A) a middle layer or a plurality of middle layers, which contain(s) particles that contain lignocellulose and which can be obtained by using a binder (a), and B) an outer layer or a plurality of outer layers, which contain(s) particles that contain lignocellulose and which can be obtained by using a binder (b), wherein the binder (a) is selected from the group comprising (a1) formaldehyde resins and (a2) an organic isocyanate having at least two isocyanate groups; wherein the binder (b) contains the following components: an aqueous component (I) containing (i) a polymer A, which is constructed from the following monomers: a) 70 to 100 wt % of at least one ethylenically unsaturated monocarboxylic acid and/or dicarboxylic acid (monomer(s) A1) and b) 0 to 30 wt % of at least one additional ethylenically unsaturated monomer that differs from the monomers A1 (monomer(s) A2), possibly (ii) a low-molecular-weight cross-linking agent having at least two functional groups, which are selected from the group comprising hydroxy, carboxylic acid and derivatives thereof, primary, secondary, and tertiary amine, epoxy, and aldehyde, an organic isocyanate having at least two isocyanate groups as component (II), and possibly a component (III) as an aqueous dispersion containing one or more polymers M, which are constructed from the following monomers: a) 0 to 50 wt % of at least one ethylenically unsaturated monomer that contains at least one epoxide group and/or at least one hydroxyalkyl group (monomer(s) M1), and b) 50 to 100 wt % of at least one additional ethylenically unsaturated monomer that differs from the monomers M1 (monomer(s) M2), and possibly common additives as component (IV), and wherein at least one middle layer (A) contains expanded plastic particles and possibly at least one outer layer B) contains expanded plastic particles, and the binder (b) possibly contains a formaldehyde scavenger.

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