Abstract:
The invention relates to a multi-layer molded body that contains lignocellulose, comprising A) a middle layer or a plurality of middle layers, which contain(s) particles that contain lignocellulose and which can be obtained by using a binder (a), and B) an outer layer or a plurality of outer layers, which contain(s) particles that contain lignocellulose and which can be obtained by using a binder (b), wherein the binder (a) is selected from the group comprising (a1) formaldehyde resins and (a2) an organic isocyanate having at least two isocyanate groups; wherein the binder (b) contains the following components: an aqueous component (I) containing (i) a polymer A, which is constructed from the following monomers: a) 70 to 100 wt % of at least one ethylenically unsaturated monocarboxylic acid and/or dicarboxylic acid (monomer(s) A1) and b) 0 to 30 wt % of at least one additional ethylenically unsaturated monomer that differs from the monomers A1 (monomer(s) A2), possibly (ii) a low-molecular-weight cross-linking agent having at least two functional groups, which are selected from the group comprising hydroxy, carboxylic acid and derivatives thereof, primary, secondary, and tertiary amine, epoxy, and aldehyde, an organic isocyanate having at least two isocyanate groups as component (II), and possibly a component (III) as an aqueous dispersion containing one or more polymers M, which are constructed from the following monomers: a) 0 to 50 wt % of at least one ethylenically unsaturated monomer that contains at least one epoxide group and/or at least one hydroxyalkyl group (monomer(s) M1), and b) 50 to 100 wt % of at least one additional ethylenically unsaturated monomer that differs from the monomers M1 (monomer(s) M2), and possibly common additives as component (IV), and wherein at least one middle layer (A) contains expanded plastic particles and possibly at least one outer layer B) contains expanded plastic particles, and the binder (b) possibly contains a formaldehyde scavenger.
Abstract:
La presente invención se refiere a un método para producir partículas de polímeros por emulsión cuya estructura es de núcleo-capa, en la que la relación ponderal de las capas está dentro de límites específicos, y también a su uso en pinturas, revestimientos de papel, espuma y composiciones cosméticas.
Abstract:
The present invention relates to a process for modifying an aqueous polymer latex of polymer particles that bear carboxyl groups comprising the mixing of the aqueous polymer latex with at least one silane compound of formula (1) at a temperature of at least 60°C: (RO)3-nR1nSiR2X (1) wherein R is C1-C10-alkyl, C3-C10-cycloalkyl, C6-C10-aryl, C1-C10-alkoxy-C1-C10-alkyl, C2-C10-alkenyl, C1-C4-alkyl-C6-C10-aryl or C6-C10-aryl-C1-C4-alkyl, R1 is C1-C10-alkyl, C3-C10-cycloalkyl, C6-C10-aryl, C2-C10-alkenyl, C1-C4-alkyl-C6-C10-aryl or C6-C10-aryl-C1-C4-alkyl, R2 is a covalent chemical bond or a C1-C20-alkylene, in which non-adjacent methylene units can be replaced by O-groups, n is 0, 1, 2 or 3, and X is a radical having 3 to 10 carbon atoms and bearing an oxirane group. The present invention also relates to modified aqueous polymer latexes obtainable by such process and to the use of these polymer latexes as binders or co-binders for industrial varnishes.
Abstract:
Described is an aqueous coating composition comprising an aqueous dispersion of a radically polymerized addition polymer and phyllosilicate. The aqueous polymer dispersion has a particularly low electrical conductivity. The composition can be used for providing oxygen barrier properties to polymer films.
Abstract:
Cuerpo moldeado que contiene lignocelulosa multicapa a partir de A) una capa media o varias capas medias, que contienen partículas que contienen lignocelulosa, que puede/n obtenerse mediante el uso de un aglutinante (a) y B) una capa de cubierta o varias capas de cubierta, que contienen partículas que contienen lignocelulosa, que puede/n obtenerse mediante el uso de un aglutinante (b), seleccionándose el aglutinante (a) del grupo que consiste en (a1) resinas de formaldehído y (a2) un isocianato orgánico con al menos dos grupos isocianato; conteniendo el aglutinante (b) los siguientes componentes: un componente acuoso (I) que contiene (i) un polímero A, que está construido a partir de los siguientes monómeros: a) del 70 al 100 % en peso de al menos un ácido mono- y/o dicarboxílico etilénicamente insaturado (monómero(s) A1) y b) del 0 al 30 % en peso de al menos un monómero etilénicamente insaturado adicional, que se diferencia de los monómeros A1 (monómero(s) A2), y opcionalmente (ii) un agente reticulante de bajo peso molecular con al menos dos grupos funcionales que se seleccionan del grupo hidroxilo, ácido carboxílico y sus derivados, amina primaria, secundaria y terciaria, epoxi, aldehído, un isocianato orgánico con al menos dos grupos isocianato como componente (II) y opcionalmente un componente (III) como dispersión acuosa, que contiene uno o varios polímero(s) M, que está(n) construido(s) a partir de los siguiente monómeros: a) del 0 al 50 % en peso de al menos un monómero etilénicamente insaturado, que contiene al menos un grupo epóxido y/o al menos un grupo hidroxialquilo (monómero(s) M1), y b) del 50 al 100 % en peso de al menos un monómero etilénicamente insaturado adicional, que se diferencia de los monómeros M1 (monómero(s) M2) así como opcionalmente aditivos habituales como componente (IV), poniéndose en contacto preferentemente el componente (II) no previamente mezclado con los componentes adicionales (I) y/o (III) y/o (IV) con las partículas que contienen lignocelulosa, y conteniendo opcionalmente el aglutinante (b) un captor de formaldehído.
Abstract:
A multilayer lignocellulose-containing molding comprising A) a middle layer or a plurality of middle layers comprising lignocellulose-containing particles which is/are obtainable by using a binder (a) and B) a covering layer or a plurality of covering layers comprising lignocellulose-containing particles which is/are obtainable by using a binder (b), the binder (a) being selected from the group consisting of (a1) formaldehyde resins and (a2) an organic isocyanate having at least two isocyanate groups; the binder (b) comprising the following components: an aqueous component (I) comprising (i) a polymer A which is composed of the following monomers: a) from 70 to 100% by weight of at least one ethylenically unsaturated mono- and/or dicarboxylic acid (monomer(s) A1) and b) from 0 to 30% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers A1 (monomer(s) A2) optionally (ii) a low molecular weight crosslinking agent having at least two functional groups which are selected from the group consisting of hydroxyl, carboxyl and derivatives thereof, primary, secondary and tertiary amine, epoxy, aldehyde, an organic isocyanate having at least two isocyanate groups as component (II) and, optionally, a component (III), as an aqueous dispersion, comprising one or more polymer(s) M which is/are composed of the following monomers: a) from 0 to 50% by weight of at least one ethylenically unsaturated monomer which comprises at least one epoxide and/or at least one hydroxyalkyl group (monomer(s) M1) and b) from 50 to 100% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers M1 (monomer(s) M2) and, optionally, customary additives as component (IV), and the binder (b) optionally comprises a formaldehyde scavenger.