BIMENTAL-EXCHANGEDZEOLITE BETA FROM ORGANOTEMPLATE-FREE SYNTHESIS AND USETHEREOF IN THE SELECTIVE CATALYTIC REDUCTION OF NOx
    34.
    发明公开
    BIMENTAL-EXCHANGEDZEOLITE BETA FROM ORGANOTEMPLATE-FREE SYNTHESIS AND USETHEREOF IN THE SELECTIVE CATALYTIC REDUCTION OF NOx 审中-公开
    BIMETALL-AUSGETAUSCHTER ZEOLITH-BETA AUS ORGANOTEMPLATE-FREIER SYNTHESE UND VERWENDUNG DAVON IN DER SELKKTIVEN KATALYTISCHEN NOX-REDUKTION

    公开(公告)号:EP3097054A4

    公开(公告)日:2017-08-30

    申请号:EP14877063

    申请日:2014-12-30

    Abstract: The present invention relates to a process for the production of a zeolitic material having a BEA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising one or more sources for YO2 and one or more sources for X2O3; (2) crystallizing the mixture obtained in step (1); (3) subjecting the zeolitic material having a BEA-type framework structure obtained in step (2) to an ion-exchange procedure with Cu; and (4) subjecting the Cu ion-exchanged zeolitic material obtained in step (3) to an ion-exchange procedure with Fe; wherein Y is a tetravalent element, and X is a trivalent element, wherein the mixture provided in step (1) and crystallized in step (2) further comprises seed crystals comprising one or more zeolitic materials having a BEA-type framework structure, and wherein the mixture provided in step (1) and crystallized in step (2) does not contain an organotemplate as a structure-directing agent, as well as to the zeolitic material having a BEA frame work structure per se, and to its use, in particular in a method for the treatment of NOx by selective catalytic reduction (SCR).

    Abstract translation: 本发明涉及生产具有包含YO 2和X 2 O 3的BEA型骨架结构的沸石材料的方法,其中所述方法包括以下步骤:(1)制备包含一种或多种YO 2源和一种或多种 X2O3来源; (2)使步骤(1)中获得的混合物结晶; (3)使步骤(2)中获得的具有BEA型骨架结构的沸石材料与Cu进行离子交换程序; (4)将步骤(3)中获得的Cu离子交换沸石材料与Fe进行离子交换程序; 其中Y是四价元素,并且X是三价元素,其中步骤(1)中提供并在步骤(2)中结晶的混合物还包含含有一种或多种具有BEA型骨架结构的沸石材料的晶种,并且其中 在步骤(1)中提供并在步骤(2)中结晶的混合物不含有作为结构导向剂的有机模板以及具有BEA框架结构本身的沸石材料,特别是其用途 在通过选择性催化还原(SCR)处理NOx的方法中。

    SYNTHESIS OF ZEOLITIC MATERIALS USING N,N-DIMETHYL ORGANOTEMPLATES
    35.
    发明公开
    SYNTHESIS OF ZEOLITIC MATERIALS USING N,N-DIMETHYL ORGANOTEMPLATES 审中-公开
    沸石材料的合成使用N,N-二甲基有机模板

    公开(公告)号:EP2753579A4

    公开(公告)日:2015-08-19

    申请号:EP12830164

    申请日:2012-09-06

    Applicant: BASF SE

    CPC classification number: C01B39/48 B01J29/7015

    Abstract: A process for the preparation of a zeolitic material having a structure comprising YO2 and X2O3 is provided, wherein said process comprises the steps of ( 1 ) providing a mixture comprising one or more ammonium compounds of which the ammonium cation has the formula (I): [R1R2NR3R4+(I) and further comprising one or more sources for Y02 and one or more sources for X2O3; (2) crystallizing the mixture provided in step ( 1 ); wherein Y is a tetravalent element, and X is a trivalent element, and wherein the ammonium compounds are preferably derivatized or underivatized N,N-dimethylpyrrolidinium compounds, Nu,Nu-dimethylpiperidinium compounds, Nu,Nu-dimethylhexahydroazepinium compounds, and mixtures thereof, and wherein the molar ratio of ammonium cation having the formula (I) to Y in the mixture provided in step (1) and crystallized in step (2) is equal to or greater than 0.25.

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