32.
    发明专利
    未知

    公开(公告)号:DE3868385D1

    公开(公告)日:1992-03-26

    申请号:DE3868385

    申请日:1988-11-15

    Applicant: DEGUSSA

    Abstract: Catalyst (I) for selective redn. of NOx with NH3 consists of an intimate mixt. of oxides of at least 3 metals, comprising (A) Ti, (B1)W and (B2) V, Fe, Nb and/or Mo, with an atomic ratio of the metals (A):(B) of 1:0.001-1, pref. 1:0.003-0.3. The novel features are : 1) (A) is a finely-divided oxide obtd. by flame hydrolysis of TiCl4, with the following properties: BET surface area=50 +- 15 m2/g; average prim. particle size=30 nm; tamped density=ca. 150 g/l (DIN 53194 or ISO 787/XI; drying loss=1.5 (wt.)% (2 h at 105 deg.C; DIN 55921, ISO 787/II or ASTM D 280-33); calcination loss= 2% (2 h at 1000 deg.C after drying 2 h at 105 deg.C; DIN 55921, ISO 787/II or ASTM D 1208-65); pH=3-4 (in 4% aq. dispersion; DIN 53200, ISO 787/IX or ASTM D 1208-65); X-ray structure mainly anatase; isoelectric point at pH 6.6; density 3.8 g/cc; and compsn. 0.3% Al2O3, 99.5% TiO2, 0.2% SiO2, 0.01% Fe2O3 and 0.3% HCl (after 2 h at 1000 deq.C); and 2) (I) is prepd. by impregnating this TiO2 with solns. of salts of the metals of gp. (B), drying and calcination at 100-650, pref. 300-600 deg.C.

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