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    32.
    发明专利
    未知

    公开(公告)号：DE4409140A1

    公开(公告)日：1995-09-21

    申请号：DE4409140

    申请日：1994-03-17

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DR ,  WIELAND STEFAN DR

    IPC: B01J43/00 ,  C08G77/48 ,  C08G77/54 ,  C08L83/14 ,  C08G77/50 ,  C08G79/00 ,  C08L83/16 ,  C08J3/05 ,  B01J41/12 ,  B01D15/04 ,  C02F1/28

    Abstract: Aq. alkali solns. of Si-contg. ion-exchangers contg. units of formula (I) are new. Also claimed is the prepn. of such solns. by (i) converting crosslinked (I) to the OH form using a 0.01-1 M aq. alkali hydroxide soln.; (ii) washing the prod. to make it neutral and free of X ions; and (iii) treating it in water at 40-100 degrees C with a basic hydroxide to dissolve it. R and R = -R -Si-(O)3 with N being connected via R with the Si atom and the 3 free valencies of O being partly or fully satisfied by H or an alkali metal ion; R = 1-10 C alkylene, 5-8 C cycloalkylene, -(CH2)n.cyclohexylene.(CH2)m-, or -(CH2)n.phenylene.(CH2)m-; n = 1-6 (no. of N-attached methylene gps.); m = 0-6; R = as per R and R or H, 1-20 C alkyl or 5-8 C cycloalkyl; R = H, 1-20 C alkyl or 5-8 C cycloalkyl; and X = a 1-3 valent anion.

    33.
    发明专利
    未知

    公开(公告)号：DK0415079T5

    公开(公告)日：1995-08-28

    申请号：DK90114313

    申请日：1990-07-26

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DR ,  WIELAND STEFAN DR

    IPC: B01D15/00 ,  B01J20/22 ,  B01J20/26 ,  C02F1/62 ,  C08G77/22 ,  C08G77/26 ,  C08G77/28 ,  C08G77/48 ,  C08G77/54 ,  C08G77/58 ,  C08J3/12

    Abstract: The invention relates to an organosiloxane copolycondensate comprising where R - R = in which R is C1-C10-alkylene, C5-C8-cycloalkylene or which is bonded directly to N or X, where X = NH-, N-CH3, N-C2H5, -S-, -S2-, -S3-, -S4-, P-C6H5, where R" is H or C1-C5-alkyl, which has optionally been crosslinked by means of Si-, Ti-, Zr- and/or Al-containing crosslinking agents, in the form of spherical particles having a diameter of from 0.01 to 3.0 mm, a specific surface area of from 0 to 1000 m /g, a specific pore volume of from 0 to 6.0 ml/g and a bulk density of from 50 to 1000 g/l. The invention furthermore relates to various preparation processes for the shaped copolycondensates, and to the use of certain compositions in each case for removing metals from solutions or for adsorption of gaseous organic compounds and/or steam.

    34.
    发明专利
    未知

    公开(公告)号：ES2059923T3

    公开(公告)日：1994-11-16

    申请号：ES90114426

    申请日：1990-07-27

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DR ,  WIELAND STEFAN DR

    IPC: C08G77/28 ,  B01J20/22 ,  B01J20/26 ,  C02F1/62 ,  C02F5/00 ,  C02F5/08 ,  C02F5/10 ,  C08G77/22 ,  C08G77/26 ,  C08G77/48 ,  C08G77/54 ,  C08G77/58 ,  C08J3/12

    Abstract: Die Erfindung betrifft gegebenenfalls mittels Si-, Ti-, Zr- und/oder Al-haltigen Vernetzern vernetztes Organosiloxanamin-Copolykondensat aus Einheiten R = direkt an N bzw. an X gebundenes Alkylen mit C1-C10, Cycloalkylen mit C5-C8 oder X = -NH2, -NH-(CH2)2-NH2, -N(CH3)2, -N(C2H5)2 -NH-(CH2)2-NH-(CH2)2-NH2, -Cl, -Br, -J, -SH, -P(C6H5)2, wobei R sec = H oder Alkyl mit C1-C3, in Form kugelförmiger Teilchen mit einem Durchmesser von 0,01 bis 3,0 mm, einer spezifischen Oberfläche von 0 bis 1000 m /g, einem spezifischen Porenvolumen von 0 bis 6,0 ml/g sowie einer Schüttdichte von 50 bis 1000 g/l. Sie betrifft weiterhin diverse Herstellungsverfahren für die geformten Copolykondensate sowie eine Verwendung jeweils bestimmter Zusammensetzungen zur Entfernung von Metallen aus Lösungen bzw. zur Adsorption von gasförmigen organischen Verbindungen und/oder von Wasserdampf.

    35.
    发明专利
    未知

    公开(公告)号：ES2056673T3

    公开(公告)日：1994-10-01

    申请号：ES92104379

    申请日：1992-03-13

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DR ,  WIELAND STEFAN DR

    IPC: B01J31/12 ,  B01J31/06 ,  B01J31/16 ,  B01J31/18 ,  C08G77/398 ,  C08G77/48 ,  C08G77/54 ,  C08G77/58 ,  C08K3/10 ,  C08L83/04 ,  C08L83/08

    Abstract: The invention relates to shaped organosiloxanamine copolycondensates which contain Pd, Pt, Ru and/or Rh and optionally also promoters and/or moderators. The shaped copolycondensate, which is used as a support for metal, comprises units and units and/or Y-R units. R to R are a group in which R is an N-, X- or Y- bonded radical (for example an alkylene radical), and R is R -SiO3/2, H, CH3, C2H5 or C3H7. X is a divalent radical, such as -S-, -S2- to -S4-, -HN-CS-NH-, and Y is a monovalent radical, such as -CN-, -SCN, -SH, -S-CH3, -NH2, or -NH-(CH2)2-NH2. The support substance may have been crosslinked by means of Si-, Ti-, Zr- or Al-containing crosslinking agents. The metal-containing product has a spherical shape and is defined by means of the parameters sphere diameter, specific surface area, pore volume and bulk density. The invention furthermore relates to a preparation process, which can be carried out in a number of variants, and for the use of the metal-containing product as a catalyst for hydrogenation and oxidation reactions.

    40.
    发明专利
    未知

    公开(公告)号：ES2105795T3

    公开(公告)日：1997-10-16

    申请号：ES95103449

    申请日：1995-03-10

    Applicant: DEGUSSA

    Inventor： PANSTER PETER DR ,  WIELAND STEFAN DR ,  GOBEL THOMAS DR ,  BRANDES CHRISTIAN ,  WERNER UTE ,  ZINSMEISTER KLAUS DR

    IPC: C04B41/49 ,  C04B41/64 ,  C09D183/04

    Abstract: Method for the undercoating or impregnation of natural or synthetic mineral building materials with aq. suspensions or solns. that contain 0.1-70 (10-30) wt.% at least one silicon-contg. ion exchange material of formula (I) or an oligomer thereof, w.r.t. soln. or suspension. The treatment method is a single- or multi-stage process and is opt. combined with a treatment process with organic or aq. solns. or emulsions contg. hydrolysable sil(ox)anes. Ä(YO)3Si(CH2)xÜnEX (I) x = 1-12; n = 1-3, depending on E; Y = H, Na, K, Mg, Ca or Ba; E = cation or anion exchanging gp.; and X = H or alkali(ne earth) metal ion, or OH or an anion.

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