34.
    发明专利
    未知

    公开(公告)号:DE2448478A1

    公开(公告)日:1975-04-24

    申请号:DE2448478

    申请日:1974-10-11

    Applicant: IBM

    Abstract: A process for the preparation of a homojunction in a semiconductor substrate, e.g., a p-n junction, during growth of a heterojunction between the substrate and a second semiconductor consisting of either gallium nitride or aluminum nitride where aluminum atoms from the aluminum nitride or gallium atoms from the gallium nitride diffuse into the substrate in a region of the substrate adjacent the aluminum nitride or gallium nitride to form the homojunction.

    SEMICONDUCTOR DEVICE
    36.
    发明专利

    公开(公告)号:GB1300528A

    公开(公告)日:1972-12-20

    申请号:GB1362471

    申请日:1971-05-07

    Applicant: IBM

    Abstract: 1300528 Semi-conductor devices INTERNATIONAL BUSINESS MACHINES CORP 7 May 1971 [17 June 1970] 13624/71 Heading H1K A " non-volatile "bi-stable switching element comprises a heterojunction diode one of the layers of which is of a material having a high density of defects (excluding normal dopants). This device maintains its impedance state when the supply is removed. In the characteristic shown in Fig. 2 line 3 represents a high-impedance state and line 5 a low-impedance state. Initially the device is in the high-impedance state which can be maintained indefinitely, the traps being filled, but when a reverse bias greater than V RB is applied the traps are emptied and the device switches along path 4 to the low-impedance state 5. While reverse bias is applied this state can be maintained and even at zero bias the lowimpedance state persists for several weeks so that on re-application of reverse bias the lowimpedance characteristic is exhibited. If the device is forward biased to a current I FS it switches along path 6 back to the highimpedance state 3. If the layer containing the defects is lightly doped the forward and reverse characteristics are symmetrical about the origin as in Fig. 2 but if the deposited layer is more heavily doped the high-impedance curve follows a normal diode characteristic in the forward direction, Fig. 3 (not shown). The device may be produced by depositing N-type GaP on a P-type Si substrate by a transport reaction method. The deposited layer may be doped with Sn, Te or Se by doping the source material, placing the doping element on the heater next to the source material, or by adding a compound of the dopant to the gas. Oxide film on the Si substrate may be removed before the growth step by heating in hydrogen or may be prevented from forming by the use of a film of iodine. The resulting wafer may be contacted using photolithographic techniques or may be dried and contacts alloyed to the surfaces. The contact to the GaP layer may be In, Sn or Au- Sn and the contact to the Si layer may be of Al or In or this may be mounted on a header. If the correct characteristic is not obtained the device may be formed by applying a number of large reverse voltage pulses. Various alternatives are mentioned including P-type GaP on N-type Si and N-type ZnSe on P-type Ge. The substrate may be monocrystalline, polyorystalline or amorphous, may be III-V compound such as GaP, GaAs, or GaAsP, or Group IV material such as SiC. The layer may be deposited on a specific crystallographic plane to produce the required density of defects (dislocations and stacking faults) but traps may be provided by introducing a deep level impurity such as Cu, Cr or Fe into the deposited layer.

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