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公开(公告)号：DE4217839B4
公开(公告)日：2004-07-01
申请号：DE4217839
申请日：1992-05-29
Applicant: KAO CORP
Inventor： HATTORI YASUYUKI , TAMURA HIROYUKI , KADOWAKI HIDETOSHI , TSUKADA KIYOSHI
IPC: B01J23/755 , C07C27/26 , C07C29/149 , C07C67/60 , C07C69/587 , C11B3/02 , C07C67/48 , B01J23/70
Abstract: A process for producing desulfurized fats and oils or fatty acid esters, which are highly suitable as a starting material for producing alcohols via hydrogenation, at a high yield is disclosed. Desulfurized fats and oils or fatty acid esters are obtained by contacting fats and oils or fatty acid esters with a catalyst represented by the following formula (I) under a hydrogen atmosphere or a mixture of hydrogen with an inert gas: Ni.CuxOy(I) wherein x represents an atomic ratio of Cu determined by referring Ni as 1 and a value of from 0.02 to 8; and y is an atomic ratio of oxygen satisfying the valence requirements of Ni and Cu. A process for producing alcohols using the desulfurized fats and oils or fatty acid esters is also disclosed. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.
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公开(公告)号：MY115471A
公开(公告)日：2003-06-30
申请号：MYPI9703903
申请日：1997-08-26
Applicant: KAO CORP
Inventor： TAHARA HIDEO , MITSUDA YOSHINORI , TAMURA HIROYUKI , HATTORI YASUYUKI
Abstract: A PROCESS FOR PRODUCING AN UNSATURATED ALCOHOL WHEREIN THE CATALYTIC ACTIVITY AND THE CAPABILITY OF MAINTAINING DOUBLE BOND ARE SUSTAINED FOR A LONG TIME AND SIDE-REACTIONS ARE SUPPRESSED.AN UNSATURATED ALCOHOL IS OBTAINED BY HYDROGENATING AN ALKYL OR ALKENYL ESTER OF AN UNSATURATED FATTY ACID OR A TRIGLYCERIDE HAVING A LONG-CHAIN ALIPHATIC UNSATURATED HYDROCARBON GROUP IN THE PRESENCE OF A CATALYTIC COMPOSITION WHICH IS A COMPOSITE METAL OXIDE CONSISTING OF (A) ZINC OXIDE AND (B) OXIDE (S) OF AT LEAST ONE METAL SELECTED FROM THE GROUP CONSISTING OF THE ELEMENTS OF THE GROUP 3A IN THE PERIODIC TABLE AND HAVING A WEIGHT RATIO OF (A) / (B) OF FROM 1/0.01 TO 1/1.2.
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公开(公告)号：DE69712811T2
公开(公告)日：2002-11-07
申请号：DE69712811
申请日：1997-02-13
Applicant: KAO CORP
Inventor： KADONO YASUO , HATTORI YASUYUKI , HORIO MASAMITSU , NAKAMURA FUMIHIKO
IPC: B01J23/00 , B01J23/745 , B01J23/80 , C07C29/149
Abstract: The present invention provides a hydrogenation catalyst precursor which does not bring about a problem of environmental pollution involved in copper-chromium catalysts and has a high activity, a high durability and a high selectivity as compared with those of conventional copper-iron-aluminum catalysts, a hydrogenation catalyst obtained by reducing the same, and a production process for alcohols using the above hydrogenation catalyst. The hydrogenation catalyst precursor described above comprises copper, iron and aluminum and containing as a principal component a compound oxide of copper, iron and aluminum in which an atomic ratio Cu : Fe : Al is 1 : (0.02 to 0.4) : (1.0 to 4.0) and which has a copper-aluminum spinel structure.
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公开(公告)号：DE10030413A1
公开(公告)日：2001-03-01
申请号：DE10030413
申请日：2000-06-21
Applicant: KAO CORP
Inventor： MIMURA TAKU , KAITA JUN , FUKUOKA NORIAKI , HATTORI YASUYUKI
Abstract: A solid acid catalyst with a with very high activity and high stability in a variety of organic reaction systems. A solid acid catalyst (I) comprising a structure (A) resulting from the removal of a hydrogen atom from at least one hydroxy group in an inorganic phosphorus acid, a structure (B) resulting from the removal of a hydrogen atom from at least one OH group in an organic phosphorus acid of formulae R -P(=O)(R )-OH (1) or R -P(R )-OH (2), and (C) at least one aluminum, gallium and/or iron atom. R , R = R, OR, OH or H, with the proviso that at least one of these groups is R or OR; R = 1-22C organic group Independent claims are also included for: (i) production of esters from starting esters or acids and alcohols using catalyst (I); (ii) production of ketals or acetals from ketones or aldehydes and alcohols using catalyst (I); and (iii) production of (I).
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公开(公告)号：ID26323A
公开(公告)日：2000-12-14
申请号：ID20000477
申请日：2000-06-08
Applicant: KAO CORP
Inventor： KAITA JUN , MIMURA TAKU , FUKUOKA NORIAKI , HATTORI YASUYUKI
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Patent Agency Ranking
公开(公告)号：DE69416955T2
公开(公告)日：1999-08-05
申请号：DE69416955
申请日：1994-12-08
Applicant: KAO CORP
Inventor： TSUKADA KIYOSHI , HATTORI YASUYUKI , MIMURA TAKU
IPC: B01J23/72 , B01J23/745 , B01J23/80 , B01J23/86 , B01J37/18 , C07B61/00 , C07C29/149 , C07C31/02 , B01J37/16
Abstract: A copper-containing hydrogenation reaction catalyst is prepared by reducing a precursor of a copper-containing catalyst usable in hydrogenation reaction with hydrogen gas or a mixture of hydrogen and an inert gas by liquid phase reduction in a stream of a solvent in the temperature range of from 50 to 140 DEG C. An alcohol is produced using the catalyst thus obtained in a fixed bed continuous reaction system.
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公开(公告)号：DE69414240T2
公开(公告)日：1999-04-22
申请号：DE69414240
申请日：1994-01-20
Applicant: KAO CORP
Inventor： TSUKADA KIYOSHI , HATTORI YASUYUKI , MIMURA TAKU , TABATA OSAMU , NISHIGAKI FUTOSHI
IPC: B01J23/72 , B01J23/60 , B01J23/70 , B01J23/745 , B01J23/80 , B01J23/86 , B01J37/00 , B01J37/16 , B01J37/18 , C07B61/00 , C07C29/149 , C07C31/125
Abstract: PCT No. PCT/JP94/00077 Sec. 371 Date Jun. 6, 1995 Sec. 102(e) Date Jun. 6, 1995 PCT Filed Jan. 20, 1994 PCT Pub. No. WO95/19844 PCT Pub. Date Jul. 27, 1995A method for preparing a copper-containing hydrogenation reaction catalyst includes the step of reducing a formed precursor of a copper-containing hydrogenation reaction catalyst with hydrogen gas or a mixture of hydrogen and inert gas by liquid phase reduction in a stream of a solvent. The reductive activation is carried out by the two steps of performing the first stage of liquid phase reduction by which the catalyst precursor is activated in the temperature range of from 20 DEG to 140 DEG C. so that at least 10% by weight of the copper oxide contained in the catalyst precursor can be reduced by the time when the temperature passes 140 DEG C., and then performing the second stage of liquid phase reduction by which the catalyst precursor is further activated in the temperature range of from 140 DEG to 250 DEG C. The catalyst thus obtained has markedly improved catalytic activity and selectivity. An alcohol of high quality can be obtained at a high productivity using the catalyst in a fixed bed continuous reaction system.
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公开(公告)号：DE69408614D1
公开(公告)日：1998-04-02
申请号：DE69408614
申请日：1994-10-04
Applicant: KAO CORP
Inventor： HATTORI YASUYUKI , TSUKADA KIYOSHI
IPC: B01J23/76 , B01J21/06 , B01J23/78 , B01J23/80 , B01J29/76 , B01J37/02 , C07B61/00 , C07C29/149 , C07C31/02 , C07C33/02 , C07C35/02 , C07C37/01 , C07C39/02 , B01J23/72
Abstract: A hydrogenation reaction catalyst precursor of the present invention comprises a catalyst carrier (A) and a metal oxide composition (B) carried on or mixed with the catalyst carrier (A) at a weight ratio of (B)/(A) = 15/85 to 65/35; the catalyst carrier (A) comprising a carrier base material of silica, alumina silica-alumina, magnesia, zirconia, zeolite or diatomaceous earth, and a coating of titanium oxide and/or titanium hydroxide, the metal oxide composition (B) comprising copper oxide, zinc oxide, and at least one oxide of a metal selected from the group consisting of an element of group IIa of the periodic table, an element of group IIIb of the table, a lantanide element, and an actinide element at a weight ratio of 100/(0 to 25)/(0 to 25). A hydrogenation reaction catalyst with a high catalytic activity and a high reaction selectivity is obtained by reduction of the hydrogenation reaction catalyst precursor. By the use of the hydrogenation reaction catalyst of the present invention, a high quality alcohol can be produced at a high yield and with a high selectivity even at a low reaction temperature and a low hydrogen pressure.
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公开(公告)号：ID18253A
公开(公告)日：1998-03-19
申请号：ID973076
申请日：1997-09-04
Applicant: KAO CORP
Inventor： TAMURA HIROYUKI , TAHARA HIDEO , MITSUDA YOSHINORI , HATTORI YASUYUKI
Abstract: A process for producing an unsaturated alcohol wherein the catalytic activity and the capability of maintaining double bond are sustained for a long time and side-reactions are suppressed. An unsaturated alcohol is obtained by hydrogenating an alkyl or alkenyl ester of an unsaturated fatty acid or a triglyceride having a long-chain aliphatic unsaturated hydrocarbon group in the presence of a catalytic composition which is a composite metal oxide consisting of (a) zinc oxide and (b) oxide(s) of at least one metal selected from the group consisting of the elements of the group 3A in the periodic table and having a weight ratio of (a)/(b) of from 1/0.01 to 1/1.2.
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公开(公告)号：ID15942A
公开(公告)日：1997-08-21
申请号：ID970429
申请日：1997-02-14
Applicant: KAO CORP
Inventor： KADONO YASUO , HATTORI YASUYUKI , HORIO MASAMITSU , NAKAMURA FUMIHIKO
IPC: B01J23/00 , B01J23/745 , B01J23/80 , C07C29/149 , B01J23/72
Abstract: The present invention provides a hydrogenation catalyst precursor which does not bring about a problem of environmental pollution involved in copper-chromium catalysts and has a high activity, a high durability and a high selectivity as compared with those of conventional copper-iron-aluminum catalysts, a hydrogenation catalyst obtained by reducing the same, and a production process for alcohols using the above hydrogenation catalyst. The hydrogenation catalyst precursor described above comprises copper, iron and aluminum and containing as a principal component a compound oxide of copper, iron and aluminum in which an atomic ratio Cu : Fe : Al is 1 : (0.02 to 0.4) : (1.0 to 4.0) and which has a copper-aluminum spinel structure.
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