-
公开(公告)号:WO2008099961A1
公开(公告)日:2008-08-21
申请号:PCT/JP2008052905
申请日:2008-02-14
Applicant: KAO CORP , DANJO HIROSHI , FUKUOKA NORIAKI , MIMURA TAKU
Inventor: DANJO HIROSHI , FUKUOKA NORIAKI , MIMURA TAKU
IPC: B01J23/75 , B01J23/76 , B01J37/12 , B01J37/18 , C07B61/00 , C07C29/149 , C07C31/125
CPC classification number: B01J23/75 , B01J21/04 , B01J21/06 , B01J21/066 , B01J21/08 , B01J23/83 , B01J23/8472 , B01J23/882 , B01J23/8913 , B01J23/894 , B01J23/8993 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/031 , B01J37/14 , B01J37/18 , C07C29/149 , C07C31/125
Abstract: Disclosed is a catalyst for producing an alcohol by hydrogenating a carboxylic acid, which contains Co metal as an essential ingredient, while containing one or more elements selected from the group consisting of Zr, Y, La, Ce, Si, Al, Sc, V and Mo as first promoter components. In this catalyst for alcohol production, the crystal phase of Co metal contains not less than 20% of a cubic phase. Also disclosed are a method for producing such a catalyst, and a method for producing an alcohol wherein a carboxylic acid is used as a raw material and hydrogenation is performed by using the catalyst.
Abstract translation: 公开了含有选自由Zr,Y,La,Ce,Si,Al,Sc,V组成的组中的一种或多种元素的含有Co金属作为必要成分的羧酸的醇的制造用催化剂 和Mo作为第一启动子组分。 在用于醇生产的催化剂中,Co金属的结晶相含有不少于20%的立方相。 还公开了这样的催化剂的制造方法以及使用羧酸作为原料的醇的制造方法,使用该催化剂进行氢化。
-
公开(公告)号:DE4207787A1
公开(公告)日:1992-10-15
申请号:DE4207787
申请日:1992-03-11
Applicant: KAO CORP
Inventor: TAMURA HIROYUKI , HATTORI YASUYUKI , HASHIBA KUNIZO , TABATA OSAMU , TSUKADA KIYOSHI , FUKUOKA NORIAKI
IPC: C07C29/149 , C11B3/02
Abstract: A process for producing desulfurized fats and oils or fatty acid esters is disclosed, which comprises treating fats and oils or fatty acid esters under hydrogen or a mixture of hydrogen and an inert gas atmosphere at a pressure of from 0.1 to 500 kg/cm2 in the absolute pressure at a temperature of from 100 DEG to 350 DEG C. in the presence of a catalyst of the following formula (I): CuxXxxYyxOz(I) wherein all symbols are defined in the disclosure. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.
-
公开(公告)号:DE10033951B4
公开(公告)日:2013-07-25
申请号:DE10033951
申请日:2000-07-13
Applicant: KAO CORP
Inventor: MIMURA TAKU , KAITA JUN , FUKUOKA NORIAKI , HATTORI YASUYUKI
Abstract: Verwendung eines heterogenen Katalysators, der Aluminiumorthophosphat umfasst und Poren, deren Durchmesser im Bereich von 6 bis 100 nm liegen, in einem Porenvolumen von 0,46 ml/g oder mehr, und einen Säurewert von 0,40 mmol/g oder mehr aufweist, für die Veresterung.
-
公开(公告)号:DE60117908T2
公开(公告)日:2006-12-21
申请号:DE60117908
申请日:2001-11-08
Applicant: KAO CORP
Inventor: TATSUMI NOBUHIRO , KATAYAMA TAKANOBU , TABATA OSAMU , MIMURA TAKU , FUKUOKA NORIAKI , YAMAMOTO KATSUTOSHI
-
公开(公告)号:EP2116300A4
公开(公告)日:2013-11-13
申请号:EP08711694
申请日:2008-02-14
Applicant: KAO CORP
Inventor: DANJO HIROSHI , FUKUOKA NORIAKI , MIMURA TAKU
IPC: B01J23/75 , B01J23/76 , B01J37/12 , B01J37/18 , C07B61/00 , C07C29/149 , C07C31/125
CPC classification number: B01J23/75 , B01J21/04 , B01J21/06 , B01J21/066 , B01J21/08 , B01J23/83 , B01J23/8472 , B01J23/882 , B01J23/8913 , B01J23/894 , B01J23/8993 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/031 , B01J37/14 , B01J37/18 , C07C29/149 , C07C31/125
Abstract: The present invention provides a catalyst for producing alcohols from carboxylic acids by hydrogenation, containing Co metal as an essential component and one or more elements selected from Zr, Y, La, Ce, Si, Al, Sc, V and Mo as a first co-catalyst component, and having 20% or more of cubic phase in the crystal phase of the Co metal, the method for producing the catalyst, and the method for producing an alcohol from a carboxylic acid as a raw material by hydrogenation using the catalyst.
-
公开(公告)号:MY126054A
公开(公告)日:2006-09-29
申请号:MYPI20002753
申请日:2000-06-19
Applicant: KAO CORP
Inventor: MIMURA TAKU , KAITA JUN , FUKUOKA NORIAKI , HATTORI YASUYUKI
Abstract: THE PRESENT INVENTION PROVIDES A SOLID ACID CATALYST DEVELOPING HIGH ACTIVITY AND EXHIBITING HIGH DURABILITY IN VARIOUS ORGANIC REACTIONS. THAT IS, THE PRESENT INVENTION PROVIDES A SOLID ACID CATALYST HAVING THE STRUCTURE (A) IN WHICH A HYDROGEN ATOM IS ELIMINATED FROM AT LEAST ONE OF OH GROUPS CONTAINED IN AN INORGANIC PHOSPHORUS ACID, THE STRUCTURE (B) IN WHICH A HYDROGEN ATOM IS ELIMINATED FROM AT LEAST ONE OF OH GROUPS CONTAINED IN AN ORGANIC PHOSPHORUS ACID REPRESENTED BY THE FORMULA (1) OR (2) AND AT LEAST ONE METAL ATOM (C) SELECTED FROM ALUMINUM, GALLIUM AND IRON AND A METHOD FOR PRODUCING AN ESTER, A KETAL OR AN ACETAL BY USING THE SOLID ACID CATALYST; WHEREIN EACH OF -R1 AND -R² IS SELECTED FROM -R, -OR, -OH AND -H IN WHICH AT LEAST ONE OF -R1 AND -R² IS -R OR -OR, GIVEN THAT -R IS AN ORGANIC GROUP HAVING 1-22 CARBON ATOMS.
-
公开(公告)号:MY122528A
公开(公告)日:2006-04-29
申请号:MYPI20002523
申请日:2000-06-06
Applicant: KAO CORP
Inventor: KAITA JUN , MIMURA TAKU , FUKUOKA NORIAKI , HATTORI YASUYUKI
IPC: C11C1/00 , B01J27/16 , B01J27/18 , B01J27/185 , C07B41/12 , C07B61/00 , C07C67/02 , C07C67/03 , C07C67/10 , C07C69/24 , C11C3/00
Abstract: THE PRESENT INVENTION PROVIDES A HETEROGENEOUS CATALYST WHICH IS HIGHLY ACTIVE, EXCELLENT IN SELECTIVITY AND FREE FROM ELUTION OF ITS CATALYST-COMPONENTS DURING REACTION AND WHICH HAS LONG LIFETIME. THAT IS, A PHOSPHATE OF A METAL SELECTED FROM THE GROUP CONSISTING OF ALUMINIUM, GALLIUM AND IRON IS USED AS THE CATALYST FOR TRANSESTERIFICATION OF THE PRESENT INVENTION.
-
公开(公告)号:DE4217044B4
公开(公告)日:2006-04-13
申请号:DE4217044
申请日:1992-05-22
Applicant: KAO CORP
Inventor: MORI ATSUHITO , HATTORI YASUYUKI , TSUKADA KIYOSHI , FUKUOKA NORIAKI
IPC: B01J23/80 , B01J21/06 , B01J23/78 , B01J23/83 , B01J23/85 , B01J23/887 , B01J37/02 , C07C29/149
Abstract: A process for producing a hydrogenation reaction catalyst precursor is disclosed, including the steps of: (i) coating the outer surface of at least one of a first titanium oxide and a first titanium hydroxide having an outer surface area of at least 15 m2/g with at least one of a second titanium oxide and a second titanium hydroxide formed by hydrolyzing at least one of a titanium alkoxide represented by Formula (I) and a titanium alkoxo acid represented by Formula (II) to prepare a catalyst carrier (A); Ti(OR)4(I) wherein R represents an alkyl group having from 1 to 18 carbon atoms or an aryl group, H2[Ti(OR)6](II) wherein R has the same meaning as above; (ii) applying a metal oxide composition (B) onto the catalyst carrier (A) obtained in step (i), or mixing the metal oxide composition (B) with the catalyst carrier (A) to obtain a hydrogenation reaction catalyst precursor. Also, a process for producing an alcohol is described, including catalytically reducing an organic carboxylic acid ester with hydrogen in the presence of a catalyst obtained by reducing the hydrogenation reaction catalyst precursor produced by the process described above.
-
公开(公告)号:PH25454A
公开(公告)日:1991-07-01
申请号:PH38734
申请日:1989-06-02
Applicant: KAO CORP
Inventor: HATTORI YASUYUKI , FUKUOKA NORIAKI , TAMURA SHIGERU , HASHIBA KUNIZO , TSUKADA KIYOSHI , MISONO MAKOTO
IPC: B01J23/80 , C07B61/00 , C07C27/00 , C07C29/136 , B01J23/72 , C07C29/149 , C07C67/00 , C07C27/08 , B01J21/06
Abstract: An alcohol is effective produced by catalytically reducing an organic carboxylic acid ester with hydrogen in the presence of a catalyst obtained by reducing a catalyst precursor comprising (A) copper oxide and (B) titanium oxide and/or titanium hydroxide at a weight ratio of (A) to (B) in the range between 15/85 and 65/35. The component (A) may be alternatively a composite metal oxide comprises copper oxide and up to 20 wt. % of zinc oxide.
-
公开(公告)号:DE10030413B4
公开(公告)日:2016-04-07
申请号:DE10030413
申请日:2000-06-21
Applicant: KAO CORP
Inventor: MIMURA TAKU , KAITA JUN , FUKUOKA NORIAKI , HATTORI YASUYUKI
Abstract: Die Erfindung stellt eine Verwendung eines festen sauren Katalysators bereit, der eine hohe Aktivität entwickelt und hohe Haltbarkeit in verschiedenen organischen Reaktionen zeigt. Das heisst, die Erfindung stellt eine Verwendung eines eines festen sauren Katalysators mit der Struktur (A), in der ein Wasserstoffatom aus mindestens einer OH-Gruppe, die in einer anorganischen Säure des Phosphors enthalten ist, entfernt wird, der Struktur (B), in der ein Wasserstoffatom aus mindestens einer OH-Gruppe, die in einer durch die Formel (1) oder (2) dargestellten organischen Säure des Phosphors enthalten ist, entfernt wird, und mindestens einem Metallatom (C), ausgewählt aus Aluminium, Gallium und Eisen, und ein Verfahren zur Herstellung eines Esters, eines Ketals oder eines Acetals unter Verwendung des festen sauren Katalysators bereit;wobei R1 und R2 jeweils aus -R, -OR, -OH und -H ausgewählt werden, wobei zumindest ein Vertreter von R1 und R2 -R oder -OR ist, wobei -R eine organische Gruppe mit 1 bis 22 Kohlenstoffatomen darstellt.
-
-
-
-
-
-
-
-
-