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公开(公告)号:ES2086751T3
公开(公告)日:1996-07-01
申请号:ES92914025
申请日:1992-04-15
Applicant: LUBRIZOL CORP
Inventor: KOLP CHRISTOPHER JAY , DALY DANIEL TIMOTHY , HUANG NAI ZHONG , KOCH FREDERICK WILLIAM , JOLLEY SCOTT TED , STOLDT STEPHEN HOWARD
IPC: C07F1/08 , C10L20060101 , C10L1/14 , C10L1/18 , C10L1/188 , C10L1/19 , C10L1/22 , C10L1/23 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/06 , C10L10/12 , F02B3/06
Abstract: This invention relates to copper-containing organometallic complexes, and to concentrates and diesel fuels containing said complexes. The diesel fuels are useful with diesel engines equipped with exhaust system particulate traps. The copper-containing organometallic complex is used for lowering the ignition temperature of exhaust particles collected in the trap. The copper-containing organometallic complex is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a copper-containing metal reactant capable of forming a complex with the organic compound (i). The functional groups are =X, -XR, -NR., -NO., =NR, =NXR, =N-R*-XR, -CN, -N=NR or -N=CR.; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10). The copper can be combined with one or more metals selected from the group consisting Na, K, Mg, Ca, Sr, Ba, V, Cr, Mo, Fe, Co, Zn, B, Pb, Sb, Ti, Mn and Zr. This invention is also directed to methods of operating a diesel engine equipped with an exhaust system particulate trap using the foregoing diesel fuel.
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公开(公告)号:AT138680T
公开(公告)日:1996-06-15
申请号:AT92913642
申请日:1992-04-15
Applicant: LUBRIZOL CORP
Inventor: HUANG NAI ZHONG , ADAMS PAUL ERNEST , DALY DANIEL TIMOTHY , JOLLEY SCOTT TED , KOCH FREDERICK WILLIAM , KOLP CHRISTOPHER JAY , STOLDT STEPHEN HOWARD , WALSH REED HUBER , DENIS RICHARD ASCOT
IPC: F02M25/00 , C10L1/08 , C10L1/14 , C10L1/18 , C10L1/188 , C10L1/19 , C10L1/22 , C10L1/23 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/00 , C10L10/06 , C10L10/12 , F02B3/06
Abstract: This invention relates to combinations of (A) organometallic complexes and (B) antioxidants. These combinations can be used in diesel fuels for operating diesel engines equipped with exhaust system particulate traps. The combination of (A) and (B) is useful in lowering the ignition temperature of exhaust particles collected in the trap. The organometallic complex (A) is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a metal reactant capable of forming a complex with the organic compound (i), the metal being any metal capable of reducing the ignition temperature of the exhaust particles. The functional groups include =X, -XR, -NR2, -NO2, =NR, =NXR, =N-R*-XR, -CN, -N=NR and -N=CR2; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10). Useful metals include Na, K, Mg, Ca, Sr, Ba, V, Cr, Fe, Co, Cu, Zn, Pb, Sb, and mixtures of two or more thereof. This invention is also directed to concentrates and diesel fuels, and to methods of operating a diesel engine equipped with an exhaust system particulate trap.
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33.
公开(公告)号:AU653424B2
公开(公告)日:1994-09-29
申请号:AU2168192
申请日:1992-04-15
Applicant: LUBRIZOL CORP
Inventor: HUANG NAI ZHONG , ADAMS PAUL ERNEST , DALY DANIEL TIMOTHY , JOLLEY SCOTT TED , KOCH FREDERICK WILLIAM , KOLP CHRISTOPHER JAY , STOLDT STEPHEN HOWARD , WALSH REED HUBER , DENIS RICHARD ASCOT
IPC: F02M25/00 , C10L1/08 , C10L1/14 , C10L1/18 , C10L1/188 , C10L1/19 , C10L1/22 , C10L1/23 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/00 , C10L10/06 , C10L10/12 , F02B3/06
Abstract: This invention relates to combinations of (A) organometallic complexes and (B) antioxidants. These combinations can be used in diesel fuels for operating diesel engines equipped with exhaust system particulate traps. The combination of (A) and (B) is useful in lowering the ignition temperature of exhaust particles collected in the trap. The organometallic complex (A) is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a metal reactant capable of forming a complex with the organic compound (i), the metal being any metal capable of reducing the ignition temperature of the exhaust particles. The functional groups include =X, -XR, -NR2, -NO2, =NR, =NXR, =N-R*-XR, -CN, -N=NR and -N=CR2; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10). Useful metals include Na, K, Mg, Ca, Sr, Ba, V, Cr, Fe, Co, Cu, Zn, Pb, Sb, and mixtures of two or more thereof. This invention is also directed to concentrates and diesel fuels, and to methods of operating a diesel engine equipped with an exhaust system particulate trap.
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34.
公开(公告)号:ZA9308269B
公开(公告)日:1994-06-08
申请号:ZA9308269
申请日:1993-11-05
Applicant: LUBRIZOL CORP
Inventor: HUANG NAI ZHONG , KOLP CHRISTOPHER JAY , SGARLATA CHRISTOPHER RICHARD
IPC: C07F1/08 , C07F1/00 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/22 , C10L1/30 , C10L10/00 , C10L10/06 , F02B3/06 , C10L , C07F
CPC classification number: C10L10/06 , C07F1/005 , C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1883 , C10L1/198 , C10L1/2222 , C10L1/301 , F02B3/06
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公开(公告)号:MX9306641A
公开(公告)日:1994-05-31
申请号:MX9306641
申请日:1993-10-26
Applicant: LUBRIZOL CORP
Inventor: HUANG NAI ZHONG , KOLP CHRISTOPHER JAY , SGARLATA CHRISTOPHER RICHARD
IPC: C07F1/08 , C07F1/00 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/22 , C10L1/30 , C10L10/00 , C10L10/06 , F02B3/06
Abstract: This invention relates to copper-containing aromatic Mannich complexes, and to concentrates and diesel fuels containing said complexes. The diesel fuels are useful with diesel engines equipped with exhaust system particulate traps. The copper-containing aromatic Mannich complex is used for lowering the ignition temperature of exhaust particles collected in the trap. The copper-containing aromatic Mannich complex is obtainable by contacting either component (A) or component (B) with component (C); component (A) being at least one compound represented by the general formula wherein R is an alkyl group of 1 to about 6 carbon atoms, and R is a saturated or unsaturated aliphatic hydrocarbyl group of about 16 to about 20 carbon atoms; component (B) being a mixture of (B)(I) and (B)(II), component (B)(I) being at least one compound represented by the general formula wherein R is an alkyl group of about 9 to about 18 carbon atoms, R is an alkylene group of 1 to about 4 carbon atoms, and R is a saturated or unsaturated aliphatic hydrocarbyl group of about 16 to about 20 carbon atoms; and component (B)(II) is at least one compound represented by the formula wherein R and R are independently alkyl groups of about 9 to about 18 carbon atoms, and R is an alkylene group of 1 to about 4 carbon atoms; and component (C) is at least one copper reactant.d re
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36.
公开(公告)号:IL107485D0
公开(公告)日:1994-02-27
申请号:IL10748593
申请日:1993-11-04
Applicant: LUBRIZOL CORP
Inventor: HUANG NAI ZHONG , KOLP CHRISTOPHER JAY , SGARLATA CHRISTOPHER RICHARD
IPC: C07F1/08 , C07F1/00 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/22 , C10L1/30 , C10L10/00 , C10L10/06 , F02B3/06 , C10L
Abstract: This invention relates to copper-containing aromatic Mannich complexes, and to concentrates and diesel fuels containing said complexes. The diesel fuels are useful with diesel engines equipped with exhaust system particulate traps. The copper-containing aromatic Mannich complex is used for lowering the ignition temperature of exhaust particles collected in the trap. The copper-containing aromatic Mannich complex is obtainable by contacting either component (A) or component (B) with component (C); component (A) being at least one compound represented by the general formula wherein R is an alkyl group of 1 to about 6 carbon atoms, and R is a saturated or unsaturated aliphatic hydrocarbyl group of about 16 to about 20 carbon atoms; component (B) being a mixture of (B)(I) and (B)(II), component (B)(I) being at least one compound represented by the general formula wherein R is an alkyl group of about 9 to about 18 carbon atoms, R is an alkylene group of 1 to about 4 carbon atoms, and R is a saturated or unsaturated aliphatic hydrocarbyl group of about 16 to about 20 carbon atoms; and component (B)(II) is at least one compound represented by the formula wherein R and R are independently alkyl groups of about 9 to about 18 carbon atoms, and R is an alkylene group of 1 to about 4 carbon atoms; and component (C) is at least one copper reactant.d re
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公开(公告)号:HUT64101A
公开(公告)日:1993-11-29
申请号:HU9300059
申请日:1992-04-15
Applicant: LUBRIZOL CORP
Inventor: DALY DANIEL TIMOTHY , ADAMS PAUL ERNEST , HUANG NAI ZHONG , JOLLEY SCOTT TED , KOCH FREDERICK WILLIAMS , KOLP CHRISTOPHER JAY , STOLDT STEPHEN HOWARD , WALSH REED HUBER , DENIS RICHARD ASCOT , DISHONG DENNIS MICHAEL
IPC: C10L1/14 , C10L1/18 , C10L1/188 , C10L1/19 , C10L1/22 , C10L1/23 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/06 , C10L10/12 , F02B3/06
Abstract: This invention relates to low-sulfur diesel fuels which are useful with diesel engines equipped with exhaust system particulate traps. These fuels contain an effective mount of an organometallic complex to lower the ignition temperature of exhaust particles collected in the trap. The sulfur content of these diesel fuels is no more than about 0.1% by weight, preferably no more than about 0.05% by weight. The organometallic complex is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a metal reactant capable of forming a complex with the organic compound (i), the metal being any metal capable of reducing the ignition temperature of the exhaust particles. The functional groups include =X, -XR, -NR2, -NO2, =NR, =NXR, =N-R*-XR, -CN, -N=NR and -N=CR2; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10). Useful metals include Na, K, Mg, Ca, Sr, Ba, Ti, Zr, V, Cr, Mo, Mn, Fe, Co, Cu, Zn, B, Pb, Sb, and mixtures of two or more thereof. This invention is also directed to methods of operating a diesel engine equipped with an exhaust system particulate trap using the foregoing low-sulfur diesel fuels.
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38.
公开(公告)号:HUT64099A
公开(公告)日:1993-11-29
申请号:HU9300062
申请日:1992-04-15
Applicant: LUBRIZOL CORP
Inventor: DALY DANIEL TIMOTHY , ADAMS PAUL ERNEST , HUANG NAI ZHONG , JOLLEY SCOTT TED , KOCH FREDERICK WILLIAMS , KOLP CHRISTOPHER JAY , STOLDT STEPHEN HOWARD , WALSH REED HUBER , DENIS RICHARD ASCOT
IPC: C10L1/08 , C10L1/14 , F02M25/00 , C10L1/18 , C10L1/188 , C10L1/19 , C10L1/22 , C10L1/23 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/00 , C10L10/06 , C10L10/12 , F02B3/06
Abstract: This invention relates to combinations of (A) organometallic complexes and (B) antioxidants. These combinations can be used in diesel fuels for operating diesel engines equipped with exhaust system particulate traps. The combination of (A) and (B) is useful in lowering the ignition temperature of exhaust particles collected in the trap. The organometallic complex (A) is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a metal reactant capable of forming a complex with the organic compound (i), the metal being any metal capable of reducing the ignition temperature of the exhaust particles. The functional groups include =X, -XR, -NR2, -NO2, =NR, =NXR, =N-R*-XR, -CN, -N=NR and -N=CR2; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10). Useful metals include Na, K, Mg, Ca, Sr, Ba, V, Cr, Fe, Co, Cu, Zn, Pb, Sb, and mixtures of two or more thereof. This invention is also directed to concentrates and diesel fuels, and to methods of operating a diesel engine equipped with an exhaust system particulate trap.
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公开(公告)号:MX9200364A
公开(公告)日:1992-11-01
申请号:MX9200364
申请日:1992-01-28
Applicant: LUBRIZOL CORP
Inventor: DALY DANIEL TIMOTHI , ADAM PAUL ERNEST , JOLLEY SCOTT TED , KOCH FREDERICK WILLIAM , KOLP CHRISTOPHER JAY , STOLDT STEPHEN HOWARD , WALSH REED HUBER , DANIS RICHARD ASCOT , DENNIS , DISHONG MICHAEL , HUANG NAI ZHONG
IPC: C10L1/14 , C10L1/18 , C10L1/188 , C10L1/19 , C10L1/22 , C10L1/23 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/06 , C10L10/12 , F02B3/06 , C10L1/00
Abstract: This invention relates to low-sulfur diesel fuels which are useful with diesel engines equipped with exhaust system particulate traps. These fuels contain an effective mount of an organometallic complex to lower the ignition temperature of exhaust particles collected in the trap. The sulfur content of these diesel fuels is no more than about 0.1% by weight, preferably no more than about 0.05% by weight. The organometallic complex is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a metal reactant capable of forming a complex with the organic compound (i), the metal being any metal capable of reducing the ignition temperature of the exhaust particles. The functional groups include =X, -XR, -NR2, -NO2, =NR, =NXR, =N-R*-XR, -CN, -N=NR and -N=CR2; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10). Useful metals include Na, K, Mg, Ca, Sr, Ba, Ti, Zr, V, Cr, Mo, Mn, Fe, Co, Cu, Zn, B, Pb, Sb, and mixtures of two or more thereof. This invention is also directed to methods of operating a diesel engine equipped with an exhaust system particulate trap using the foregoing low-sulfur diesel fuels.
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