公开(公告)号：JPH0446933B2

公开(公告)日：1992-07-31

申请号：JP4687789

申请日：1989-02-27

Applicant: TORAY INDUSTRIES

Inventor： KANAI TAKASHI ,  KIMURA MICHIO ,  NOGUCHI YOSHIO

IPC: C07C17/38 ,  C07C17/00 ,  C07C17/389 ,  C07C25/02 ,  C07C25/08 ,  C07C67/00

公开(公告)号：JPH0446931B2

公开(公告)日：1992-07-31

申请号：JP33141588

申请日：1988-12-27

Applicant: TORAY INDUSTRIES

Inventor： YAMADA BUNJI ,  KIMURA MICHIO ,  NOGUCHI YOSHIO

IPC: C07C25/02 ,  C07C17/00 ,  C07C17/38 ,  C07C17/389 ,  C07C67/00

公开(公告)号：JPH0486604A

公开(公告)日：1992-03-19

申请号：JP19980990

申请日：1990-07-27

Applicant: TORAY INDUSTRIES

Inventor： KIMURA MICHIO ,  OKA KOICHIRO

IPC: G02B6/00 ,  G02B3/00 ,  G02B6/028

Abstract: PURPOSE:To improve surface hardness and heat resistance by using a monomer compsn. which can form a network polymer and a polymer having the refractive index different from the refractive index of this monomer compsn. CONSTITUTION:The monomer compsn. which can form the network polymer is partly polymerized and is molded to the fiber shape. Another monomer compsn. which can form the polymer having the refractive index different from the refractive index of the monomer compsn. or a mixture compose of >= 2 kinds of the monomers including this monomer is impregnated into the molding and the monomers are volatilized from the surface thereof or while the monomers are volatilized from the surface thereof or while the monomers are volatilized, the polymn. of the monomers is completed. The monomer compsn. prepd. by mixing the monomer compsn. which can form the network polymer, i.e. the monomer mixture contg. the monomer which can form the network polymer as well as a polymn. initiator and various polymn. compds. is first polymerized. The ratio of the monomer which forms the network polymer with respect to the entire part of the monomer mixture is preferably >= 2wt.% in this case. The plastic optical transmission body having the excellent heat resistance and surface hardness is obtd. in this way.

公开(公告)号：JPH0486603A

公开(公告)日：1992-03-19

申请号：JP19980890

申请日：1990-07-27

Applicant: TORAY INDUSTRIES

Inventor： KIMURA MICHIO ,  OKA KOICHIRO

IPC: G02B6/00 ,  G02B3/00 ,  G02B6/028

Abstract: PURPOSE:To obtain the optical transmission body which substantially prevents the phase sepn. of a polymer and has excellent transparency by using a mixture composed of the specific polymer and a monomer having the refractive index different from the refractive index of this polymer. CONSTITUTION:The polymer to be used is so formed that the polymer has radical polymerizable functional groups in its side chains and that these groups exist in the quantity of >= 0.2 mol% per repeating unit of the polymer. The polymer having at least one kind of the radical polymerizable functional groups in the side chains and the monomer having the refractive index different from the refractive index of the polymer when polymerized or a monomer mixture composed of >= 2 kinds of the monomers including this monomer are mixed and after the mixture is molded to a fiber shape, the monomers are volatilized from the molding surface or the monomers are polymerized while volatilized. The distributed index type optical transmission body having the excellent transparency and the excellent surface hardness and heat resistance is obtd. in this way.

公开(公告)号：JPH0446931A

公开(公告)日：1992-02-17

申请号：JP15576890

申请日：1990-06-13

Applicant: TORAY INDUSTRIES

Inventor： KARASAWA HIROO ,  KIMURA MICHIO ,  FUKUDA TADANORI

IPC: C08G75/02 ,  C08G75/0254

Abstract: PURPOSE:To increase intrinsic viscosity, decrease reaction time, and improve mechanical strengths by conducting the polycondensation of an alkali metal sulfide with a dihalide compd. in the presence of a specific quaternary ammonium salt. CONSTITUTION:An alkali metal sulfide (e.g. sodium sulfide nona-hydrate) and a dihalide compd. of formula I (wherein R and R are each H or a hydrocarbon group; and R is a direct bond or a hydrocarbon group) (e.g. 1,6-dibromohexane) are polycondensed in the presence of a phase transfer catalyst comprising a quaternary ammonium salt of formula II (wherein R to R are each an aliph. alkyl group provided that at least two of them are 6C or higher alkyl) (e.g. trioctylmethylammonium chloride) in a solvent at 50-150 deg.C.

公开(公告)号：JPH03293619A

公开(公告)日：1991-12-25

申请号：JP9730190

申请日：1990-04-11

Applicant: TORAY INDUSTRIES

Inventor： KIMURA MICHIO ,  OKA KOICHIRO ,  BABA SETSUO

IPC: G02C5/00

Abstract: PURPOSE:To obtain the plastic spectacle frame having sufficient rigidity, flexural property, heat resistance and transparency while the frame is slim by essentially consisting of the frame of polyphenylene sulfide sulfone. CONSTITUTION:This spectacle frame is essentially composed of the polyphenylene sulfide sulfone. Any polyphenylene sulfide sulfones are usable without particular limitation, insoar as they are the polymers having the unit expressed by formula I. Such polyphenylene sulfide sulfones are theremoplastic noncrystalaline resins and high dimensional stability as these resins are lower in molding shrinkage than crystalline resins and have low water absorptivity. The spectacle frame which has the excellent transparency, mechanical strength, flexural property, and impact property and retains its initial shape without collapsing even in high-temp. environment is obtd.

公开(公告)号：JPH02240054A

公开(公告)日：1990-09-25

申请号：JP6186789

申请日：1989-03-13

Applicant: TORAY INDUSTRIES

Inventor： KIMURA MICHIO ,  IGUCHI YUICHIRO ,  OKA KOICHIRO

IPC: C07C321/04

Abstract: NEW MATERIAL:Bis(2-mercaptoethylsulfide)methane of formula I. USE:Useful as a synthetic intermediate for synthetic resin modifier, pharmaceuticals and agricultural chemicals, a raw material for optical resin, etc. It is odorless and nontoxic and exhibits high refractive index and light- resistance when used especially as an optical resin. PREPARATION:The objective compound of formula I can be produced by reacting 2mol of 2-mercaptoethanol of formula HSCH2CH2OH with 1mol of a dihalomethane of formula XCH2Y (X and Y are Cl, Br or I), reacting the resultant bis(2-hydroxyethylsulfide)methane of formula II with thiourea in the presence of hydrochloric acid or hydrobromic acid to obtain a diisothiuronium salt of formula III and hydrolyzing the salt with an aqueous solution of an alkali.

公开(公告)号：JPH01299872A

公开(公告)日：1989-12-04

申请号：JP13083588

申请日：1988-05-27

Applicant: TORAY INDUSTRIES

Inventor： KIMURA MICHIO ,  YORUBE HIDEMITSU ,  KADODE AKIRA

IPC: C08L81/02 ,  C08L81/00 ,  C08L81/06

Abstract: PURPOSE:To obtain the title composition improved in mechanical properties such as impact resistance, by mixing a specified polyphenylene sulfide resin with an aromatic polysulfone resin. CONSTITUTION:A polyphenylene sulfide resin which is a polymer containing at least 70mol%, desirably, at least 90mol% repeating units of the formula is subjected to a deionization treatment by at least one operation selected from among acid treatment, hot-water treatment, washing with an organic solvent, etc., to obtain a deionized polyphenylene sulfide resin (A) of an Na content

公开(公告)号：JPH01250330A

公开(公告)日：1989-10-05

申请号：JP33141588

申请日：1988-12-27

Applicant: TORAY INDUSTRIES

Inventor： YAMADA BUNJI ,  KIMURA MICHIO ,  NOGUCHI YOSHIO

IPC: C07C25/02 ,  C07C17/00 ,  C07C17/38 ,  C07C17/389 ,  C07C67/00

Abstract: PURPOSE:To adsorb and separate especially the 3,5-isomer, by treating a dichlorocumene isomer mixture with an adsorbent consisting of zeolite, such as faujasite, L or beta type, having a specific silica/alumina molar ratio and pore diameter. CONSTITUTION:The 3,5-isomer is separated from a dichlorocumene isomer mixture. In the process, zeolite (e.g., faujasite, L or beta type) having >=2 molar ratio of silica/alumina and 0.6-1.0nm pore diameter is used as an adsorbent to carry out adsorption at 50-250 deg.C under atmospheric pressure -40kg/cm G. Thereby, the aimed substance is efficiently obtained in high purity. The method for adsorption and separation may be carried out by either of methods for chromatographic separation and collection and using continuous a pseudo-moving bed. The present substance is useful as a synthetic intermediate for medicines, agricultural chemicals, dyes, etc.

公开(公告)号：JPH01174562A

公开(公告)日：1989-07-11

申请号：JP33502387

申请日：1987-12-28

Applicant: TORAY INDUSTRIES

Inventor： KIMURA MICHIO ,  KADOI AKIRA ,  YOBE HIDEMITSU

IPC: C08L77/00 ,  C08L81/02

Abstract: PURPOSE:To obtain a polyphenylene sulfide resin composition having improved mechanical properties such as impact characteristics without deteriorating the excellent characteristics of the base resin, by adding a polyamide resin to a deionized polyphenylene sulfide resin. CONSTITUTION:A polyphenylene sulfide resin containing >=70mol.%, preferably >=90mol.% of the recurring unit of formula is subjected to acid treatment (e.g., immersing the resin in an aqueous solution of acetic acid at pH4 and 80-90 deg.C and stirring for 30min), hot-water treatment (stirring the resin in hot water of >=100 deg.C in an autoclave in inert atmosphere) or washing with an organic solvent (preferably N-methylpyrrolidone, acetone, etc.) and the treated resin is washed with water (preferably distilled water or deionized water). (A) 1-99wt.% of the deionized polyphenylene sulfide resin produced by the above process is compounded with (B) 99-1wt.% of a polyamide having a relative viscosity of 2-5 to obtain the objective polyphenylene sulfide resin composition.