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公开(公告)号:JPS5661454A
公开(公告)日:1981-05-26
申请号:JP13754879
申请日:1979-10-26
Applicant: TORAY INDUSTRIES
Inventor: IYAMA MITSUAKI , MURAKI TOSHIO
Abstract: PURPOSE:To provide a heat-sensitive element in which impedance characteristics are remarkably changed with temperatures, by a method wherein liCl is blended with a specified polyamide resin. CONSTITUTION:(B) 100-6,000ppm, perf. 300-3,000ppm (calculated as Li) of LiCl is blended with (A) a polyamide resin contg. not more than 14 amide gp. per 100 carbon atoms (e.g. a polyaminoundecamide). The mixt, is melt-kneaded and then molded into a rod or a sheet to form the desired heat-sensitive element. EFFECT:Electrical properties are remarkably changed with temperatures. The amount of the element is not changed with time by bleedout. The element does not corrode aluminum and copper which are used for signal conductors.
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公开(公告)号:JPS5596589A
公开(公告)日:1980-07-22
申请号:JP337979
申请日:1979-01-18
Applicant: TORAY INDUSTRIES
Inventor: KONDOU TAKEO , MURAKI TOSHIO
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公开(公告)号:JPS5574537A
公开(公告)日:1980-06-05
申请号:JP14783378
申请日:1978-12-01
Applicant: TORAY INDUSTRIES
Inventor: CHIBA KAZUMASA , EGAWA KEIICHI , MURAKI TOSHIO
Abstract: PURPOSE:To improve performances such as faster water developing speed and faithful reproduction of fine lines and small spots etc. by making combined use of the copolymerized polyamide containing the specific amount of the polyether segment portions of the specific molecular weights and a photo-polymerizable unsaturated compound. CONSTITUTION:The polyoxy ethylene which has amino groups or carboxyl groups at the terminal and which is of 150-1500 in number average molecular weight of the polyether segment portions, the copolymerized polyamide which contains 30- 70wt% of the constituting units composed of aliphatic dicarboxylic acid or diamine and whose value of O/N is within a range of 1-4 and a photo-polymerizable unsaturated compound (acrylic ester of glycol, etc.) are combined at 5-200wt% based on the weight of the polyamide, and besides these, a photosensitizer, heat polymerization inhibitor are added to produce the photosensitive resin composition. In this way, the printing plate or the like which is of good transparency, soft, tough and highly accurate is obtained.
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公开(公告)号:JPS5272753A
公开(公告)日:1977-06-17
申请号:JP14843975
申请日:1975-12-15
Applicant: TORAY INDUSTRIES
Inventor: MURAKI TOSHIO , YAMADA KEIJIROU
Abstract: PURPOSE:Softened polyamide compositions capable of dispersing a comparatively large amount of plasticizers finely and homogeneously, obtained by making polymers such as polyetherpolyamide, etc. absorb plasticizers and then adding the said polymers to polyamides.
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公开(公告)号:JPH09217281A
公开(公告)日:1997-08-19
申请号:JP2279696
申请日:1996-02-08
Applicant: TORAY INDUSTRIES
Inventor: ENOU MASAZUMI , MURAKI TOSHIO
IPC: D06M15/55 , D06M13/02 , D06M13/322 , D06M13/325 , D06M13/335 , D06M13/35 , D06M13/352 , D06M101/00 , D06M101/40
Abstract: PROBLEM TO BE SOLVED: To produce a carbon fiber for a chopped strand useful for a carbon- fiber reinforced composite material excellent in mechanical characteristics by applying a binder consisting essentially of a thermosetting resin and a curing agent to a carbon fiber bundle. SOLUTION: This carbon fiber bundle for a chopped strand comprises 0.5-5wt.% binder applied thereto and has a bending resistance within the range of 20-100mm. The carbon fiber bundle is obtained by preparing a binder, containing at least one water-soluble curing agent, selected a (cyclo)aliphatic amine, an aliphatic amine containing an aromatic ring, an aromatic amine and an imidazole compound and added to an emulsion prepared by emulsifying and dispersing a thermosetting epoxy resin in water and having >=50 deg.C glass transition point temperature, impregnating the carbon fiber bundle with a liquid of the binder, then drying the resultant carbon fiber bundle by heating, removing water and curing the epoxy resin.
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公开(公告)号:JPH08232135A
公开(公告)日:1996-09-10
申请号:JP31424895
申请日:1995-12-01
Applicant: TORAY INDUSTRIES
Inventor: ENOU MASAZUMI , HAYASHI MASAHIKO , MURAKI TOSHIO
Abstract: PURPOSE: To obtain a woven fabric for a carbon-fiber reinforced plastic(CFRP), having a sufficient cover factor, a slight extent of bowed weft yarns and excellent in compressive strength, etc., by binding both selvedge parts of a carbon fiber woven fabric with a small number of binding yarns and then carrying out the opening treatment of the woven fabric with water jets. CONSTITUTION: One to ten binding yarns for preventing weft yarns 1 from fraying are woven into both selvedge parts of a carbon fiber woven fabric to carry out the opening treatment of the woven fabric with water jets. The basis weight of the woven fabric is preferably about 140-220g/m and the woven fabric having >=95% cover factor and
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公开(公告)号:JPH08151426A
公开(公告)日:1996-06-11
申请号:JP29272494
申请日:1994-11-28
Applicant: TORAY INDUSTRIES
Inventor: ENOU MASAZUMI , MURAKI TOSHIO , AZUMA KUNIHIRO , NODA SHUNSAKU
Abstract: PURPOSE: To obtain a resin composition desirable for obtaining an advanced composite material having excellent mechanical properties and durability by mixing an epoxy resin with a curing agent and a reactive-group-containing solid acrylonitrile/butadiene rubber in a specified manner. CONSTITUTION: This composition is obtained by adding a curing agent to a mixture comprising a reactive-group-containing solid acrylonitrile/butadiene rubber and an epoxy resin and obtained by dissolving the rubber and the resin in an organic solvent and removing the solvent from the resulting solution with a thin film evaporator. This composition is one comprising the epoxy resin, the curing agent and the reactive-group-containing solid acrylonitrile/ butadiene rubber in an amount of 3-10wt.% based on the entire resin composition and satisfying the relationship (wherein P is the viscosity (poise) of the epoxy resin composition at 80 deg.C, and W is the percentage by weight of the reactive- group-containing solid acrylonitrile/butadiene rubber based on the entire resin composition).
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公开(公告)号:JPH083335A
公开(公告)日:1996-01-09
申请号:JP13886794
申请日:1994-06-21
Applicant: TORAY INDUSTRIES
Inventor: ENOU MASAZUMI , MURAKI TOSHIO , SAWAOKA RYUJI , OKI NOBUAKI
Abstract: PURPOSE:To obtain the prepreg economically stabilized in the adhesivity of a matrix resin by preventing the spring back of the carbon fiber. bundle. CONSTITUTION:This unidirectional carbon fiber prepreg contains carbon fiber bundles having 0.5-10.0wt.% of a shape-stabilizing agent adhered thereto and having a torsional strength of 5-40 deg.C and an epoxy resin composition as essential components, and the method for producing the unidirectional carbon fiber prepreg having characteristics comprising having 0.5-10.0wt.% of the epoxy resin composition cured product adhered to the carbon fibers and having a carbon fiber torsional strength of 5-40 comprise thermally impregnating the carbon fiber bundles having (A) a low temperature-curing agent adhered thereto with the epoxy resin composition under a pressure and curing a part of the epoxy resin composition with (A) the curing agent in the impregnation process.
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公开(公告)号:JPH07227939A
公开(公告)日:1995-08-29
申请号:JP1921294
申请日:1994-02-16
Applicant: TORAY INDUSTRIES
Inventor: ENOU MASAZUMI , AZUMA TOSHIAKI , MURAKI TOSHIO
Abstract: PURPOSE:To provide a honeycomb molding, the porosities at the surface of a skin material and in the skin material of which are small. CONSTITUTION:At the manufacturing of a honeycomb molding, which consists of a honeycomb core material and fibrous fabric reinforced composite material skin materials, which are integrated with the honeycomb core material at its upper and lower sides, molding is performed under heat and pressure by laminating a fiber reinforced prepreg to the upper and lower sides of the honeycomb core material under the condition that a uniform film having a thickness of 10-200mum is interposed between one of the surface laminated with the prepreg and the surface of a tool.
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公开(公告)号:JPH06345884A
公开(公告)日:1994-12-20
申请号:JP13845793
申请日:1993-06-10
Applicant: TORAY INDUSTRIES
Inventor: ENOU MASAZUMI , MURAKI TOSHIO , AZUMA TOSHIAKI , NOMAN FUMIAKI
Abstract: PURPOSE:To obtain the subject composition comprising a specific epoxy resin, a specific amount of a solid nitrile rubber, and an aromatic amine curing agent, good in handling properties such as a tack.draping property and excellent in dynamic characteristics such as toughness. CONSTITUTION:This epoxy resin composition comprises (A) an epoxy resin containing 20-50 wt.% of a bisphenol A type epoxy resin solid at room temperature, (B) a solid nitrile rubber, and (C) an aromatic amine ceering agent (preferably the various isomers of diaminodiphenyl sulfone), the content of the component B in the composition being 2-8 wt.%. The component A is preferably the combination of 10-50% of tetraglycidylaminodiphenyl methane, 1-10% of a liquid bisphenol A type epoxy resin, 5-25% of a liquid bisphenol F type epoxy resin, 10-50% of a solid bisphenol A type epoxy resin, and 5-30% of a brominated bisphenol A type epoxy resin, because the balance between heat resistance, water resistance and workability is good.
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