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公开(公告)号：DE69531641D1
公开(公告)日：2003-10-09
申请号：DE69531641
申请日：1995-03-15
Applicant: TORAY INDUSTRIES
Inventor： SAWAOKA RYUJI , KOUCHI SHINJI , MURAKI TOSHIO
Abstract: A microcapsule-type curing agent comprises (A) a curing agent for a thermosetting resin and (B) a thermoplastic resin dissolvable in the thermosetting resin by heating. The microcapsule-type curing agent is formed as a particle-like material in which the component (A) is coated with a layer whose main constituent is the component (B) and the mean particle diameter of which is in the range of 0.1 to 20 mu m. By using the microcapsule-type curing agent, a thermosetting resin composition and a prepreg which are good in storage stability at a room temperature and excellent in thermal resistance of a cured product made therefrom can be obtained. Further, a fiber reinforced composite material obtained using this thermosetting resin composition is excellent in curing uniformity and thermal resistance.
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公开(公告)号：DE69526997D1
公开(公告)日：2002-07-18
申请号：DE69526997
申请日：1995-03-21
Applicant: TORAY INDUSTRIES
Inventor： MURAKI TISHIO , TOKUNOU MASAZUMI , SAWAOKA RYUJI , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , TAZAKI TOKUO
Abstract: A prepreg precursor comprising a carbon fiber woven fabric having applied to the fabric from 0.5 to 10 wt% of a stabilizer material for rendering stable the structural form of the fabric. Prepregs can then be produced using the woven fabric. The undesired settlement, into the prepreg of matrix resin with which the fabric is impregnated in order to produce the prepreg and which is originally present on the surface of the woven fabric, is thus prevented. Hence, compared with a prepreg prepared using conventional woven fabric, a prepreg prepared by using the woven fabric of the invention can hold its tackiness for a long time and can be used to produce a fiber reinforced composite material excellent in smoothness without being devoid of the resin on the surface.
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公开(公告)号：DE69531641T2
公开(公告)日：2004-07-01
申请号：DE69531641
申请日：1995-03-15
Applicant: TORAY INDUSTRIES
Inventor： SAWAOKA RYUJI , KOUCHI SHINJI , MURAKI TOSHIO
Abstract: A microcapsule-type curing agent comprises (A) a curing agent for a thermosetting resin and (B) a thermoplastic resin dissolvable in the thermosetting resin by heating. The microcapsule-type curing agent is formed as a particle-like material in which the component (A) is coated with a layer whose main constituent is the component (B) and the mean particle diameter of which is in the range of 0.1 to 20 mu m. By using the microcapsule-type curing agent, a thermosetting resin composition and a prepreg which are good in storage stability at a room temperature and excellent in thermal resistance of a cured product made therefrom can be obtained. Further, a fiber reinforced composite material obtained using this thermosetting resin composition is excellent in curing uniformity and thermal resistance.
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公开(公告)号：DE60013527D1
公开(公告)日：2004-10-14
申请号：DE60013527
申请日：2000-03-10
Applicant: TORAY INDUSTRIES
Inventor： KAMAE TOSHIYA , OOSEDO HIROKI , NODA SHUNSAKU , KOUCHI SHINJI , SAWAOKA RYUJI
Abstract: An object of the invention is to provide an epoxy resin composition having a low viscosity around a room temperature and excellent reinforcing fiber impregnating properties, thereby to provide a composite material having excellent heat resistance and mechanical properties including compressive strength. According to the present invention there is provided an epoxy resin composition comprising an aromatic epoxy resin having at least di-functionality, an aromatic amine compound and/or an alicyclic amine compound, wherein 5 minutes after the main agent comprising the epoxy resin and the curing agent comprising the aromatic amine compound and/or the alicyclic amine compound are mixed, the composition shows a viscosity at 25 DEG C in the range of from 1 to 1500 mPas, and Tc, tc, and Tg satisyfy the following equation. Tg ≥ Tc + 20 - k x (Tc - 90) k = 0 when 60 ≤ Tc
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公开(公告)号：AU1610795A
公开(公告)日：1995-10-19
申请号：AU1610795
申请日：1995-03-23
Applicant: TORAY INDUSTRIES
Inventor： MURAKI TOSHIO , TOKUNOU MASAZUMI , SAWAOKA RYUJI , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , TAZAKI TOKUO
Abstract: A prepreg precursor comprising a carbon fiber woven fabric having applied to the fabric from 0.5 to 10 wt% of a stabilizer material for rendering stable the structural form of the fabric. Prepregs can then be produced using the woven fabric. The undesired settlement, into the prepreg of matrix resin with which the fabric is impregnated in order to produce the prepreg and which is originally present on the surface of the woven fabric, is thus prevented. Hence, compared with a prepreg prepared using conventional woven fabric, a prepreg prepared by using the woven fabric of the invention can hold its tackiness for a long time and can be used to produce a fiber reinforced composite material excellent in smoothness without being devoid of the resin on the surface.
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Patent Agency Ranking
公开(公告)号：DE60013527T2
公开(公告)日：2005-09-22
申请号：DE60013527
申请日：2000-03-10
Applicant: TORAY INDUSTRIES
Inventor： KAMAE TOSHIYA , OOSEDO HIROKI , NODA SHUNSAKU , KOUCHI SHINJI , SAWAOKA RYUJI
Abstract: An object of the invention is to provide an epoxy resin composition having a low viscosity around a room temperature and excellent reinforcing fiber impregnating properties, thereby to provide a composite material having excellent heat resistance and mechanical properties including compressive strength. According to the present invention there is provided an epoxy resin composition comprising an aromatic epoxy resin having at least di-functionality, an aromatic amine compound and/or an alicyclic amine compound, wherein 5 minutes after the main agent comprising the epoxy resin and the curing agent comprising the aromatic amine compound and/or the alicyclic amine compound are mixed, the composition shows a viscosity at 25 DEG C in the range of from 1 to 1500 mPas, and Tc, tc, and Tg satisyfy the following equation. Tg ≥ Tc + 20 - k x (Tc - 90) k = 0 when 60 ≤ Tc
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公开(公告)号：DE69526997T2
公开(公告)日：2003-01-23
申请号：DE69526997
申请日：1995-03-21
Applicant: TORAY INDUSTRIES
Inventor： MURAKI TISHIO , TOKUNOU MASAZUMI , SAWAOKA RYUJI , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , TAZAKI TOKUO
Abstract: A prepreg precursor comprising a carbon fiber woven fabric having applied to the fabric from 0.5 to 10 wt% of a stabilizer material for rendering stable the structural form of the fabric. Prepregs can then be produced using the woven fabric. The undesired settlement, into the prepreg of matrix resin with which the fabric is impregnated in order to produce the prepreg and which is originally present on the surface of the woven fabric, is thus prevented. Hence, compared with a prepreg prepared using conventional woven fabric, a prepreg prepared by using the woven fabric of the invention can hold its tackiness for a long time and can be used to produce a fiber reinforced composite material excellent in smoothness without being devoid of the resin on the surface.
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公开(公告)号：AU2941100A
公开(公告)日：2000-09-28
申请号：AU2941100
申请日：2000-03-10
Applicant: TORAY INDUSTRIES
Inventor： KAMAE TOSHIYA , OOSEDO HIROKI , NODA SHUNSAKU , KOUCHI SHINJI , SAWAOKA RYUJI
Abstract: An object of the invention is to provide an epoxy resin composition having a low viscosity around a room temperature and excellent reinforcing fiber impregnating properties, thereby to provide a composite material having excellent heat resistance and mechanical properties including compressive strength. According to the present invention there is provided an epoxy resin composition comprising an aromatic epoxy resin having at least di-functionality, an aromatic amine compound and/or an alicyclic amine compound, wherein 5 minutes after the main agent comprising the epoxy resin and the curing agent comprising the aromatic amine compound and/or the alicyclic amine compound are mixed, the composition shows a viscosity at 25 DEG C in the range of from 1 to 1500 mPas, and Tc, tc, and Tg satisyfy the following equation. Tg ≥ Tc + 20 - k x (Tc - 90) k = 0 when 60 ≤ Tc
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9.发明公开
公开(公告)号：EP0947562A4
公开(公告)日：2001-01-03
申请号：EP98947875
申请日：1998-10-14
Applicant: TORAY INDUSTRIES
Inventor： OOSEDO HIROKI , SAWAOKA RYUJI , NODA SHUNSAKU , MIYOSHI NAOMI
IPC: C08G59/40 , C08J5/24 , C08L67/06 , C08L101/00 , C08F290/06 , C08K5/20 , C08K5/36 , C08K5/43 , C08K5/5399 , C08L63/00
CPC classification number: C08J5/24 , C08G59/40 , C08J2363/00 , C08L67/06 , Y10T428/24994 , Y10T428/249952
Abstract: In order to realise the objectives stated above, the thermosetting resin composition for carbon fibre reinforced composite materials of the present invention chiefly comprises the following components. (A) Thermosetting resin (B) Compound containing one functional group which can react with thermosetting resin (A) or its curing agent, and a moiety selected from the following formulae (1) to (4) Furthermore, the present invention also relates to a prepreg formed by impregnating reinforcing fibre with the aforesaid resin composition and to carbon fibre reinforced composite materials comprising reinforcing fibre and a cured aforesaid thermosetting resin composition. In accordance with the present invention, there can be obtained a thermosetting resin composition where the adhesion to reinforcing fibre by the cured material and the elastic modulus of the cured material are excellent, and by using this resin composition there can be obtained carbon fibre reinforced composite materials which are excellent in their 0 DEG compressive strength, 90 DEG tensile strength and interlaminar shear strength, and which also have outstanding impact resistance.
Abstract translation: 为了实现上述目的，本发明的碳纤维增强复合材料用热固性树脂组合物主要包括以下成分。 （A）热固性树脂（B）含有可与热固性树脂（A）或其固化剂反应的一个官能团的化合物和选自下式（1）〜（4）的部分
此外，本发明 还涉及通过用上述树脂组合物浸渍增强纤维和由增强纤维和固化的上述热固性树脂组合物制成的碳纤维增强复合材料形成的预浸料。 根据本发明，可以获得热固性树脂组合物，其中通过固化材料对增强纤维的粘附性和固化材料的弹性模量优异，并且通过使用该树脂组合物，可以获得碳纤维增强复合材料 其0°抗压强度，90°拉伸强度和层间剪切强度优异的材料，并且还具有突出的抗冲击性。 -
10.发明公开EPOXY RESIN COMPOSITION, EPOXY RESIN COMPOSITION FOR FIBER-REINFORCED COMPOSITE, AND FIBER-REINFORCED COMPOSITE CONTAINING THE SAME 有权环氧树脂组合物，纤维强化复合材料用环氧树脂组合物和含有增强纤维复合材料
公开(公告)号：EP1094087A4
公开(公告)日：2002-10-02
申请号：EP00907993
申请日：2000-03-10
Applicant: TORAY INDUSTRIES
Inventor： KAMAE TOSHIYA , OOSEDO HIROKI , NODA SHUNSAKU , KOUCHI SHINJI , SAWAOKA RYUJI
CPC classification number: C08L63/00 , C08G59/18 , C08G59/50 , C08G59/5033 , Y10T428/24994 , Y10T428/2918 , Y10T428/31511
Abstract: An epoxy resin composition which has a low viscosity and is excellent in infiltration into reinforcing fibers; and a composite having excellent mechanical properties. The composition comprises a polyfunctional aromatic epoxy resin and, compounded therewith, an aromatic amine compound and/or an alicyclic amine compound. It is characterized by having a viscosity at 25 DEG C of 1 to 1,500 mPa. s as measured at 5 minutes after a main ingredient comprising the epoxy resin is mixed at 25 DEG C with a hardener comprising the amine compound(s) and by satisfying the following equation (1): Tg >/=Tc + 20 - k x (Tc - 90) wherein k is 0 when 60
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