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公开(公告)号:JPH07323512A
公开(公告)日:1995-12-12
申请号:JP12127694
申请日:1994-06-02
Applicant: TORAY INDUSTRIES
Inventor: MORITA TORU , SASAKI TOSHIHIRO , OKASAKA HIDESADA
Abstract: PURPOSE:To obtain a film improved in surface flatness and cutting resistance and having uniform thickness by adding a metal element and phosphorus element represented by a specific formula to polyester constituting an auxiliary layer and setting a crystallization parameter defined by a separate specific formula to specific temp. or lower and making the same smaller than that of main layer polyester. CONSTITUTION:It is necessary to add a metal element (M) and a phosphorus element (P) to polyester constituting an auxiliary layer so as to satisfy formulae 0.1 g of polyester. In the constitution of DELTATcg=Tc-Tg (wherein Tc is crystallization temp. of polyester and Tg is glass transition temp. of polyester), the crystallization parameter DELTATcg of the auxiliary layer polyester is 70 deg.C or lower and smaller than the crystallization parameter Tcg of the main layer polyester. When M, M/P and DELTATcg are within prescribed ranges, a film good in surface roughness and cutting resistance and having uniform thickness is obtained.
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公开(公告)号:JPH07286094A
公开(公告)日:1995-10-31
申请号:JP8203694
申请日:1994-04-20
Applicant: TORAY INDUSTRIES
Inventor: SASAKI TOSHIHIRO , MORITA TORU , OKASAKA HIDESADA
IPC: C07C31/20 , C08G63/181 , C08K5/42 , C08L67/00 , C08L67/02
Abstract: PURPOSE:To obtain a glycol slurry for a polyester additive which has high softening point and gives a polyester formed article excellent in transparency, antistatic properties and abrasion resistance when formed into film or fiber. CONSTITUTION:This slurry contains 1-70wt.% metal sulfonate derivative represented by the formula R(X)nSO3M (wherein R is 5-30C alkyl; X is an aromatic group; n is 0, 1 or 2; and M is an alkali metal or alkaline earth metal element) and has a pH (hydrogen ion concentration) of 10 or higher.
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公开(公告)号:JPH07138459A
公开(公告)日:1995-05-30
申请号:JP28800593
申请日:1993-11-17
Applicant: TORAY INDUSTRIES
Inventor: OKASAKA HIDESADA , MORITA TORU , SASAKI TOSHIHIRO
Abstract: PURPOSE:To obtain a polyester composition containing Al2O3-ZrO2 composite oxide particles, having excellent abrasion resistance, transportability and durability and useful as a biaxially drawn film, especially as a substrate for magnetic recording tape. CONSTITUTION:This polyester composition contains Al2O3-ZrO2 composite oxide particles produced e.g. by evaporating AlCl3 and ZrCl4, introducing the compounds into an oxyhydrogen flame using nitrogen gas as a carrier and reacting the compounds in the flame. The ratios of Al2O3 and ZrO2 in the composite oxide particle are preferably 10-90wt.% for Al2O3 and preferably 90-10wt.%, more preferably 80-20wt.%, especially 70-30wt.% for ZrO2. The average particle diameter of the temporary particles of the composite oxide particles is preferably 10-500nm, more preferably 20-300nm, especially 30-200nm. The amount of the composite oxide particle to be added to the polyester is preferably 0.01-5wt.%.
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公开(公告)号:JPH07117199A
公开(公告)日:1995-05-09
申请号:JP26522693
申请日:1993-10-22
Applicant: TORAY INDUSTRIES
Inventor: MORITA TORU , SASAKI TOSHIHIRO , OKASAKA HIDESADA
Abstract: PURPOSE:To provide a biaxially oriented laminated film having abrasion resistance, an antistatic and traveling property, evenness, and heat stability. CONSTITUTION:The biaxially oriented laminated film is such that polyester forming a surface layer (secondary layer) contains an organic sulfonic metal acid of 0.1-10wt.% and insoluble particles of 0.01-10wt.% relative to polyester, and the thickness of the secondary layer is to 0.005-5mum. In this way, there are achieved good characteristics such as abrasion resistance, an antistatic and traveling property, evenness, and heat stability, and it is suitably used in the field of a magnetic medium, in particular, of a magnetic tape base film or the like.
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公开(公告)号:JPH0570670A
公开(公告)日:1993-03-23
申请号:JP23515591
申请日:1991-09-13
Applicant: TORAY INDUSTRIES
Inventor: SASAKI TOSHIHIRO , YOSHIDA MINORU , SUZUKI MASARU
Abstract: PURPOSE:To provide the subject composition comprising silica particles having a specific particle size and a specified thermoplastic polyester, having excellent sliding property abrasion resistance and affinity, and suitable for obtaining films or fibers. CONSTITUTION:The objective composition comprises (A) silica particles having a D1/D2 ratio of >=2 between a particle size (D1m#,) measured by a dynamic light scattering method and a particle size (D2mmu) measured by a nitrogen gas adsorption method, having the D1 of 60-600mmu, having a thickness of 41-100mmu on the observation using an electron microscope, and having a linear or branched shape, and (B) a thermoplastic polyester having 10-100 equivalents per 10 g of the polyester.
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公开(公告)号:JP2003201347A
公开(公告)日:2003-07-18
申请号:JP2001347763
申请日:2001-11-13
Applicant: TORAY INDUSTRIES
Inventor: UCHIDA MINORU , SASAKI TOSHIHIRO , NARUSE YOSHIHIRO
IPC: C08J3/20
Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing a polyester composition which contains inorganic porous particles at a high concentration, suppressed in the drop of a limiting viscosity and contains no large-sized particles and is excellent in the particle dispersibility. SOLUTION: The method for manufacturing the polyester composition by means of a vented kneader comprises addition and mixing of the inorganic porous particles having an average particle diameter of 0.01-10 μm and a water content of less than 10 wt.%, to the polyester in the state of substantial powder and of a limiting viscosity of 0.5 or more. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2003155625A
公开(公告)日:2003-05-30
申请号:JP2001349881
申请日:2001-11-15
Applicant: TORAY INDUSTRIES
Inventor: NARUSE YOSHIHIRO , SASAKI TOSHIHIRO , NAGANO TATSUYA
Abstract: PROBLEM TO BE SOLVED: To provide a highly hygroscopic polyester fiber usable as a comfortable material for underwear, sportswear, lining cloths and the like as woven/ knitted fabrics or the like. SOLUTION: This highly hygroscopic polyester fiber contains silica-based inorganic particles.
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公开(公告)号:JP2003155400A
公开(公告)日:2003-05-27
申请号:JP2001357231
申请日:2001-11-22
Applicant: TORAY INDUSTRIES
Inventor: NARUSE YOSHIHIRO , UCHIDA MINORU , SASAKI TOSHIHIRO
IPC: C08L67/00 , C08K3/22 , C08K3/26 , C08K3/30 , C08K3/36 , C08K9/02 , C08K9/06 , C08L71/02 , D01F6/92
Abstract: PROBLEM TO BE SOLVED: To provide a moisture-absorbing or releasing fiber which has an excellent moisture-absorbing or releasing property and is therefore especially suitable as a synthetic fiber having good wearing comfortableness. SOLUTION: This fiber comprises a moisture-absorbing or releasing polyester composition containing 1 to 20 wt.% of moisture-absorbing or releasing silica- based inorganic particles having an average particle diameter, a specific surface, a pore volume, and a moisture-absorbing parameter (ΔMR) in specific ranges.
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公开(公告)号:JP2002088574A
公开(公告)日:2002-03-27
申请号:JP2000246922
申请日:2000-08-16
Applicant: TORAY INDUSTRIES
Inventor: SASAKI TOSHIHIRO , NARUSE YOSHIHIRO , SHIMIZU YUZO
Abstract: PROBLEM TO BE SOLVED: To provide a polyester fiber that is suitable for producing combined filament yarns or blended yarns and fabrics with a regular polyester fiber has increased dyeability and resistance to alkali hydrolysis. SOLUTION: A specific copolymer is combined with regular polyester fiber to produce the objective modified polyester fiber. Regular polyester fiber is improved its dye dyeability and resistance to alkali hydrolysis by admixing a specific copolymer composition to regular polyester.
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公开(公告)号:JP2002030521A
公开(公告)日:2002-01-31
申请号:JP2000219952
申请日:2000-07-21
Applicant: TORAY INDUSTRIES
Inventor: NARUSE YOSHIHIRO , MATSUMURA YOSHITAKA , SASAKI TOSHIHIRO
Abstract: PROBLEM TO BE SOLVED: To obtain a moisture-absorbing and moisture-releasing fiber especially suitable as a synthetic fiber having wearing comfort s due to excellent moisture- absorbing and moisture-releasing properties. SOLUTION: This moisture-absorbing and moisture-releasing fiber comprises a moisture-absorbing and moisture-releasing polyester composition obtained by adding 1-20 wt.% based on a polyester resin of a moisture-absorbing and moisture-releasing silica-based inorganic particle having an average particle diameter, a specific surface area, a pore volume, a moisture absorption parameter (ΔMR), a particle size distribution and a flatness ratio in specific ranges to the polyester resin composed of >=80 mol% of an alkylene terephthalate repeating unit.
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