公开(公告)号：US09663369B2

公开(公告)日：2017-05-30

申请号：US13329184

申请日：2011-12-16

Applicant: Ali Afzali-Ardakani ,  Bhupesh Chandra ,  George S. Tulevski

Inventor： Ali Afzali-Ardakani ,  Bhupesh Chandra ,  George S. Tulevski

IPC: C01B31/02 ,  H01B1/04 ,  H01J1/304 ,  H01J9/02 ,  B82Y30/00 ,  B82Y40/00

CPC classification number: H01J9/025 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/168 ,  H01J1/304 ,  H01J2201/30453 ,  H01J2201/30469

Abstract: A process comprises combining a Ce (IV) salt dissolved in a solvent comprising water with a carbon material comprising CNT or graphene wherein the Ce (IV) salt is selected from a Ce (IV) ammonium salt of a nitrogen oxide acid, Ce (IV) ammonium salt of a sulfur oxide acid, Ce (IV) salt of a lower alkyl organo sulfur acid, or Ce (IV) salt of a lower alkane organo sulfur acid. In one embodiment the Ce (IV) salt is selected from Ce (IV) ammonium nitrate, Ce (IV) ammonium sulfate, Ce (IV) lower alkyllsulfonate, or Ce (IV) trifluoro lower alkanesulfonate. A product is produced by this process. An article of manufacture comprises this product on a substrate.

公开(公告)号：US20130153831A1

公开(公告)日：2013-06-20

申请号：US13329184

申请日：2011-12-16

Applicant: Ali Afzali-Ardakani ,  Bhupesh Chandra ,  George S. Tulevski

Inventor： Ali Afzali-Ardakani ,  Bhupesh Chandra ,  George S. Tulevski

IPC: H01B1/04 ,  B82Y40/00 ,  B82Y30/00

CPC classification number: H01J9/025 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/168 ,  H01J1/304 ,  H01J2201/30453 ,  H01J2201/30469

Abstract: A process comprises combining a Ce (IV) salt dissolved in a solvent comprising water with a carbon material comprising CNT or graphene wherein the Ce (IV) salt is selected from a Ce (IV) ammonium salt of a nitrogen oxide acid, Ce (IV) ammonium salt of a sulfur oxide acid, Ce (IV) salt of a lower alkyl organo sulfur acid, or Ce (IV) salt of a lower alkane organo sulfur acid. In one embodiment the Ce (IV) salt is selected from Ce (IV) ammonium nitrate, Ce (IV) ammonium sulfate, Ce (IV) lower alkyllsulfonate, or Ce (IV) trifluoro lower alkanesulfonate. A product is produced by this process. An article of manufacture comprises this product on a substrate.

Abstract translation: 一种方法包括将溶解在包含水的溶剂中的Ce（IV）盐与包含CNT或石墨烯的碳材料组合，其中Ce（IV）盐选自氮氧化物的Ce（IV）铵盐，Ce（IV ）硫酸盐的铵盐，低级烷基有机硫酸的Ce（IV）盐或低级烷烃有机硫酸的Ce（IV）盐。 在一个实施方案中，Ce（IV）盐选自Ce（IV）硝酸铵，Ce（IV）硫酸铵，Ce（IV）低级烷基磺酸盐或Ce（IV）三氟低级链烷磺酸盐。 一个产品是通过这个过程生产的。 制品在基材上包含该产品。

公开(公告)号：US20110115363A1

公开(公告)日：2011-05-19

申请号：US13055560

申请日：2009-07-30

Applicant: Yoshihisa Ishiguro ,  Masanori Haba ,  Ryouichi Suzuki

Inventor： Yoshihisa Ishiguro ,  Masanori Haba ,  Ryouichi Suzuki

IPC: H01J9/02

CPC classification number: H01J35/065 ,  H01J1/304 ,  H01J3/021 ,  H01J2201/30453 ,  H01J2235/062

Abstract: An electron emitter includes a guard electrode 13 on the outer circumferential side of a carbon film structure 10 which is formed on a substrate 7 by plasma CVD method. This guard electrode 13 includes a curved surface portion (a curved surface portion that curves from top toward a side opposite to the film-forming direction) 13a convex in a film-forming direction of the carbon film structure 10. A curvature radius R1 of an outer-circumferential-side portion of the curved surface portion 13a is larger than or equal to a curvature radius R2 of a carbon-film-structure-side portion of the curved surface portion 13a.

Abstract translation: 电子发射体在碳膜结构体10的外周侧具有通过等离子体CVD法在基板7上形成的保护电极13。 该保护电极13包括在碳膜结构体10的成膜方向上凸出的曲面部（从顶部朝向与成膜方向相反的一侧弯曲的曲面部）13a。曲率半径R1为 曲面部13a的外周侧部分大于或等于曲面部分13a的碳膜结构侧部分的曲率半径R2。

公开(公告)号：US07635945B2

公开(公告)日：2009-12-22

申请号：US11565528

申请日：2006-11-30

Applicant: Yuan-Chao Yang ,  Jie Tang ,  Liang Liu ,  Shou-Shan Fan

Inventor： Yuan-Chao Yang ,  Jie Tang ,  Liang Liu ,  Shou-Shan Fan

IPC: H01J1/62 ,  H01J63/04

CPC classification number: H01J63/04 ,  H01J31/123 ,  H01J63/02 ,  H01J2201/30453 ,  H01J2329/86

Abstract: A field emission device (10) includes a sealed container (11) with a light-permeable portion (12). A phosphor layer (13) is formed on the light-permeable portion. A light-permeable anode (14) is formed on the light-permeable portion. At least one cathode is positioned opposite to the light-permeable anode. A shielding barrel (16) is electrically connected to the at least one cathode and disposed in the container. The shielding barrel has opposite open ends respectively facing towards the light-permeable anode and the cathode (18, 19). The shielding barrel has an inner surface, and a slurry layer (17) containing conductive nano material is formed on the inner surface of the shielding barrel.

Abstract translation: 场发射装置（10）包括具有透光部分（12）的密封容器（11）。 荧光体层（13）形成在透光部分上。 在透光部分上形成透光阳极（14）。 至少一个阴极与透光阳极相对设置。 屏蔽筒（16）电连接到至少一个阴极并且设置在容器中。 屏蔽筒具有相对的开口端，分别面向透光阳极和阴极（18,19）。 屏蔽筒具有内表面，并且在屏蔽筒的内表面上形成含有导电纳米材料的浆料层（17）。

公开(公告)号：US20090033196A1

公开(公告)日：2009-02-05

申请号：US12154035

申请日：2008-05-19

Applicant: Young-Mi Cho ,  Chang-Wook Kim ,  Hee-Sung Moon

Inventor： Young-Mi Cho ,  Chang-Wook Kim ,  Hee-Sung Moon

IPC: H01J1/02

CPC classification number: H01J1/304 ,  H01J3/021 ,  H01J2201/30426 ,  H01J2201/30453

Abstract: Electron emission sources, electron emission devices including the electron emission sources, and methods of making the electron emission sources are provided. The electron emission source includes a carbon-based material, and a degradation prevention material for preventing degradation of the carbon-based material. A binding energy between the degradation prevention material and external oxygen is greater than a binding energy between the carbon-based material and the external oxygen. The electron emission sources have excellent field emission efficiencies and long lifetimes.

Abstract translation: 提供电子发射源，包括电子发射源的电子发射装置，以及制造电子发射源的方法。 电子发射源包括碳基材料和用于防止碳基材料劣化的防分解材料。 降解防止材料和外部氧之间的结合能大于碳基材料和外部氧之间的结合能。 电子发射源具有优异的场发射效率和长寿命。

公开(公告)号：US20080174229A1

公开(公告)日：2008-07-24

申请号：US11790764

申请日：2007-04-27

Applicant: Kwang-Seok Jeong

Inventor： Kwang-Seok Jeong

IPC: H01J1/62

CPC classification number: H01J1/304 ,  H01J1/3048 ,  H01J29/04 ,  H01J31/127 ,  H01J2201/30453 ,  H01J2201/30469 ,  H01J2329/0444 ,  H01J2329/0455

Abstract: An electron emission device includes a base substrate, first electrodes on the base substrate, second electrodes electrically insulated from the first electrodes, a first insulation layer between the first electrodes and the second electrodes, electron emission source holes formed in the first insulation layer and the second electrodes to expose the first electrodes, and electron emission sources in the electron emission source holes, each electron emission source including at least one electron emission material and at least one catalyst metal nano particle.

Abstract translation: 电子发射装置包括基底基板，基底基板上的第一电极，与第一电极电绝缘的第二电极，第一电极和第二电极之间的第一绝缘层，形成在第一绝缘层中的电子发射源孔和 用于暴露第一电极的第二电极和电子发射源孔中的电子发射源，每个电子发射源包括至少一个电子发射材料和至少一个催化剂金属纳米颗粒。

公开(公告)号：WO2010002046A1

公开(公告)日：2010-01-07

申请号：PCT/KR2008/003874

申请日：2008-07-01

Applicant: KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY ,  LEE, Seung Seob ,  LEE, Seok Woo ,  LEE, Jung A

Inventor： LEE, Seung Seob ,  LEE, Seok Woo ,  LEE, Jung A

IPC: H01J1/30

CPC classification number: H01J1/3044 ,  H01J3/022 ,  H01J9/025 ,  H01J31/127 ,  H01J63/02 ,  H01J2201/30415 ,  H01J2201/30453 ,  H01J2203/0228 ,  H01J2329/0418 ,  H01J2329/0444 ,  H01J2329/4626

Abstract: Provided is a method for manufacturing a field emission array with a carbon microstructure, The method includes: a photomask attachment step of attaching a photomask with a pattern groove to one surface of a transparent substrate; a photoresist attachment step of attaching a negative photoresist to one surface of the photomask; an exposure step of irradiating light toward the opposite surface of the transparent substrate from the photomask to cure a portion of the negative photoresist with the light irradiated on the negative photoresist through the pattern groove; a developing step of removing an uncured portion of the negative photoresist while leaving the cured portion of the negative photoresist as a microstructure; a pyrolysis step of heating and carbonizing the microstructure thus obtained; and a cathode attachment step of attaching a voltage- supplying cathode to the surface of the transparent substrate on which the microstructure is formed.

Abstract translation: 本发明提供一种具有碳微观结构的场致发射阵列的制造方法。该方法包括：将具有图案槽的光掩模附着在透明基板的一个表面上的光掩模附着工序; 将负性光致抗蚀剂附着到光掩模的一个表面的光致抗蚀剂附着步骤; 曝光步骤，从所述光掩模向所述透明基板的相对表面照射光，以通过所述图案凹槽照射在所述负性光致抗蚀剂上的光来固化所述负性光致抗蚀剂的一部分; 去除负性光致抗蚀剂的未固化部分同时留下负性光致抗蚀剂的固化部分作为微结构的显影步骤; 对由此获得的微结构进行加热和碳化的热解步骤; 以及将电压供给阴极附接到其上形成微结构的透明基板的表面的阴极附着步骤。

公开(公告)号：WO2007066932A1

公开(公告)日：2007-06-14

申请号：PCT/KR2006/005149

申请日：2006-12-01

Applicant: ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE ,  KIM, Dae Jun ,  SONG, Yoon Ho ,  JEONG, Jin Woo

Inventor： KIM, Dae Jun ,  SONG, Yoon Ho ,  JEONG, Jin Woo

IPC: B82B3/00

CPC classification number: H01J9/025 ,  B22F2999/00 ,  C22C2026/002 ,  H01J1/304 ,  H01J2201/30453 ,  H01J2201/30469 ,  B22F1/0022 ,  B22F1/0018 ,  B22F1/0074

Abstract: Provided are methods of manufacturing carbon nanotube (CNT) paste, to which a nano-sized particle is added, and a CNT emitter with high reliability for a field emission display (FED). The method includes the steps of: (i) dispersing CNT powder in a solvent; (ii) adding an organic binder to the solution in which the CNT powder is dispersed; and (iii) performing a milling process to adjust viscosity of the dispersion solution to which the organic binder is added, wherein a nano-sized metal particle is added in step (i) or (iii). Accordingly, the nano-sized metal particle is added as a metal filler of the CNT paste, and thus a metal may be melted at a low temperature at which CNTs do not deteriorate. Thus, adhesion between the CNT paste and a cathode may be improved, and resistance between the cathode and the CNT or between CNTs may be reduced. Further, the CNT paste manufactured by the above method is employed in manufacturing the CNT emitter to thereby obtain uniform emission of electrons from the CNT emitter and increase electron emission sites, and thus the reliability of the CNT emitter may be further improved.

Abstract translation: 提供了制造纳米尺寸颗粒的碳纳米管（CNT）浆料和用于场发射显示（FED）的具有高可靠性的CNT发射体的方法。 该方法包括以下步骤：（i）将CNT粉末分散在溶剂中; （ii）向其中分散有CNT粉末的溶液中加入有机粘合剂; 和（iii）进行研磨过程以调节添加有机粘合剂的分散液的粘度，其中在步骤（i）或（iii）中加入纳米尺寸的金属颗粒。 因此，纳米尺寸金属颗粒作为CNT浆料的金属填料添加，因此金属可以在不劣化CNT的低温下熔融。 因此，可以提高CNT浆料和阴极之间的粘附性，并且可以降低阴极和CNT之间或CNT之间的电阻。 此外，通过上述方法制造的CNT浆料用于制造CNT发射体，从而从CNT发射体获得均匀的电子发射并增加电子发射部位，从而可以进一步提高CNT发射体的可靠性。

公开(公告)号：US20190214215A1

公开(公告)日：2019-07-11

申请号：US16311985

申请日：2017-03-16

Applicant: MEIDENSHA CORPORATION

Inventor： Daizo TAKAHASHI ,  Michihiro HATANAKA

IPC: H01J35/06 ,  H01J1/304 ,  H01J9/50

CPC classification number: H01J35/065 ,  H01J1/304 ,  H01J9/50 ,  H01J35/06 ,  H01J2201/30453 ,  H01J2235/062 ,  H01J2235/064 ,  H05G1/00

Abstract: Emitter (3) and target (7) are arranged so as to face each other in vacuum chamber (1), and guard electrode (5) is provided at outer circumferential side of electron generating portion (31) of emitter (3). Emitter (3) is supported movably in both end directions of vacuum chamber (1) by emitter supporting unit (4) having movable body (40). To perform regeneration process of guard electrode (5), emitter is moved to no-discharge position by operating emitter supporting unit, and state in which field emission of electron generating portion (31) is suppressed is set, then by applying voltage across guard electrode (5), discharge is repeated. After regeneration process, by operating emitter supporting unit again, emitter is moved to discharge position, and state in which field emission of electron generating portion (31) is possible is set with movement of movable body (40) toward the other end side being restrained by movement restraining unit (6).

公开(公告)号：US08378561B2

公开(公告)日：2013-02-19

申请号：US13055560

申请日：2009-07-30

Applicant: Yoshihisa Ishiguro ,  Masanori Haba ,  Ryouichi Suzuki

Inventor： Yoshihisa Ishiguro ,  Masanori Haba ,  Ryouichi Suzuki

IPC: H01J63/04

CPC classification number: H01J35/065 ,  H01J1/304 ,  H01J3/021 ,  H01J2201/30453 ,  H01J2235/062

Abstract: An electron emitter includes a guard electrode 13 on the outer circumferential side of a carbon film structure 10 which is formed on a substrate 7 by plasma CVD method. This guard electrode 13 includes a curved surface portion (a curved surface portion that curves from top toward a side opposite to the film-forming direction) 13a convex in a film-forming direction of the carbon film structure 10. A curvature radius R1 of an outer-circumferential-side portion of the curved surface portion 13a is larger than or equal to a curvature radius R2 of a carbon-film-structure-side portion of the curved surface portion 13a.

Abstract translation: 电子发射体在碳膜结构体10的外周侧具有通过等离子体CVD法在基板7上形成的保护电极13。 该保护电极13包括在碳膜结构体10的成膜方向上凸出的曲面部（从顶部朝向与成膜方向相反的一侧弯曲的曲面部）13a。曲率半径R1为 曲面部13a的外周侧部分大于或等于曲面部分13a的碳膜结构侧部分的曲率半径R2。