Abstract:
PURPOSE:To obtain a polyimide composition having a finely dispersed silica and excellent tensile modulus by mixing a polyamic acid with a specified compound in an organic polar solvent and cyclizing the polyamic acid through dehydration. CONSTITUTION:A polyamic acid [e.g. a polyamic acid obtained from bis(4- aminophenyl) ether and pyromellitic anhydride], an alkoxysilane and/or its partial hydrolytic condensate (e.g. tetraethoxysilane) and optionally water are mixed in an organic polar solvent (e.g. dimethylacetamide), and the polyamic acid is cyclized through dehydration.
Abstract:
PURPOSE:To form a monomolecular film or monomolecular built-up film having functions such as photoelectric transduction and magnetism or gas sensing and excellent in mechanical strengths, heat resistance and chemical resistance, by using a polyimide having a porphyrin structure as a constituting component. CONSTITUTION:This monomolecular film or monomolecular built-up film is prepared by using a polyimide having recurring units of formula I {wherein R is a tetravalent aromatic organic group (e.g., a group of formula II or III), R is porphyrin ring-containing bivalent aromatic organic group [e.g., a group of formula IV or V (wherein M is a metal such as Fe, Mg or Pb)]}. This film has functions such as photoelectric transduction and magnetism or gas sensing, excels in mechanical strengths, heat resistance and chemical resistance, and can be applied to, for example, a photoelectric transducing element, a memory and recording element or a gas sensor.
Abstract:
NEW MATERIAL:5,15-Di(4-aminophenyl)-diphenylporphyrin expressed by formula I or a porphyrin ring-containing diamine expressed by formula II. USE:A raw material for polyimides, polyamidimides, polyamides, etc., containing porphyrin. PREPARATION:For example, pyrrole is added dropwise into a solution containing p-nitrobenzaldehyde or m-nitrobenzaldehyde and benzaldehyde and refluxed to initially form a corresponding dinitro compound [example; 5,15-di(4- nitrophenyl) 10,20-diphenyl porphyrin]. Then the nitro group thereof is reduced with stannous chloride, etc.
Abstract:
PURPOSE:To readily obtain a diamond film at a low cost, by reacting a mixed gas of a hydrocarbon and hydrogen under a given pressure while discharging in a glow.arc transfer region and depositing the diamond film on a substrate provided on the anode. CONSTITUTION:The cathode 5 and anode 6 are placed in a vacuum reaction vessel 2 and a substrate for depositing diamond is placed on the anode 6. Air is excluded from an evacuation system 3 to keep the reaction vessel 1 in a vacuum and a mixed gas of a hydrocarbon gas, e.g. methane gas, and hydrogen gas is introduced from an inlet pipe 2 and kept under >=100Torr, preferably 100-1,000Torr pressure. A DC high voltage is applied from an electric power source 9 across the cathode 5 and anode 6 to react the mixed gas while discharging in a glow.arc transfer region. Thereby a diamond film is formed on the substrate provided on the anode 6. The resultant diamond film is useful for producing semiconductors, etc., related to electronics.
Abstract:
PROBLEM TO BE SOLVED: To provide an epitaxial diamond film underlaying substrate and its manufacturing method in which a diamond of high quality having a large area of ≥1 inch (2.5 cm) in diameter on an iridium substrate can be subjected to the epitaxial growth by using the CVD method, and an epitaxial diamond film manufactured by the epitaxial diamond film underlaying substrate and its manufacturing method. SOLUTION: An iridium (Ir) film is deposited by the epitaxial growth by the vacuum vapor deposition method or the sputtering method on a substrate of a single crystal magnesium oxide (MgO) or a single crystal sapphire (α-Al 2 O 3 ). The bias nucleus generation of forming an epitaxial diamond nucleus is performed by exposing DC plasma containing ions to a surface of the film-deposited iridium (Ir) substrate. COPYRIGHT: (C)2008,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a filing implement which has self-supporting properties, durability, multi-functionality and safety required as the implement, a rigid structure in a simple constitution, which can be worked at a low cost and which is suitable for housing, storing and carrying various type sheets, cards, disc or the like susceptible to a fault due to an electromagnetic wave by using a file raw material having an electromagnetic wave shielding function and to provide a method for manufacturing the same. SOLUTION: The filing implement comprises a cover part 10 made in a rectangular shape of a predetermined dimension of one file raw material F, folding pieces 11a, 11b, 12a and 12b of a required shape extended from the peripheral sides of the cover part 10, and a backbone part 14 double-folded at a center of the part 10. In this implement, the pieces 11a, 11b, 12a and 12b are folded at insides and the part 14 is folded.