公开(公告)号：KR101304325B1

公开(公告)日：2013-09-11

申请号：KR1020110038472

申请日：2011-04-25

Applicant: 한국과학기술연구원

Inventor： 이상협 ,  이동기 ,  홍석원 ,  최경진 ,  백경열

IPC: B82B3/00 ,  C08L79/00 ,  C08L81/00

Abstract: 본 발명은 표면매개물질의 요구 없이 금 나노막대 표면에 실리카를 안정적으로 코팅할 수 있는 금 나노막대의 표면 실리카 코팅 방법 및 이를 이용한 나노하이브리드 제조방법 그리고 그에 따라 제조된 나노하이브리드에 관한 것으로서, 본 발명에 따른 금 나노막대의 표면 실리카 코팅 방법은 금 나노막대를 준비하는 단계 및 아민기(amine function)를 갖는 고분자물질과 머캅토기(mercapto function)를 갖는 고분자물질이 혼합된 혼합물을, 상기 금 나노막대와 혼합, 교반하여 금 나노막대 표면에 실리카층을 코팅하는 단계를 포함하여 이루어지는 것을 특징으로 한다.

公开(公告)号：KR1020130091891A

公开(公告)日：2013-08-20

申请号：KR1020120013210

申请日：2012-02-09

Applicant: 한국과학기술연구원 ,  주식회사 삼양사

Inventor： 이상협 ,  이영행 ,  김연석 ,  백경열

IPC: B01J41/12 ,  C08J7/12 ,  C08F12/08 ,  B01J47/00

CPC classification number: B01J41/12 ,  C08F12/08 ,  C08J5/2243 ,  C08J2325/08

Abstract: PURPOSE: An ion-exchange resin and a manufacturing method thereof are provided. Under the manufacturing method of the ion-exchange resin, the formation of methyl chloride is maximized to produce an ion-exchange resin with high functionality and the specific surface area of the ion-exchange resin is maximized to increase the ion exchange capacity of the ion-exchange resin. CONSTITUTION: A manufacturing method of an ion-exchange resin comprises the steps of: preparing a macromolecular bead by mixing styrene monomer and divinyl benzene in an aqueous solution, mixing the macromolecular bead in the aqueous solution, alkyl halide material, and a reaction catalyst to drive the chloromethylation reaction for producing a resin with methyl chloride, and reacting the resin having methyl chloride with amine material to attach an amine group to the resin with methyl chloride. In the steps, the organic solvent is dichloroethane, the alkyl halide material is chloromethylmethylether and the reaction catalyst is ferric chloride (FeCl3). [Reference numerals] (AA) Styrene / Divinylbenzene; (BB) Polymer bead; (CC) CM resin; (DD) Resin after amine reaction; (EE) Resin after OH regeneration reaction

Abstract translation: 目的：提供一种离子交换树脂及其制造方法。 在离子交换树脂的制造方法中，最大限度地形成氯甲烷以产生具有高官能度的离子交换树脂，离子交换树脂的比表面积最大化以提高离子的离子交换容量 交换树脂。 构成：离子交换树脂的制造方法包括以下步骤：通过在水溶液中混合苯乙烯单体和二乙烯基苯来制备高分子珠，将高分子珠在水溶液中混合，将卤代烷烃物质和反应催化剂混合 驱动氯甲基化反应，用甲基氯制备树脂，并使具有甲基氯的树脂与胺材料反应，将胺基与甲基氯连接。 在这些步骤中，有机溶剂是二氯乙烷，烷基卤物质是氯甲基甲基醚，反应催化剂是氯化铁（FeCl 3）。 （AA）苯乙烯/二乙烯基苯; （BB）聚合物珠; （CC）CM树脂; （DD）胺反应后的树脂; （EE）OH再生反应后的树脂

公开(公告)号：KR1020130076231A

公开(公告)日：2013-07-08

申请号：KR1020110144741

申请日：2011-12-28

Applicant: 코오롱인더스트리 주식회사 ,  한국과학기술연구원

Inventor： 최진식 ,  채헌승 ,  이동희 ,  백경열 ,  김현지 ,  김성혜

IPC: C08F6/08 ,  B01D15/36 ,  C08F34/00 ,  C08F8/04

CPC classification number: C08F6/02 ,  C08G61/06 ,  C08G2261/3324 ,  C08G2261/418

Abstract: PURPOSE: A method for removing metal-containing catalyst is provided to effectively remove catalyst metals which are obligatorily added into the polymerization and hydrogenation process of cyclic olefinic polymers, thereby providing high purity cyclic olefinic polymers with high yield. CONSTITUTION: A method for removing a metal-containing catalyst, removing metal-containing catalyst residues from cyclic olefinic polymers which are obtained through the polymerization and hydrogenation process of random cyclic olefinic monomers, includes a step of treating the solution of the cyclic olefinic polymers containing a tungsten-containing catalyst residue, an aluminum-containing catalyst residue, and a ruthenium-containing residue by a functionalized ion exchange resin which is macroporous and is modified by one or more functional groups selected from a primary amine, a secondary amine, and a hydroxyl group.

Abstract translation: 目的：提供一种去除含金属催化剂的方法，以有效地除去强制加入到环烯烃聚合物的聚合和加氢过程中的催化剂金属，从而以高产率提供高纯度环烯烃聚合物。 构成：通过无规环状烯属单体的聚合和氢化方法除去含金属的催化剂，去除由环状烯烃聚合物形成的含金属的催化剂残留物的方法包括以下步骤：处理含有 含钨催化剂残渣，含铝催化剂残余物和含钌残基的官能化离子交换树脂，该功能化离子交换树脂是大孔的，并被一个或多个选自伯胺，仲胺和 羟基。

公开(公告)号：KR101249798B1

公开(公告)日：2013-04-03

申请号：KR1020100079633

申请日：2010-08-18

Applicant: 한국과학기술연구원

Inventor： 황승상 ,  홍순만 ,  곽순종 ,  백경열 ,  구종민 ,  최승석 ,  이성수

IPC: C08G77/06 ,  C08G77/08 ,  C08G77/34

CPC classification number: C08G77/08 ,  C08G77/06

Abstract: 본 발명은 트리 알콕시 실록산 단량체를 통해 폴리실세스퀴옥산을 중합하는 방법으로서, 트리 알콕시 실록산 단량체, 유기 용매, 물 및 촉매를 포함하는 함수 유기용액을 제조하는 단계; 및 상기 함수 유기용액 중 유기 용매의 양 또는 함수량을 조절하는 단계를 포함하여 바구니형 폴리실세스퀴옥산 또는 사다리형 폴리실세스퀴옥산을 선택적으로 제조하는 것을 특징으로 하는 방법 및 이에 의해 제조된 바구니형 폴리실세스퀴옥산 또는 사다리형 폴리실세스퀴옥산에 관한 것이다.

公开(公告)号：KR1020120009731A

公开(公告)日：2012-02-02

申请号：KR1020100070201

申请日：2010-07-20

Applicant: 한국과학기술연구원

Inventor： 곽순종 ,  육주영 ,  황승상 ,  홍순만 ,  구종민 ,  백경열

IPC: C09J7/02 ,  C09J5/04 ,  C09J183/02 ,  B32B37/00

CPC classification number: C09J7/22 ,  B32B37/0038 ,  C09J5/04 ,  C09J183/02 ,  C09J2205/10 ,  C09J2205/31

Abstract: PURPOSE: A plastic-organic/inorganic hybrid adhesive film is provided to remarkably improve binding strength between a plastic material and an organic/inorganic hybrid film, thereby using for insulative coating, a film for hard coating, various display materials, etc. CONSTITUTION: A plastic-organic/inorganic hybrid adhesive film comprises a plastic material, and an organic/inorganic hybrid film adhered to the surface of the surface of the plastic material through a chemical bond. The chemical bond is generated by a ring-opening reaction between a reactive amine functional group, which is chemically combined to the surface of the plastic material, and an epoxy silane coupling agent in the organic/inorganic hybrid film.

Abstract translation: 目的：提供塑料 - 有机/无机复合粘合剂膜，以显着提高塑料材料与有机/无机混合膜之间的结合强度，从而用于绝缘涂层，硬涂层用膜，各种显示材料等。构成： 塑料 - 有机/无机混合粘合剂膜包括塑料材料和通过化学键粘附到塑料材料表面的有机/无机杂化膜。 化学键是通过与塑料材料的表面化学结合的反应性胺官能团和有机/无机混合膜中的环氧硅烷偶联剂之间的开环反应产生的。

公开(公告)号：KR1020110119278A

公开(公告)日：2011-11-02

申请号：KR1020100038894

申请日：2010-04-27

Applicant: 한국과학기술연구원

Inventor： 구종민 ,  홍순만 ,  황승상 ,  백경열 ,  곽순종 ,  김명희 ,  김보리 ,  곽희라 ,  민경호 ,  박윤덕

IPC: H01L41/053 ,  H01L41/45

CPC classification number: H01L41/193 ,  H01L41/0986 ,  H01L41/45

Abstract: PURPOSE: A polymer composite actuator is provided to improve the distribution of fillers by using elastic elements including maleic anhydride, acryl, urethane, carboxyl group and amine groups. CONSTITUTION: An elastic dielectric layer(3a) includes an elastomer and polymer composite. The elastomer includes a polar group. The polymer composite includes one or more conductive or high dielectric fillers. A top electrode is attached to one surface of the elastic dielectric layer. A bottom electrode(3b) is attached to the surface of the elastic dielectric layer opposite to the surface with the top electrode.

Abstract translation: 目的：提供聚合物复合促进剂，通过使用马来酸酐，丙烯酸，氨基甲酸酯，羧基和胺基等弹性元素改善填料的分布。 构成：弹性介电层（3a）包括弹性体和聚合物复合材料。 弹性体包括极性基团。 聚合物复合材料包括一种或多种导电或高介电填料。 顶部电极附接到弹性介电层的一个表面。 底部电极（3b）与顶部电极附接到与表面相反的弹性介电层的表面。

公开(公告)号：KR1020110118890A

公开(公告)日：2011-11-02

申请号：KR1020100038276

申请日：2010-04-26

Applicant: 한국과학기술연구원

Inventor： 백경열 ,  황승상 ,  최승석 ,  이성수 ,  이희승 ,  오성연

IPC: C09K11/06 ,  H01L51/50

CPC classification number: C08G77/26 ,  H01L51/0094 ,  H01L51/5012 ,  Y02E10/549 ,  Y10T428/24355 ,  H01L51/0003 ,  H01L51/0044

Abstract: PURPOSE: A light-emitting material is provided to ensure excellent heat resistance and mechanical properties and high light emitting efficiency and to eliminate the disadvantages of a POSS structure with weak thin film properties. CONSTITUTION: A light-emitting material comprises polysilsesquioxane having a ladder structure where a photoactive group is bonded to a siloxane main chain. The polysilsesquioxane is represented by chemical formula 1. In chemical formula 1, R is a functional group having optical activity by a double or triple bond within a phenyl-based monocyclic group, a heterocyclic group thereof or cyclic group, or a derivative thereof, wherein the phenyl-based monocyclic group includes a substituted or unsubstituted phenylene, pyrene, rubrene, coumarin, oxazine, carbazole, thiophene, iridium, porphyrin, and azo-based dye functional groups; and n is 1-100,000.

Abstract translation: 目的：提供发光材料，以确保优异的耐热性和机械性能和高发光效率，并消除具有弱薄膜性能的POSS结构的缺点。 构成：发光材料包括具有光活性基团与硅氧烷主链结合的梯形结构的聚倍半硅氧烷。 聚倍半硅氧烷由化学式1表示。在化学式1中，R是在苯基单环基团，其杂环基团或环状基团或其衍生物中具有双键或三键的光学活性的官能团，其中 苯基单环基团包括取代或未取代的亚苯基，芘，红荧烯，香豆素，恶嗪，咔唑，噻吩，铱，卟啉和偶氮类染料官能团; n为1-100,000。

公开(公告)号：KR101071924B1

公开(公告)日：2011-10-11

申请号：KR1020080114066

申请日：2008-11-17

Applicant: 한국과학기술연구원

Inventor： 구종민 ,  홍순만 ,  황승상 ,  곽순종 ,  백경열

IPC: B01D71/00

Abstract: 본발명은다공성전이금속산화촉매분리막및 이의제조방법에관한것으로, 구체적으로 1) 나노구조주형으로서블록공중합체, 계면활성제, 유기고분자및 이들의혼합물중의어느하나, 1종이상의전이금속화합물, 및/또는실리카전구체를상온에서용매에혼합하는단계; 2) 상기혼합물을판상또는중공사분리막형태의틀에채운후 이로부터용매를제거하여나노구조를형성하고그 구조내에전이금속및/또는실리카를담지시키는단계; 및 3) 상기혼합물을 150 내지 1,000℃의온도에서 1 내지 24시간동안소결하여나노구조주형을제거하는단계에의해제조되는다공성전이금속산화촉매분리막및 이의제조방법에관한것이다. 본발명에따른다공성전이금속산화촉매분리막은다양한크기의다중기공구조를가져비표면적이매우크고산화효율이우수할뿐만아니라연속공정으로의처리가가능하여폐수, 특히난분해성유기물을함유한폐수의처리에유용하게사용될수 있다.

公开(公告)号：KR1020110087713A

公开(公告)日：2011-08-03

申请号：KR1020100007270

申请日：2010-01-27

Applicant: 한국과학기술연구원

Inventor： 구종민 ,  홍순만 ,  황승상 ,  곽순종 ,  백경열 ,  민경호 ,  박윤덕 ,  김보리 ,  김명희 ,  곽희라 ,  황보민영

IPC: H02N2/02 ,  H01L41/193

CPC classification number: H02N2/04 ,  H01L41/0472 ,  H01L41/193 ,  H02N2/22 ,  Y10S310/80

Abstract: PURPOSE: A transparent and flexible electrode and a polymer actuator using the same are provided to prevent a problem that a cracking is created in an electrode material when voltage is applied to apply the flexible actuator to many field of applications in which transparency is necessary. CONSTITUTION: A flexible a first transparent electrode layer(2a) and a second transparent electrode(2b) is laminated on at least one transparent elasticity dielectric layer. The first transparent electrode layer and the second transparent electrode include a binder. The binder includes PEDOT(Poly ethylene-dioxy-thiophene). Power supply connectors(11a,11b) are connected to the first transparent electrode layer and the second transparent electrode, respectively. Transmittance about visible ray is over 50%.

Abstract translation: 目的：提供透明和柔性电极和使用其的聚合物致动器，以防止在施加电压时在电极材料中产生裂纹的问题，以将柔性致动器应用于需要透明度的许多应用领域。 构成：柔性的第一透明电极层（2a）和第二透明电极（2b）层叠在至少一个透明弹性介电层上。 第一透明电极层和第二透明电极包括粘合剂。 粘合剂包括PEDOT（聚乙烯 - 二氧噻吩）。 电源连接器（11a，11b）分别连接到第一透明电极层和第二透明电极。 关于可见光的透射率超过50％。

公开(公告)号：KR1020090124613A

公开(公告)日：2009-12-03

申请号：KR1020080050926

申请日：2008-05-30

Applicant: 한국과학기술연구원

Inventor： 안수미 ,  황승상 ,  백경열 ,  최승석 ,  강상욱

IPC: C07D409/04 ,  C07D249/02

CPC classification number: C08G61/126 ,  C08G2261/1412 ,  C08G2261/1646 ,  C08G2261/3223 ,  C08G2261/92

Abstract: PURPOSE: A method for functionalizing polyalkylthiophene terminal is provided to produce highly functional polyalkylthiophene of semiconductor layer for organic thin film transistor. CONSTITUTION: A method for functionalizing polyalkylthiophene terminal comprises: a step of polymerizing 2-bromot-3-funtional thiopene under the presence of catalyst containing LDA(lithium diisopropylamide), zinc chloride(ZnCl2) and (1,3-bis(diphenylphosphino)propane)dichlronikel(II); a step of reacting with grignard reagent of chemical formula 2(CH≡C-MgBr) to produce polyalkylthiophene having introduced alkyne group at terminal of chemical formula 3; and a step of reacting the polyalkylthiophene with azide compound of chemical formula 4(N3-R3).

Abstract translation: 目的：提供用于官能化聚烷基噻吩末端的方法，以制备用于有机薄膜晶体管的半导体层的高官能度聚烷基噻吩。 构成：聚烷基噻吩末端官能化的方法包括：在含有LDA（二异丙基氨基锂），氯化锌（ZnCl 2）和（1,3-双（二苯基膦基）丙烷）的催化剂存在下聚合2-溴-3-功能硫代萘的步骤 ）dichlronikel（II）; 与化学式2（CH≡C-MgBr）的格氏试剂反应生成在化学式3末端引入炔基的聚烷基噻吩的步骤; 和使聚烷基噻吩与化学式4（N 3 -R 3）的叠氮化合物反应的步骤。