公开(公告)号：MY136768A

公开(公告)日：2008-11-28

申请号：MYPI20033358

申请日：2003-09-05

Applicant: BASF AG

Inventor： PINKOS ROLF DR ,  GERSTLAUER ACHIM DR ,  HAUBNER MARTIN DR ,  SCHLITTER STEPHAN DR ,  KAESHAMMER STEFAN DR ,  PFAFF KLAUS-PETER DR

IPC: C08G65/20

Abstract: THE PRESENT INVENTION PROVIDES A PROCESS FOR PREPARING MONO- OR DIESTERS OF POLYTETRAHYDROFURAN OR OF TETRAHYDROFFURAN COPOLYMERS BY POLYMERIZING TETRAHYDROFURAN IN THE PRESENCE OF AT LEAST ONE TELOGEN AND /OR OF A COMONOMER OVER AN ACIDIC CATALYST, WHEREIN THE POLYMERIZATION REACTOR IS STARTED UP USING A MIXTURE OF POLYTETRAHYDROFURAN ,THE MONO- OR DIESTERS OF POLYTETRAHYDROFURAN AND/OR OF THE THF COPOLYMERS, TETRAHYDROFURAN , ANY COMONOMER AND AT LEAST ONE CARBOXYLIC ACID AND /OR ONE CARBOXYLIC ANHYDRIDE.

公开(公告)号：MY136380A

公开(公告)日：2008-09-30

申请号：MYPI20032872

申请日：2003-07-30

Applicant: BASF AG

Inventor： PINKOS ROLF DR ,  KAESHAMMER STEFAN DR ,  MENGER VOLKMAR DR ,  HAUBNER MARTIN DR ,  GROLL PETER DR ,  SCHLITTER STEPHAN DR ,  PFAFF KLAUS-PETER DR

IPC: C07D307/08 ,  C08G65/20 ,  C08G65/26

Abstract: THE INVENTION RELATES TO A PROCESS FRO THE CONTINUOUS PREPARATION OF THF BY REACTION OF A 1, 4-BUTANEDIOL-CONTAINING REACTION MIXTURE OVER A HETEROPOLYACID CATALYST WHICH HAS NOT BEEN PREDRIED, WHEREIN THE REACTION MIXTURE COMPRISES 2-(4-HYDROXYBUTOXY) TETRAHYDROFURAN.

公开(公告)号：SI1008573T1

公开(公告)日：2002-10-31

申请号：SI9930070

申请日：1999-11-18

Applicant: BASF AG

Inventor： PINKOS ROLF DR

IPC: B01J31/24 ,  C07B61/00 ,  C07C5/05 ,  C07C5/09 ,  C07C13/263 ,  C07C13/275

Abstract: A carboxylic acid is used in a process to hydrogenate polyene compounds to monoenes using a ruthenium catalyst. A process to hydrogenate a polyene to a monoene uses a ruthenium catalyst in the presence of a carboxylic acid.

公开(公告)号：CZ164398A3

公开(公告)日：1998-09-16

申请号：CZ164398

申请日：1996-11-18

Applicant: BASF AG

Inventor： BROCKER FRANZ JOSEF DR ,  FISCHER ROLF DR ,  KAIBEL GERD DR ,  PINKOS ROLF DR

IPC: B01J37/02 ,  C07D307/08 ,  C23C14/16

Abstract: PCT No. PCT/EP96/05071 Sec. 371 Date May 22, 1998 Sec. 102(e) Date May 22, 1998 PCT Filed Nov. 18, 1996 PCT Pub. No. WO97/19939 PCT Pub. Date Jun. 5, 1997In a process for the catalytic hydrogenation of 2,5- and 2,3-dihydrofuran with hydrogen to give tetrahydrofuran, use is made of a catalyst in which a metal or a plurality of metals have been deposited by vapor deposition or sputtering on a metal wire mesh or a metal foil as support.

公开(公告)号：DE19622497A1

公开(公告)日：1997-12-11

申请号：DE19622497

申请日：1996-06-05

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PINKOS ROLF DR

IPC: B01J23/36 ,  B01J23/72 ,  B01J31/24 ,  C07B61/00 ,  C07C41/01 ,  C07C41/26 ,  C07C41/30 ,  C07C43/13 ,  C07C43/15 ,  C07C43/178 ,  C07D307/08 ,  C07C43/10 ,  C07C41/20 ,  C07C11/08 ,  C07C6/00

Abstract: The invention concerns a process for preparing tetrahydrofuran by reacting 1,4-butene diol diethers of formulae (I) -RO-CH2-CH=CH-CH2-OR and/or (II) -RO-CH2-CH2=CH-CH2-OR, in which the R groups can be identical or different and stand for C1-C15 alkyl or cycloalkyl groups, C6-C12 aryl groups or C7-C15 aralkyl groups, with water and hydrogen at temperatures of between 20 and 300 DEG C and a pressure of between 1 and 300 bar in the presence of catalysts or catalyst combinations which both contain components which can hydrogenate and comprise acid or basic centres. The invention further concerns a novel process for preparing the 1,4-butene diol diethers of formula (I) by metathesis.

公开(公告)号：DE59205953D1

公开(公告)日：1996-05-15

申请号：DE59205953

申请日：1992-10-15

Applicant: BASF AG

Inventor： PINKOS ROLF DR ,  FISCHER ROLF DR

IPC: C07B61/00 ,  B01J29/90 ,  C07C29/04 ,  C07C35/08

Abstract: Process for the preparation of cycloalkanols by reacting cycloolefins with water in the presence of solid, acidic catalysts at a temperature from 50 to 280 DEG C under superatmospheric pressure, with the proviso that the pressure and temperature conditions suffice for the formation of a liquid phase of water and cycloolefins, characterised in that a mixture of water and cycloolefin is passed through a layer of solid, acidic catalysts which is held in a fixed position, with the proviso that no visible liquid phase is formed in this layer.

公开(公告)号：DE4422671A1

公开(公告)日：1996-01-04

申请号：DE4422671

申请日：1994-06-30

Applicant: BASF AG

Inventor： FISCHER MARTIN DR ,  FISCHER ROLF DR ,  JOHN MICHAEL DR ,  PINKOS ROLF DR

IPC: B01J27/053 ,  B01J27/122 ,  B01J27/14 ,  B01J27/232 ,  B01J31/04 ,  C07B61/00 ,  C07D307/28

Abstract: Method for the prepn. of 2,5-dihydrofurans of formula (I) by the catalytic rearrangement of 3,4-epoxybutene of formula (II) in the liq. phase, in the presence of a novel catalyst comprising one or more copper (I) salts; R1-R6 = H or 1-4C alkyl.

公开(公告)号：DE4339269A1

公开(公告)日：1995-05-24

申请号：DE4339269

申请日：1993-11-18

Applicant: BASF AG

Inventor： PINKOS ROLF DR ,  FISCHER ROLF DR

IPC: C07D307/33 ,  B01J23/36 ,  B01J23/656 ,  B01J23/72 ,  B01J23/86 ,  C07B61/00 ,  C07D307/32 ,  C07D315/00 ,  B01J23/64

Abstract: PCT No. PCT/EP94/03683 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 9, 1994 PCT Pub. No. WO95/14010 PCT Pub. Date May 26, 1995A process for the preparation of gamma -butyrolactone, in which 2,5-dihydrofuran or 2,3-dihydrofuran or a mixture of these two dihydrofurans is caused to react in the gas phase in the presence of water and in the presence or absence of additional hydrogen at elevated temperature over a hydrogenating catalyst.

公开(公告)号：DE4429700A1

公开(公告)日：1995-03-02

申请号：DE4429700

申请日：1994-08-22

Applicant: BASF AG

Inventor： PINKOS ROLF DR ,  FISCHER ROLF DR

IPC: B01J23/36 ,  C07C29/10 ,  C07C33/035 ,  C07C41/03 ,  C07C67/26 ,  C07C29/128

Abstract: Process for reacting vinyl oxiranes of the formula in which R and R are identical or different and represent a hydrogen atom or C1- to C5-alkyl, with oxygen nucleophiles in the presence of rhenium-containing catalysts to give butenediols and butenediol derivatives of the formulae in which R and R are identical or different and represent a hydrogen atom, an aliphatic radical having 1 to 10 C atoms or , where R is hydrogen or an aliphatic, cycloaliphatic, araliphatic or aromatic radical having 1 to 15 C atoms, and R to R have the abovementioned meanings.

公开(公告)号：DE4321843A1

公开(公告)日：1995-01-12

申请号：DE4321843

申请日：1993-07-01

Applicant: BASF AG

Inventor： PINKOS ROLF DR ,  FISCHER ROLF DR

IPC: C07D207/26 ,  C07D207/267 ,  C07D207/32 ,  C07D207/323 ,  C07D295/02 ,  C07D295/023 ,  C07D295/00 ,  C07D207/04 ,  C07D207/08 ,  C07C213/04 ,  B01J23/44 ,  B01J23/72 ,  B01J23/70 ,  B01J23/00 ,  B01J31/28 ,  B01J27/122 ,  B01J27/06

Abstract: Nitrogen five-membered ring heterocycles of the formula I in which R , R , R , R , R , R , R and R are hydrogen or R is C1- to C10-alkyl, C1- to C10-hydroxyalkyl, C1- to C10-aminoalkyl, aryl, C7- to C10-aralkyl or C7- to C10-alkylaryl, R and R are C1- to C8-alkyl, R and R together are oxygen, with the proviso that R is hydrogen, R and R and/or R and R or R and R together are a bond, are prepared by reacting vinyloxiranes of the formula II in which R and R have the abovementioned meanings, with ammonia or primary amines of the formula III R - NH2 in which R has the abovementioned meanings, in the presence of a compound of an element of sub-group VIII or of sub-group I of the Periodic Table of the Elements, optionally with addition of a Lewis acid, at temperatures from 20 to 200 DEG C and pressures from 1 to 70 bar, and then cyclising in the presence of hydrogen and of a hydrogenation catalyst at temperatures from 150 to 350 DEG C and pressures from 0.1 to 300 bar.