公开(公告)号：JP2002371064A

公开(公告)日：2002-12-26

申请号：JP2002157090

申请日：2002-05-30

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

Inventor： BOETTCHER ARND ,  PINKOS ROLF DR ,  LORENZ RUDOLF ERICH ,  BECKER HEIKE

IPC: C07D201/16 ,  C07D223/10 ,  C08F2/38

CPC classification number: C07D223/10 ,  C07D201/16

Abstract: PROBLEM TO BE SOLVED: To provide a method for purifying N-vinyl-ε-caprolactam for producing an N-vinyl-ε-caprolactam hardly manifesting any sensibility for color changes, i.e., having high color stability higher than that of usual N-vinyl-ε-caprolactam obtained by distillation.
SOLUTION: N-vinyl-ε-caprolactam to be purified having at least 95 mass % purity is changed to a molten liquid, which is partially crystallized and the crystal is separated from the mother liquid.
COPYRIGHT: (C)2003,JPO

Abstract translation: 要解决的问题：提供一种N-乙烯基-ε-己内酰胺的纯化方法，用于制造几乎不表现出颜色变化的任何敏感性的N-乙烯基-ε-己内酰胺，即具有比通常的N-乙烯基 通过蒸馏获得的ε-己内酰胺。 解决方案：将具有至少95质量％纯度的待纯化的N-乙烯基-ε-己内酰胺改变为部分结晶并将晶体与母液分离的熔融液。

公开(公告)号：JP2002284728A

公开(公告)日：2002-10-03

申请号：JP2002003435

申请日：2002-01-10

Applicant: BASF AG

Inventor： LORENZ RUDOLF ERICH ,  BOETTCHER ARND ,  BECKER HEIKE ,  PINKOS ROLF DR

IPC: C07B63/04 ,  C07C41/46 ,  C07C43/16 ,  C07D223/10 ,  C08F2/00

Abstract: PROBLEM TO BE SOLVED: To obtain an alkenyl compound stabilized in a color number having a remarkably low color number for expressing no tendency to be colored after a storage of longer period of several months or extremely slight coloration with avoiding an expensive cost. SOLUTION: The color number of an alkenyl compound having a divalent or a trivalent heteroatom at α position to a double bond is stabilized and/or lowered mixing an oxidizing agent with the alkenyl compound.

公开(公告)号：JPH10114705A

公开(公告)日：1998-05-06

申请号：JP24899897

申请日：1997-09-12

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PINKOS ROLF DR ,  RIEBER NORBERT DR ,  SCHULZ MICHAEL DR ,  TELES JOAQUIM HENRIQUE DR

IPC: B01J27/128 ,  B01J27/138 ,  B01J31/02 ,  B01J31/12 ,  C07B61/00 ,  C07C27/02 ,  C07C35/06 ,  C07C67/03 ,  C07C67/04 ,  C07C69/06

Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound in a short time without generating a coupling product and effectively utilizing the starting substances by reacting a specific cyclopentene with formic acid in the presence of an acidic catalyst. SOLUTION: The objective cyclopentyl formate of the formula II is produced by reacting (A) 1mol of a cyclopentene compound of the formula I (R1 to R3 are each H or a 1-8C alkyl, preferably a 1-4C alkyl) with (B) 0.1-25mol of formic acid in the presence of (C) 0.0001-25mol of an acidic catalyst (e.g. a Lewis acid) at -80 to +200 deg.C, preferably 35-80 deg.C. The component A is available as a 5C stream from a cracking apparatus or an oil refinery plant. Cyclopentyl formate is useful as a production raw material for cyclopentanol.

公开(公告)号：MY146257A

公开(公告)日：2012-07-31

申请号：MYPI20053905

申请日：2005-08-19

Applicant: BASF AG

Inventor： WINDECKER GUNTHER ,  WECK ALEXANDER ,  ROESCH MARKUS DR ,  STEINIGER MICHAEL DR ,  PINKOS ROLF DR ,  HAUTTE DANY VANDEN

IPC: C07D307/08

Abstract: THE PRESENT INVENTION PROVIDES A PROCESS FOR DISTILLATIVELY PURIFYING TETRAHYDROFURAN IN THE PRESENCE OF A POLAR SOLVENT.

公开(公告)号：MY138082A

公开(公告)日：2009-04-30

申请号：MYPI20034951

申请日：2003-12-22

Applicant: BASF AG

Inventor： SCHLITTER STEPHAN DR ,  HAUBNER MARTIN DR ,  ZEHNER PETER DR ,  HESSE MICHAEL DR ,  WECK ALEXANDER ,  PINKOS ROLF DR ,  XDFLER THOMAS GRA DR

IPC: C08G65/26

Abstract: THE PRESENT INVENTION RELATES TO A PROCESS FOR PREPARING POLYTETRAHYDROFURAN, POLYTETRAHYDROFURAN COPOLYMER, DIESTER OR MONOESTER BY POLYMERIZING TETRAHYDROFURAN IN THE PRESENCE OF AT LEAST ONE TELOGEN AND/OR COMONOMER AND OF AN ACIDIC HETEROGENEOUS CATALYST BASED ON ACTIVATED SHEET OR MIXED METAL OXIDES IN A FLUIDIZED BED.

公开(公告)号：MY119458A

公开(公告)日：2005-05-31

申请号：MYPI9704749

申请日：1997-10-10

Applicant: BASF AG

Inventor： BROCKER FRANZ JOSEF ,  KAIBEL GERD ,  WULFF-DORING JOACHIM ,  BECKER RAINER ,  PINKOS ROLF DR

IPC: B01J25/02 ,  C07C29/17 ,  B01J8/02 ,  B01J8/06 ,  B01J10/00 ,  B01J19/00 ,  B01J19/24 ,  B01J19/26 ,  C07B61/00 ,  C07C31/20

Abstract: A PROCESS FOR PREPARING 1, 4-BUTANEDIOL BY CONTINUOUS CATALYTIC HYDROGENATION OF 1, 4-BUTYNEDIOL COMPRISES REACTING 1, 4-BUTYNEDIOL WITH HYDROGEN IN THE LIQUID CONTINUOUS PHASE IN THE PRESENCE OF A HETEROGENEOUS HYDROGENATION CATALYST AT FROM 20 TO 300°C, A PRESSURE OF FROM 1 TO 200 BAR AND VALUES OF THE LIQUID-SIDE VOLUMETRIC MASS TRANSFER COEFFICIENT KLA OF FROM 0.1 S-1 TO 1 S-1 A)USING A CATALYST SUSPENDED IN THE REACTION MEDIUM, WHERE IF A PACKED BUBBLE COLUMN IS EMPLOYED THIS IS OPERATED IN THE UPFLOW MODE AND AT A RATIO OF GAS LEAVING THE REACTION VESSEL TO GAS FED TO THE REACTION VESSEL OF FROM 0.99:1 TO 0.4:1, OR B)PASSING THE LIQUID AND GAS IN COCURRENT IN AN UPWARD DIRECTION THROUGH A FIXED-BED REACTOR OPERATED IN THE GAS-CIRCULATION MODE WHILE MAINTAINING A RATIO OF THE GAS FED TO THE REACTION VESSEL TO GAS LEAVING THE REACTION VESSEL OF FROM 0.99:1 TO 0.4:1.

公开(公告)号：ES2178334T3

公开(公告)日：2002-12-16

申请号：ES99122885

申请日：1999-11-18

Applicant: BASF AG

Inventor： PINKOS ROLF DR

IPC: B01J31/24 ,  C07B61/00 ,  C07C5/05 ,  C07C5/09 ,  C07C13/263 ,  C07C13/275

Abstract: A carboxylic acid is used in a process to hydrogenate polyene compounds to monoenes using a ruthenium catalyst. A process to hydrogenate a polyene to a monoene uses a ruthenium catalyst in the presence of a carboxylic acid.

公开(公告)号：DE19750532A1

公开(公告)日：1999-05-20

申请号：DE19750532

申请日：1997-11-14

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PINKOS ROLF DR ,  STEIN FRANK DR

IPC: C07B61/00 ,  C07C29/149 ,  C07C29/80 ,  C07C31/20 ,  C07C51/367 ,  C07C62/02 ,  C07C67/31 ,  C07C69/675 ,  C07C29/74 ,  C07C59/01

Abstract: A process for the production of 1,6-hexanediol and 6-hydroxycaproic acid or their esters by catalytic hydrogenation of adipic acid, adipic acid monoesters or adipic acid diesters or of product streams that contain adipic acid or esters as essential components. The hydrogenated mixture is distilled to separate hexanediol, 6-hydroxycaproic acid and/or their esters and the bottoms product containing oligomeric esters of 6-hydroxycaproic acid is recycled to the hydrogenation step. The mixture to product and recycle stream is hydrogenated at 100-300 deg C and 10-300 bar in the liquid phase in the presence of a catalyst with a molar ratio of carboxyl groups to hydrogen of 1:5-1:100.

公开(公告)号：DE19725533A1

公开(公告)日：1998-12-24

申请号：DE19725533

申请日：1997-06-17

Applicant: BASF AG

Inventor： EBEL KLAUS DR ,  PINKOS ROLF DR

IPC: B01J23/80 ,  C07B61/00 ,  C07C29/149 ,  C07C29/36 ,  C07C31/133 ,  C07C51/353 ,  C07C67/347 ,  C07C53/134

Abstract: The invention relates to an advantageous method for industrial production of sought-after odoriferous musk root substances 2-cyclododecyl-propanol by reacting cyclododecene in the presence of catalytic amounts of a radical initiator with an excess of propionic acid or propionic acid derivative and subsequent catalytic hydrogenation of the formed 2-cyclododecyl propionic acid or the corresponding 2-cyclododecyl propionic acid derivatives.

公开(公告)号：DE59308777D1

公开(公告)日：1998-08-20

申请号：DE59308777

申请日：1993-12-08

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PINKOS ROLF DR

IPC: C07D201/02 ,  C07D207/26 ,  C07D207/267 ,  C07D307/32 ,  C07D307/33 ,  C07D315/00

Abstract: Process for the preparation of 5-membered heterocycles of the general formula I in which R is methyl or hydroxyethyl, R , R , R , R and R are hydrogen, C1- to C12-alkyl, C 2- to C12-alkenyl, aryl, C3- to C8-cycloalkyl, C1- to C12-alkoxy, halogen, C2- to C20-alkoxycarbonylalkyl, C2- to C20-alkylcarbonyloxy, formyl, C2- to C20-formylalkyl, benzoyl, -CH(OR )(OR ), or R and R together are a C2- to C7-alkylene chain which is optionally monosubstituted to pentasubstituted by R or a =CH-CH=CH-CH= unit which is optionally monosubstituted to tetrasubstituted by R , and X is oxygen or N-R , by reacting 5-membered heterocycles of the general formula II in which R , R , R , R , R and X have the abovementioned meaning and Y is hydrogen, acetyl or C2- to C20-alkoxycarbonyl, with dimethyl carbonate or ethylene carbonate in the presence of a nitrogen-containing base at temperatures from 50 to 300@C and pressures from 0.01 to 50 bar.