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公开(公告)号:DE10056251B4
公开(公告)日:2006-06-08
申请号:DE10056251
申请日:2000-11-14
Applicant: BASF AG
Inventor: BIEDERMANN ANJA , KRECH RUEDIGER , ROTERMUND UDO , REICHELT MICHAEL
Abstract: Polyurethane foam is produced by processing the reaction mixture (polyisocyanates and compounds with at least two NCO-reactive hydrogen atoms) in an extruder in which the pressure is higher than atmospheric pressure. A method for the production of polyurethane foam by reacting polyisocyanates with compounds containing at least two hydrogen atoms which react with isocyanate groups involves (a) mixing these reactants, (b) feeding the mixture into an extruder in which the internal pressure is above atmospheric pressure, (c) extruding the foamed mixture and (d) hardening the foam. An Independent claim is also included for polyurethane foam, especially rigid polyurethane foam, obtained by this method.
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公开(公告)号:DE10056251A1
公开(公告)日:2002-05-29
申请号:DE10056251
申请日:2000-11-14
Applicant: BASF AG
Inventor: BIEDERMANN ANJA , KRECH RUEDIGER , ROTERMUND UDO , REICHELT MICHAEL
Abstract: Polyurethane foam is produced by processing the reaction mixture (polyisocyanates and compounds with at least two NCO-reactive hydrogen atoms) in an extruder in which the pressure is higher than atmospheric pressure. A method for the production of polyurethane foam by reacting polyisocyanates with compounds containing at least two hydrogen atoms which react with isocyanate groups involves (a) mixing these reactants, (b) feeding the mixture into an extruder in which the internal pressure is above atmospheric pressure, (c) extruding the foamed mixture and (d) hardening the foam. An Independent claim is also included for polyurethane foam, especially rigid polyurethane foam, obtained by this method.
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公开(公告)号:DE19962273A1
公开(公告)日:2001-06-28
申请号:DE19962273
申请日:1999-12-23
Applicant: BASF AG
Inventor: FALKE PETER , HENDREICH REGINA , THOM ARND , JUNG LUDWIG , REICHELT MICHAEL , BIEDERMANN ANJA
IPC: C08G18/38 , C08G18/48 , C08G18/76 , C08J9/00 , C08L61/28 , C08L75/04 , C08J3/20 , C08J9/22 , C08K7/00 , C08K13/04
Abstract: Comminuted melamine-formaldehyde condensate foam or fiber material (I) is used to produce flame-retardant hard polyurethane foams. Independent claims are also included for the following: (1) a process for producing flame-retardant hard polyurethane foams by reacting polyisocyanates with at least one compound containing at least two reactive hydrogen atoms in the presence of water or other blowing agents and other additives, in which (I) is added to the reaction mixture together with at least one flame retardant; (2) a hard polyurethane foam produced by a process as in (1).
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公开(公告)号:DE59703250D1
公开(公告)日:2001-05-03
申请号:DE59703250
申请日:1997-11-05
Applicant: BASF AG
Inventor: REICHELT MICHAEL , HEINZ MARION , ROTERMUND UDO , HEMPEL RENATE , HENSIEK RAINER , SEIFERT HOLGER
IPC: C07C263/18 , C08G18/24 , C08G18/70
Abstract: The invention relates to polyisocyanates containing tin in the form of compounds of quadrivalent and/or bivalent tin in a quantity ranging from 0.1 to 20 ppm tin with respect to the mass of the polyisocyanate, the polyurethane and/or the polyisocyanurate. The invention further relates to the method for preparing said polyisocyanates and their use.
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公开(公告)号:AT200088T
公开(公告)日:2001-04-15
申请号:AT97950104
申请日:1997-11-05
Applicant: BASF AG
Inventor: REICHELT MICHAEL , HEINZ MARION , ROTERMUND UDO , HEMPEL RENATE , HENSIEK RAINER , SEIFERT HOLGER
IPC: C07C263/18 , C08G18/24 , C08G18/70
Abstract: The invention relates to polyisocyanates containing tin in the form of compounds of quadrivalent and/or bivalent tin in a quantity ranging from 0.1 to 20 ppm tin with respect to the mass of the polyisocyanate, the polyurethane and/or the polyisocyanurate. The invention further relates to the method for preparing said polyisocyanates and their use.
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公开(公告)号:DE19853025A1
公开(公告)日:2000-05-25
申请号:DE19853025
申请日:1998-11-18
Applicant: BASF AG
Inventor: REICHELT MICHAEL , MALOTKI PETER VON , GUETTES BERN
IPC: C08G18/38 , C08G18/40 , C08G18/42 , C08G18/50 , C08J9/00 , C08K5/5333 , C09K21/14 , C08L75/04 , C09K21/00
Abstract: A halogen-free flame-resistant isocyanate-based rigid foam is prepared from an aromatic polyether polyol and a mixture of isocyanate reactive and unreactive phosphonate compounds. A halogen-free, flame-resistant isocyanate-based rigid foam (I) is prepared by reaction of: (A) organic polyisocyanates, optionally modified; (B) a mixture of a polyol and a flame retardant additive; (C) optionally other compounds that are reactive with isocyanates; and (D) optionally other halogen-free flame retardants in the presence of (E) other known processing aids and additives. (B) is a mixture of (B1) an aromatic polyetherpolyol, (B2) a polyester polyol, (B3) a phosphonate that is reactive with isocyanate groups and (B4) a phosphonic acid or ester than is not reactive with isocyanate groups.
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公开(公告)号:AT188227T
公开(公告)日:2000-01-15
申请号:AT96111811
申请日:1996-07-23
Applicant: BASF AG
Inventor: VON MALOTKI PETER DR , HENSIEK RAINER , REICHELT MICHAEL
IPC: C08G18/28
Abstract: A fireproofed isocyanate-based rigid foam (I) is obtd. by reacting (a) polyisocyanates and/or modified polyisocyanates with (b) cpd(s). contg. isocyanate-reactive H atoms and opt. (c) low molecular wt. chain extenders and/or crosslinkers, in presence of (d) blowing agents, (e) catalysts, (f) bromine-contg. fire retardant(s) and opt. (g) other additives, etc.. Fire retardant (f) is tribromo-neopentyl alcohol (TBNPA), and the crosslinking index of all the cpds. with NCO-reactive H atoms (including (f)) is at least 3.0. Also claimed is prodn. of the foam as above.
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公开(公告)号:CA2272812A1
公开(公告)日:1999-11-26
申请号:CA2272812
申请日:1999-05-26
Applicant: BASF AG
Inventor: REICHELT MICHAEL , ROTERMUND UDO , SCHARR VOLKER , GMEREK KARL-HEINZ , FALKE PETER
IPC: C08G18/10 , C08G18/76 , C08G18/80 , C07C271/08 , C07C269/02 , C08G18/72
Abstract: In a process for preparing prepolymers containing isocyanate groups by reacting organic isocyanates (a) with H-acid compounds (b), the reaction to give the prepolymer is carried out directly in the process stream of the isocyanate-producing plant. Also provided are the prepolymers containing isocyanate groups prepared is this way, their use for preparing PUR and also a process for preparing PUR by reacting at least one prepolymer containing isocyanate groups, if desired in admixture with further organic and/or modified organic isocyanates (a), with compounds containing at least two reactive hydrogen atoms (b) in the presence of, if desired, blowing agents (c), catalysts (d) and, if desired, further auxiliaries and/or additives (e).
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公开(公告)号:CA2260343A1
公开(公告)日:1999-08-13
申请号:CA2260343
申请日:1999-02-11
Applicant: BASF AG
Inventor: REICHELT MICHAEL , JUNG LUDWIG , ROTERMUND UDO , BAUM EVA
Abstract: Rigid foams based on isocyanate are produced by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high molecular weight compound containing at least two reactive hydrogen atoms and, if desired, c) low molecular weight chain extenders and/or crosslinkers in the presence of d) carbon dioxide as sole or additional blowing agent, e) foam stabilizers, f) catalysts and, if desired, g) further auxiliaries and/or additives, wherein at least one organosilicon compound having a relative ethylene oxide/propylene oxide weight ratio of over 70/30 is used as foam stabilizer, with the total Si content being greater than or equal to 5% by weight, based on the weight of the foam stabilizer or stabilizers used. The isocyanate-based rigid foams produced in this way can be used as insulation material.
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公开(公告)号:DE19744426A1
公开(公告)日:1999-07-08
申请号:DE19744426
申请日:1997-10-08
Applicant: BASF AG
Inventor: FRITZ RALF DR , PRETZSCH REGINA , GUETTES BERND , REICHELT MICHAEL
IPC: C07F9/40 , C08G18/28 , C08G18/38 , C08G18/66 , C08G18/48 , C09K21/14 , C09K3/10 , C08L75/04 , C08J3/20 , C08J9/34 , C08K5/5333 , C08K5/5337
Abstract: Dialkyl-hydroxyalkane phosphonates are prepared by reacting a phosphonate and an aldehyde in the presence of a basic catalyst. Dialkyl-hydroxyalkyl phosphonates (I) of formula (1) are produced by reaction of: (A) a phosphonate of formula: (R -O)-PO(OR )-H (2), (B) an aldehyde of formula: R -COH (3), and (C) a basic catalyst, involves (1) mixing (A), (B) and (C), or (2) mixing (A) and (B) or (A) and (C) at 20-60 degrees C, and adding the subsequent component when the mixture reaches 20-60 degrees C, then heating at 61-300 degrees C for 1-30 minutes. R ,R = 1-10C alkyl, 6-13C aryl or 7-14C benzyl, optionally substituted with halogen or hydroxy; R = H, 1-10C alkyl, 6-13C aryl, 7-14C benzyl or a furfuryl Independent claims are also included for: (i) a polyurethane (II) containing (I); and (ii) a process for the production of (II) by reaction of: (D) an organic poly isocyanate, (E) a high mol. wt. compound having, at least, groups containing a hydrogen free to react with isocyanate groups, and (F) a dialkyl-hydroxyalkyl phosphonate (I).
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