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公开(公告)号:BRPI0609083A2
公开(公告)日:2010-11-16
申请号:BRPI0609083
申请日:2006-04-07
Applicant: BASF AG
Inventor: MAASE MATTHIAS , STEGMANN VEIT
Abstract: Solution comprises cellulose and an ionic liquid containing anions and cations as solvent, where the cation exhibits at least one atom of nitrogen, oxygen, sulfur and phosphorus, which is present in protonated form. An independent claim is included for the preparation of the solution.
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公开(公告)号:DE102007040919A1
公开(公告)日:2008-03-27
申请号:DE102007040919
申请日:2007-08-30
Applicant: BASF AG
Inventor: WISSEL KATHRIN , HALBRITTER KLAUS , MASSONNE KLEMENS , STEGMANN VEIT
IPC: C07D233/54 , C08F4/00 , C08F10/00 , C08F110/00
Abstract: Producing homo- or copolymers with a weight-average molecular weight of 10000-10000000 by polymerizing olefinic monomers having 3, 4, 6-8 or 10-30 carbon atoms and optionally olefinic comonomers having 3-30 carbon atoms in the liquid phase in the presence of an ionic liquid catalyst comprises using a pyrazolium salt (I) as the catalyst. Producing homo- or copolymers with a weight-average molecular weight of 10000-10000000 by polymerizing olefinic monomers having 3, 4, 6-8 or 10-30 carbon atoms and optionally olefinic comonomers having 3-30 carbon atoms in the liquid phase in the presence of an ionic liquid catalyst comprises using a pyrazolium salt of formula (I) as the catalyst. R1>-R3>optionally substituted 1-200C aliphatic, alicyclic or aromatic (hetero)hydrocarbyl, or R3> can be H; A : n-valent anion; n : 1-4. An independent claim is also included for pyrazolium salts of formula (I) with the following definitions. R1>-R3>1-6C alkyl, or R3> can be H; A : aluminate anion (AlX4.mAlX3)->; X : halo; m : 0-1.5. [Image].
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公开(公告)号:DE102006042891A1
公开(公告)日:2008-03-27
申请号:DE102006042891
申请日:2006-09-09
Applicant: BASF AG , UNIV SIEGEN
Inventor: MASSONNE KLEMENS , D ANDOLA GIOVANNI , STEGMANN VEIT , MORMANN WERNER , WEZSTEIN MARKUS , LENG WEI , FREYER STEPHAN
Abstract: Method for breaking down of poly-, oligo-, disaccharide (I) or its derivative comprises dissolving (I) in an ionic liquid and treating the mixture at an elevated temperature, optionally in the presence of water.
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公开(公告)号:DE102006032569A1
公开(公告)日:2008-01-17
申请号:DE102006032569
申请日:2006-07-12
Applicant: BASF AG , UNIV SIEGEN
Inventor: MASSONNE KLEMENS , STEGMANN VEIT , D ANDOLA GIOVANNI , MORMANN WERNER , WEZSTEIN MARKUS , LENG WEI
Abstract: Silylating poly-, oligo-, disaccharides or their derivatives comprises dissolving the poly-, oligo- disaccharides in an ionic liquid and reacting the obtained mixture with a silylating agent. An independent claim is included for a method for the acylation of silylated poly-, oligo- or disaccharides comprising dissolving the poly-, oligo- disaccharides in an ionic liquid, reacting the obtained mixture with a silylating agent and subsequently acylating the obtained mixture.
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公开(公告)号:DE102006031810A1
公开(公告)日:2008-01-10
申请号:DE102006031810
申请日:2006-07-07
Applicant: BASF AG , UNIV SIEGEN
Inventor: MASSONNE KLEMENS , STEGMANN VEIT , D ANDOLA GIOVANNI , MORMANN WERNER , WEZSTEIN MARKUS , LENG WEI
Abstract: Acetalizing poly-, oligo-, di- saccharide or its derivative comprises dissolving the poly-, oligo or di saccharide in an ionic liquid and reacting the obtained mixture with a vinyl ether. Independent claims are included for: (1) acetylated cellulose obtained by the above method; (2) preparation of cross linked cellulose comprising dissolving the poly- or oligo- saccharide or its derivative, in at least an ionic liquid and reacting the obtained mixture with the vinyl ether and an acid; and (3) the cross linked cellulose obtained by the above method.
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公开(公告)号:DE102006029306A1
公开(公告)日:2007-12-27
申请号:DE102006029306
申请日:2006-06-23
Applicant: BASF AG , UNIV SIEGEN
Inventor: MASSONNE KLEMENS , STEGMANN VEIT , D ANDOLA GIOVANNI , MORMANN WERNER , WEZSTEIN MARKUS , LENG WEI
Abstract: A method for the silylation of poly-, oligo- or di-saccharides or their derivatives involves dissolving these compounds in ionic liquid(s) and reacting them with a silylating agent.
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公开(公告)号:MX2007012500A
公开(公告)日:2007-11-09
申请号:MX2007012500
申请日:2006-04-12
Applicant: BASF AG
Inventor: MAASE MATTHIAS , STEGMANN VEIT
Abstract: La invencion se relaciona con una solucion que comprende celulosa, un liquido ionico que contiene aniones y cationes como solvente y 6 a 30% en peso de una base de nitrogeno, basada en el peso total de la solucion, la produccion de la misma y el uso de la misma para el tratamiento fisico o quimico de celulosa.
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48.
公开(公告)号:CA2633623A1
公开(公告)日:2007-07-12
申请号:CA2633623
申请日:2006-12-22
Applicant: BASF AG
Inventor: MASSONNE KLEMENS , MAASE MATTHIAS , HERMANUTZ FRANK , STEGMANN VEIT , GAEHR FRANK , LUTZ MICHAEL , UERDINGEN ERIC
Abstract: A solution system for biopolymers in the form of carbohydrates based on a molten ionic liquid, additives optionally being contained in the solution system, is described. This solution system contains a protic solvent or a mixture of several protic solvents, and in the case where the protic solvent is solely water, this is present in the solution system in an amount of more than about 5 wt. %. Carbohydrates can be incorporated into the solution system, in particular in the form of starch, cellulose and derivatives thereof, and it can then be used for regeneration of the carbohydrates contained therein. A particularly advantageous process for the preparation of the solution system containing the carbohydrates and for the preparation of regenerated carbohydrates, in particular in the form of regenerated cellulose fibers, is moreover described. The invention accordingly also provides such spun fibers as are distinguished in that they are non-fibrillating. The invention offers in particular economic advantages over the systems of the prior art.
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公开(公告)号:DE102005017733A1
公开(公告)日:2006-10-19
申请号:DE102005017733
申请日:2005-04-15
Applicant: BASF AG
Inventor: MAASE MATTHIAS , STEGMANN VEIT
IPC: C08L1/02
Abstract: The present invention relates to a solution comprising cellulose, an ionic liquid comprising anions and cations as solvent and 6-30% by weight of a nitrogen-comprising base, based on the total weight of the solution, its preparation and also its use for the physical or chemical treatment of cellulose.
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公开(公告)号:DE102005017715A1
公开(公告)日:2006-10-19
申请号:DE102005017715
申请日:2005-04-15
Applicant: BASF AG
Inventor: MAASE MATTHIAS , STEGMANN VEIT
IPC: C08L1/02
Abstract: Solution comprises cellulose and an ionic liquid containing anions and cations as solvent, where the cation exhibits at least one atom of nitrogen, oxygen, sulfur and phosphorus, which is present in protonated form. An independent claim is included for the preparation of the solution.
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