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公开(公告)号:WO2006029807A2
公开(公告)日:2006-03-23
申请号:PCT/EP2005009820
申请日:2005-09-13
Applicant: BASF AG , HUBER GUENTHER , LUTZ MICHAEL , WILLE MICHAEL , FRIEDRICH HOLGER , GUTH JOSEF , BEHLING UWE , FRANKE AXEL , GUNKEL ELISABETH
Inventor: HUBER GUENTHER , LUTZ MICHAEL , WILLE MICHAEL , FRIEDRICH HOLGER , GUTH JOSEF , BEHLING UWE , FRANKE AXEL , GUNKEL ELISABETH
Abstract: The invention relates to an electrolysis device for the production of alkali metals from a liquid alkali metal heavy metal alloy (6), comprising at least two tubes (1) which are arranged in a substantially horizontal manner above each other and which are connected to each other by means of tube couplings (3), forming an electrolysis unit (2); two solid electrolyte tubes (12) which are arranged in each tube (1) and which are closed at one end and which have an opening (11) at the other, conducting the alkali metal ions, wherein the solid electrolyte tubes (12) are arranged concentrically in the tube (1) and are oriented with the opening (11) towards one end of the tube (1) such that a first annular gap for guiding the liquid alkali metal heavy metal alloy (6) forming an anode, is located between the inside of the tube (1) and the outside of the solid electrolyte tubes (12); an alloy inlet (8) and an alloy outlet (9) for the liquid alkali metal heavy metal alloy (6) in each of the tubes (1) which lead into the first annular gap (13) of a tube (1), being horizontally distanced from each other, from the top down; an inner chamber (14) which is sealed off from the alloy inlet (8), first annular gap (13) and alloy outlet (9) in each of the solid electrolyte tubes (12) for receiving liquid alkali metal which can be used as a cathode and which is connected to the alkali metal outlet (15); and two respective closure devices (4) which are arranged at the two ends of each tube (1).
Abstract translation: 本发明涉及的电解装置用于从(6)具有液体碱金属 - 重金属合金制备碱金属 - 至少两个叠置基本水平设置,通过连接件的装置(3)相互连接的管(1)形成一个电解单元(2), 布置的两个在每个管(1)的,在一端封闭,在另一端具有固体电解质管(12),其进行碱金属离子,固体电解质管(12)在所述管(1)同心布置,并具有开口(11) - 与(1)的面向所述管的开口(11)一个端部,使得第一环形间隙(13),用于引导阳极形成液态碱金属 - 重金属的管的内部之间的合金(6)(1)和外侧 固体电解质管(12), - 一入口合金(8)和一个出口合金(9),用于将液体碱金属Schwermetalllegier UNG(6)在各管(1)的情况下,互相水平地从上方或从下方到管(1)开放的第一环形间隙(13)隔开, - 一个相对于该合金的入口(8),所述第一环形间隙(13) 并在每一个固体电解质管(12)的合金流动密封(9)的内部(14),用于接收所述可用作为与碱金属出口(15)连接的阴极液体碱金属,以及 - 两个封闭装置(4),这两个在 各管(1)被布置的结束。
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公开(公告)号:WO2007113209A8
公开(公告)日:2008-03-20
申请号:PCT/EP2007053033
申请日:2007-03-29
Applicant: BASF AG , MARTIN MARC , HUBER GUENTHER , LUTZ MICHAEL , KANTHER WOLFGANG , GUTH JOSEF , FRIEDRICH HOLGER
Inventor: MARTIN MARC , HUBER GUENTHER , LUTZ MICHAEL , KANTHER WOLFGANG , GUTH JOSEF , FRIEDRICH HOLGER
CPC classification number: C22B26/10 , C22B3/20 , C22B43/00 , C25B1/36 , Y02P10/234
Abstract: The invention relates to a method for removing small quantities of water and other possible components from alkali metal amalgam. Said alkali metal amalgam is brought into contact with an element which is not soluble in mercury and the reaction of the water with the alkali metal amalgam and the other possible components is catalysed to form hydroxides and hydrogen. The catalytically active element is selected from, for example, iron, nickel, cobalt, titanium, chrome, molybdenum, stainless steel, tungsten carbide and graphite.
Abstract translation: 本发明涉及一种用于除去少量的水和选自碱金属汞齐,其特征在于,所述碱金属汞齐被带入与一个元件接触可能的进一步的组分的方法,该是在汞不溶性和水与碱金属汞齐和可能的其它组分,以形成氢氧化物的反应 和氢催化。 催化元素选自例如 铁,镍,钴,钛,铬,钼,不锈钢,碳化钨,石墨。
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公开(公告)号:WO2007113209A2
公开(公告)日:2007-10-11
申请号:PCT/EP2007053033
申请日:2007-03-29
Applicant: BASF AG , MARTIN MARC , HUBER GUENTHER , LUTZ MICHAEL , KANTHER WOLFGANG , GUTH JOSEF , FRIEDRICH HOLGER
Inventor: MARTIN MARC , HUBER GUENTHER , LUTZ MICHAEL , KANTHER WOLFGANG , GUTH JOSEF , FRIEDRICH HOLGER
CPC classification number: C22B26/10 , C22B3/20 , C22B43/00 , C25B1/36 , Y02P10/234
Abstract: The invention relates to a method for removing small quantities of water and other potential components from alkali metal amalgam. Said alkali metal amalgam is brought into contact with an element which is not soluble in mercury and the reaction of the water with the alkali metal amalgam and the other potential components is catalysed to form hydroxides and hydrogen.
Abstract translation: 本发明涉及一种用于除去少量的水和选自碱金属汞齐,其特征在于,所述碱金属汞齐被带入与一个元件接触可能的进一步的组分的方法,该是在汞不溶性和水与碱金属汞齐和可能的其它组分,以形成氢氧化物的反应 和氢催化。
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公开(公告)号:DE502005002528D1
公开(公告)日:2008-02-21
申请号:DE502005002528
申请日:2005-09-13
Applicant: BASF AG
Inventor: HUBER GUENTHER , LUTZ MICHAEL , WILLE MICHAEL , FRIEDRICH HOLGER , GUTH JOSEF , BEHLING UWE , FRANKE AXEL , GUNKEL ELISABETH
Abstract: An electrolysis device producing alkali metals from a liquid alkali metal heavy metal alloy, including at least two connected tubes forming an electrolysis unit. Two solid electrolyte tubes are arranged concentrically in each tube and oriented with openings towards one end of each tube such that a first annular gap for guiding a liquid alkali metal forming an anode is located between the inside of the tube and the outside of the solid electrolyte tubes. An alloy inlet and outlet for the liquid alkali metal in each of the tubes leads into the first annular gap of a tube. An inner chamber sealed off from the alloy inlet, first annular gap, and alloy outlet in each solid electrolyte tube receives liquid alkali metal that can be used as a cathode connected to the alkali metal outlet. Two respective closure devices are arranged at the two ends of each tube.
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公开(公告)号:AT383458T
公开(公告)日:2008-01-15
申请号:AT05784834
申请日:2005-09-13
Applicant: BASF AG
Inventor: HUBER GUENTHER , LUTZ MICHAEL , WILLE MICHAEL , FRIEDRICH HOLGER , GUTH JOSEF , BEHLING UWE , FRANKE AXEL , GUNKEL ELISABETH
Abstract: An electrolysis device producing alkali metals from a liquid alkali metal heavy metal alloy, including at least two connected tubes forming an electrolysis unit. Two solid electrolyte tubes are arranged concentrically in each tube and oriented with openings towards one end of each tube such that a first annular gap for guiding a liquid alkali metal forming an anode is located between the inside of the tube and the outside of the solid electrolyte tubes. An alloy inlet and outlet for the liquid alkali metal in each of the tubes leads into the first annular gap of a tube. An inner chamber sealed off from the alloy inlet, first annular gap, and alloy outlet in each solid electrolyte tube receives liquid alkali metal that can be used as a cathode connected to the alkali metal outlet. Two respective closure devices are arranged at the two ends of each tube.
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公开(公告)号:CA2633623A1
公开(公告)日:2007-07-12
申请号:CA2633623
申请日:2006-12-22
Applicant: BASF AG
Inventor: MASSONNE KLEMENS , MAASE MATTHIAS , HERMANUTZ FRANK , STEGMANN VEIT , GAEHR FRANK , LUTZ MICHAEL , UERDINGEN ERIC
Abstract: A solution system for biopolymers in the form of carbohydrates based on a molten ionic liquid, additives optionally being contained in the solution system, is described. This solution system contains a protic solvent or a mixture of several protic solvents, and in the case where the protic solvent is solely water, this is present in the solution system in an amount of more than about 5 wt. %. Carbohydrates can be incorporated into the solution system, in particular in the form of starch, cellulose and derivatives thereof, and it can then be used for regeneration of the carbohydrates contained therein. A particularly advantageous process for the preparation of the solution system containing the carbohydrates and for the preparation of regenerated carbohydrates, in particular in the form of regenerated cellulose fibers, is moreover described. The invention accordingly also provides such spun fibers as are distinguished in that they are non-fibrillating. The invention offers in particular economic advantages over the systems of the prior art.
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公开(公告)号:DE102005062608A1
公开(公告)日:2007-07-05
申请号:DE102005062608
申请日:2005-12-23
Applicant: BASF AG
Inventor: STEGMANN VEIT , MASSONNE KLEMENS , MAASE MATTHIAS , UERDINGEN ERIC , LUTZ MICHAEL , HERMANUTZ FRANK , GAEHR FRANK
Abstract: Solution system (I) for biopolymers in the form of carbohydrates, based on molten ionic liquid, optionally containing additives, contains protic solvent(s) and, if the only protic solvent is water, in an amount more than about 5 wt.%. Independent claims are included for (1) process for producing (I); (2) process for producing regenerated carbohydrates using (I); (3) regenerated carbohydrate produced by this process, especially in the form of regenerated cellulose fibers.
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公开(公告)号:DE102006035830A1
公开(公告)日:2008-02-07
申请号:DE102006035830
申请日:2006-08-01
Applicant: BASF AG
Inventor: STEGMANN VEIT , MASSONNE KLEMENS , MAASE MATTHIAS , UERDINGEN ERIC , LUTZ MICHAEL , HERMANUTZ FRANK , GAEHR FRANK
IPC: C07D233/58 , C08B1/00 , D01D5/00 , D01F2/08
Abstract: Solvent system based on molten ionic liquid for biopolymers in the form of carbohydrates, comprises optionally additives and a protic solvent or its mixture, and if the protic solvent is water alone, then this is present in the solvent system in an amount of more than about 5 wt.%. Independent claims are included for: (1) a method for the production of a solvent system comprising mixing the carbohydrates with the molten ionic liquid and the protic solvent and/or its mixture, until the carbohydrates are dissolved; (2) a method for the production of regenerated carbohydrates, preferably starch, cellulose and their derivatives using the solvent system, where the solvent system is precipitated, preferably wet spun in a coagulation medium, and contains a solvent, which does not dissolve the carbohydrates and is mixable with the molten ionic liquid; (3) a regenerated carbohydrates, preferably in the form of regenerated cellulose fibers obtained by the above method; and (4) spinnable fibers based on regenerated cellulose with a wet fibrillation grade of /~2.
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