公开(公告)号：ID18456A

公开(公告)日：1998-04-09

申请号：ID973147

申请日：1997-09-10

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FLICK KLEMENS ,  LUYKEN HERMANN ,  REHFINGER ALWIN ,  BASSLER PETER

IPC: C07B61/00 ,  B01J23/78 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07

Abstract: PCT No. PCT/EP97/04542 Sec. 371 Date Mar. 10, 1999 Sec. 102(e) Date Mar. 10, 1999 PCT Filed Aug. 21, 1997 PCT Pub. No. WO98/11051 PCT Pub. Date Mar. 19, 1998A process for coproduction of 6-aminocapronitrile and hexamethylenediamine starting from a mixture comprising a phosphorus-containing compound and essentially adiponitrile and obtained by reaction of butadiene with hydrocyanic acid in the presence of a catalyst comprising a phosphorus-containing compound comprises (1) reducing the weight proportion of phosphorus-containing compound, calculated as phosphorus, in the mixture, (2) partially hydrogenating the resulting mixture in the presence of a catalyst to form an alpha , omega -aminonitrile, and (3) removing 6-aminocapronitrile and hexamethylenediamine from the mixture.

公开(公告)号：CA2265513A1

公开(公告)日：1998-03-19

申请号：CA2265513

申请日：1997-09-01

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  EBEL KLAUS ,  FISCHER ROLF ,  VOIT GUIDO ,  MERGER MARTIN

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: Process for the manufacture of aliphatic alpha, omega amino nitriles by partial hydrogenation of aliphatic alpha, omega dinitriles in the presence of a catalyst, characterized by the fact that a catalyst is used for partial hydrogenation containing (a) iron or a compound based on iron or its mixtures and (b) 0.01 - 5 wt % related to (a) of a promotor on the basis of 2,3,4 or 5 elements selected from aluminium, silicon, zirconium, titanium and vanadium and (c) 0 - 5 wt % related to (a) of a compound based on an alkali metal or alkaline earth metal.

公开(公告)号：CA2265472A1

公开(公告)日：1998-03-19

申请号：CA2265472

申请日：1997-08-21

Applicant: BASF AG

Inventor： FISCHER ROLF ,  LUYKEN HERMANN ,  VOIT GUIDO ,  BASSLER PETER ,  REHFINGER ALWIN

IPC: B01J27/187 ,  C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C211/12 ,  C07C253/30 ,  C07C253/34 ,  C07C255/24

Abstract: The invention concerns a process for simultaneously preparing 6aminocapronitrile and hexamethylene diamine proceeding from adipodinitrile. The process is characterized in that: (1) adipodinitrile is partially hydrogenated in the presence of a catalyst in order to obtain a mixture containing 6-aminocapronitrile, hexamethylene diamine and adipodinitrile; (2) 6-aminocapronitrile and hexamethylene diamine are separated from the mixture; (3) between 0.01 and 10 wt %, relative to adipodinitrile, of an acid or an acidic ion exchanger is added to the part substantially containing adipodinitrile, and the adipodinitrile is separated from the mixture; and (4) the adipodinitrile is returned to step (1).

公开(公告)号：CA2263111A1

公开(公告)日：1998-03-19

申请号：CA2263111

申请日：1997-08-21

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  FISCHER ROLF ,  VOIT GUIDO ,  SCHNURR WERNER ,  EBEL KLAUS

IPC: B01J23/75 ,  B01J23/74 ,  B01J23/76 ,  B01J25/00 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24 ,  C07C255/25

Abstract: The invention concerns catalysts suitable for preparing aliphatic alpha-, omega-aminonitriles by partial hydrogenation of aliphatic dinitriles, containing: (a) metallic cobalt, a cobalt compound or their mixtures, the metallic cobalt portion being between 20 and 100 wt % relative to (a); (b) between 10 and 70 wt %, relative to (a), of metallic iron, iron oxide, a further iron compound or their mixtures, the iron oxide portion being between 20 and 100 wt % relative to (b); and (c) between 0 and 1 wt %, relative to (a), of a compound based on an alkali metal, alkaline earth metal or zinc.

公开(公告)号：CA2261614A1

公开(公告)日：1998-02-05

申请号：CA2261614

申请日：1997-07-29

Applicant: BASF AG

Inventor： FISCHER ROLF ,  FLICK KLEMENS ,  VOIT GUIDO ,  SCHNURR WERNER

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B43/04 ,  C07B61/00 ,  C07C20060101 ,  C07C209/48 ,  C07C209/52 ,  C07C211/12 ,  C07C211/35 ,  C07C253/30 ,  C07C255/24

Abstract: The invention concerns the production of compounds containing NH2-groups by hydrogenating compounds containing at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures not below room temperature and under increased hydrogen partial-pressure, preferably in the presence of a solvent, in which one (a) uses a cobalt and/or ironcontaining catalyst, and (b), after conversion of the compound to be hydrogenated and/or the selectivity of the product desired drops below a defined value, or after an increase in the quantity of an undesired by-product beyond a defined value, one breaks off the hydrogenation by stopping the supply of the compounds to be hydrogenated and, if desired, of any solvents present, (c) one treats the catalyst with hydrogen at a temperature between 150 to 400 ~C and a hydrogen pressure between 0.1 to 30 MPa and selects a treatment time of 2 to 48 hours, and (d) one subsequently continues the hydrogenation of a least one compound containing an unsaturated carbonnitrogen bond as well as the regeneration of cobalt and/or iron-containing catalysts.

公开(公告)号：NO975499D0

公开(公告)日：1997-11-28

申请号：NO975499

申请日：1997-11-28

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  BECK KARL ,  AUMUELLER ALEXANDER ,  WITZEL TOM ,  VOIT GUIDO

IPC: C07C253/30 ,  C07C255/41 ,  C07C

Abstract: PCT No. PCT/EP96/02238 Sec. 371 Date Dec. 1, 1997 Sec. 102(e) Date Dec. 1, 1997 PCT Filed May 24, 1996 PCT Pub. No. WO96/38409 PCT Pub. Date Dec. 5, 1996A process for preparing 2-cyano-3,3-diarylacrylic esters of the general formula I where R1 and R2 are hydrogen, C1-C12-alkyl groups, C-C12-alkoxy groups or di(C1-C4-alkyl)amino groups and R3 is a C4-C18-alkyl group which can be interrupted by ether-functional oxygen atoms, by reacting a benzophenone imine of the general formula II with a cyanoacetic ester of the general formula III wherein the reaction is carried out at from 20 to 60 DEG C. and, during this, the liberated ammonia is continuously removed from the reaction mixture with the aid of a stream of gas or by reducing the pressure to from 900 to 100 mbar.

公开(公告)号：NO975499A

公开(公告)日：1997-11-28

申请号：NO975499

申请日：1997-11-28

Applicant: BASF AG

Inventor： HOLDERBAUM MARTIN ,  BECK KARL ,  AUMUELLER ALEXANDER ,  WITZEL TOM ,  VOIT GUIDO

IPC: C07C253/30 ,  C07C255/41

CPC classification number: C07C253/30

公开(公告)号：AU2636297A

公开(公告)日：1997-10-29

申请号：AU2636297

申请日：1997-04-04

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  MELDER JOHANN-PETER ,  FISCHER ROLF ,  HARDER WOLFGANG

IPC: B01J25/02 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A process for the coproduction of 6-aminocapronitrile (ACN) and hexamethylenediamine (HMD) by treatment of adiponitrile (ADN) with hydrogen in the presence of a nickel-containing catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent comprises, after the conversion based on ADN and/or the selectivity based on ACN has or have dropped below a defined value (a) interrupting the treatment of ADN with hydrogen by stopping the feed of ADN and of the solvent, if used, (b) treating the catalyst at from 150 DEG to 400 DEG C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and (c) then continuing the hydrogenation of ADN with the treated catalyst of stage (b).

公开(公告)号：AU2636097A

公开(公告)日：1997-10-29

申请号：AU2636097

申请日：1997-04-03

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF-HARTMUTH

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A process for the coproduction of 6-aminocapronitrile (ACN) and hexamethylenediamine (HMD) by treatment of adiponitrile (ADN) with hydrogen in the presence of a nickel-containing catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent comprises, after the conversion based on ADN and/or the selectivity based on ACN has or have dropped below a defined value (a) interrupting the treatment of ADN with hydrogen by stopping the feed of ADN and of the solvent, if used, (b) treating the catalyst at from 150 DEG to 400 DEG C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and (c) then continuing the hydrogenation of ADN with the treated catalyst of stage (b).

公开(公告)号：ID16587A

公开(公告)日：1997-10-16

申请号：ID971147

申请日：1997-04-04

Applicant: BASF AG

Inventor： SCHURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  MELDER JOHANN-PETER ,  FISCHER ROLF ,  HARDER WOLFGANG

IPC: C07B61/00 ,  B01J25/02 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A process for the coproduction of 6-aminocapronitrile (ACN) and hexamethylenediamine (HMD) by treatment of adiponitrile (ADN) with hydrogen in the presence of a nickel-containing catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent comprises, after the conversion based on ADN and/or the selectivity based on ACN has or have dropped below a defined value (a) interrupting the treatment of ADN with hydrogen by stopping the feed of ADN and of the solvent, if used, (b) treating the catalyst at from 150 DEG to 400 DEG C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and (c) then continuing the hydrogenation of ADN with the treated catalyst of stage (b).