VERWENDUNG VON THIURONIUMSALZEN ALS GLANZMITTEL FÜR WÄSSRIG-SAURE GALVANISCHE NICKELBÄDER
    45.
    发明公开
    VERWENDUNG VON THIURONIUMSALZEN ALS GLANZMITTEL FÜR WÄSSRIG-SAURE GALVANISCHE NICKELBÄDER 失效
    USE硫脲盐ALS增白剂用于水性-ACID电偶镍浴。

    公开(公告)号:EP0675975A1

    公开(公告)日:1995-10-11

    申请号:EP94901946.0

    申请日:1993-12-02

    CPC classification number: C07C335/32 C25D3/12

    Abstract: Nickel-plated shaped parts are produced by galvanic precipitation of nickel from aqueous-acid baths which contain as essential constituents one or several nickel salts, one or several inorganic acids and one or several brighteners. As brighteners are used thiourea salts having general formula (I), in which R to R stand for hydrogen, C1 to C18-alkyl, which may be substituted by carboxyl groups, C1 to C4-alkoxycarbonyl groups or cyano groups, C2 to C12-alkenyl, C2 to C12-alkinyl, C5 to C8-cycloalkyl, C7 to C12-phenylalkyl or phenyl, which may be substituted by one or two C1 to C4-alkyl residues, C1 to C4-alkoxy residues, halogen atoms, hydroxyl groups, phenyl groups, phenyl residues or C1 to C4 alkoxycarbonyl groups; Y stands for a chemical bond or for linear or branched alkylene, alkenylene or alkinylene having each up to 20 C atoms; A stands for hydrogen or a group having the formulae: -CO-H, -CO-R , -CO-OH, -CO-OR , -CO-NR R , -CO-CH2-CO-OR , -O-CO-H, -O-CO-R , -NR -CO-R , -NR -CO-R , -OR , -SO2-R , -SO2-OH, -SO2-OR , -PO(PH)2, -PO(OH)(OR ), -PO(OR )2, OPO(OH)2, -OPO(PH)(PR ) or -OPO(OR )2 in which R stands for C1 to C12-alkyl, C2 to C12-alkenyl, C2 to C12-alkinyl, C5 to C8-cycloalkyl, C7 to C12-phenylalkyl or phenyl, which may be substituted by one or two C1 to C4-alkyl residues, halogen atoms, hydroxyl groups, phenyl residues or C1 to C4-alkoxycarbonyl groups; and R and R stand for hydrogen or C1 to C4-alkyl; n is a number from 1 to 4 and X stands for a water solubility-promoting, n-valent inorganic or organic anion.

Patent Agency Ranking