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    METHOD FOR PRODUCING FORMIC ACID
    41.
    发明专利
    METHOD FOR PRODUCING FORMIC ACID 未知

    公开(公告)号：CA2765430A1

    公开(公告)日：2010-12-29

    申请号：CA2765430

    申请日：2010-06-11

    Applicant: BASF SE

    Inventor： SCHAUB THOMAS ,  PACIELLO ROCCO ,  MOHL KLAUS-DIETER ,  SCHNEIDER DANIEL ,  SCHAFER MARTIN ,  RITTINGER STEFAN

    IPC: C07C51/00 ,  C07C51/44 ,  C07C53/02

    Abstract: The invention relates to a method for producing formic acid by hydrogenation of carbon dioxide in the presence of a catalyst which contains an element of the 8th, 9th or 10th group of the periodic system, a tertiary amine and a polar solvent, at a pressure of 0.2 to 30 MPa abs and a temperature of 20 to 200°C, thereby producing two liquid phases, and separation of the two liquid phases. The liquid phase (B) enriched by the tertiary amine is returned to the hydrogenation reactor and the formic acid/amine addition product from the liquid phase (A) enriched by the formic acid/amine addition product and the polar solvent is thermally separated into free formic acid and free tertiary amine in a distillation unit and the tertiary amine released during separation and the polar solvent are returned to the hydrogenation reactor.

    PROCESS FOR PREPARING FORMIC ACID
    46.
    发明专利
    PROCESS FOR PREPARING FORMIC ACID 未知

    公开(公告)号：MY159513A

    公开(公告)日：2017-01-13

    申请号：MYPI2011006186

    申请日：2010-06-11

    Applicant: BASF SE

    Inventor： SCHAUB THOMAS ,  PACIELLLO ROCCO ,  MOHL KLAUS-DIETER ,  SCHNEIDER DANIEL ,  SCHÄFER MARTIN ,  RITTINGER STEFAN

    IPC: C07C51/42 ,  C07C53/00

    Abstract: PROCESS FOR PREPARING FORMIC ACID BY HYDROGENATION OF CARBON DIOXIDE IN THE PRESENCE OF A CATALYST COMPRISING AN ELEMENT OF GROUP 8, 9 OR 10 OF THE PERIODIC TABLE, A TERTIARY AMINE AND A POLAR SOLVENT AT A PRESSURE OF FROM 0.2 TO 30 MPA ABS AND A TEMPERATURE OF FROM 20 TO 200° C. TO FORM TWO LIQUID PHASES, SEPARATION OF THE TWO LIQUID PHASES, WHEREIN THE LIQUID PHASE (B) ENRICHED WITH THE TERTIARY AMINE IS RECIRCULATED TO THE HYDROGENATION REACTOR (A) AND THE FORMIC ACID/AMINE ADDUCT FROM THE LIQUID PHASE (A) ENRICHED WITH THE FORMIC ACID/AMINE ADDUCT AND THE POLAR SOLVENT IS THERMALLY DISSOCIATED INTO FREE FORMIC ACID AND FREE TERTIARY AMINE IN A DISTILLATION UNIT (C) AND THE TERTIARY AMINE LIBERATED IN THE DISSOCIATION AND THE POLAR SOLVENT ARE RECIRCULATED TO THE HYDROGENATION REACTOR (A). (FIG. 3)

    processo para preparar ácido fórmico
    49.
    发明专利
    processo para preparar ácido fórmico 未知

    公开(公告)号：BR112012012033A2

    公开(公告)日：2016-05-17

    申请号：BR112012012033

    申请日：2011-06-16

    Applicant: BASF SE

    Inventor： SCHNEIDER DANIEL ,  FRIES DONATA MARIA ,  MOHL KLAUS-DIETER ,  SCHÄFER MARTIN ,  PACIELLO ROCCO ,  RITTINGER STEFAN ,  SCHAUB THOMAS

    IPC: C07C51/00 ,  C07C53/02

    Abstract: "processo para preparar ácido fórmico". é proposto um processo para´preparar ácido fórmico através da reação de dióxido de carbono (1) com hidrogênio (2) em um reator de hidrogenação (i) na presença de um catalisador que compreende um elemento dos grupos 8,9 ou 10 da tabela periódica, de uma amina terciária contendo pelo menos 12 átomos de carbono por molécula e um solvente polar que compreende um ou mais monoaçlcoóis selecionados de metanol, etanol, propanóis e butanóis, e água, para formar adutos de ácido fórmico/amina como intermediários, que são subsequentemente clivados de maneira térmica, com processamento das saídas (3) do reator de hidrogenação (i) em várias etapas de processo, uma corrente (13) compreendendo amina terciária do processamento sendo usada como solvente seletivo para o catalisador.

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