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公开(公告)号：JP2013209432A
公开(公告)日：2013-10-10
申请号：JP2013140738
申请日：2013-07-04
Applicant: Basf Se , ビーエーエスエフ ソシエタス・ヨーロピアBasf Se
Inventor： HEYDRICH GUNNAR , GRALLA GABRIELE , RAULS MATTHIAS DR , SCHMIDT-LEITHOFF JOACHIM , EBEL KLAUS DR , KRAUSE WOLFGANG DR , OEHLENSCHLAEGER STEFFEN , JAEKEL CHRISTOPH , FRIEDRICH MARKO , BERGNER EIKE JOHANNES , KASHANI-SHIRAZI NAWID , PACIELLO ROCCO
IPC: C07C29/156 , B01J31/28 , C07B53/00 , C07B61/00 , C07C35/12
CPC classification number: C07C29/56 , C07B2200/07 , C07C29/172 , C07C29/78 , C07C45/62 , C07C45/82 , C07C2601/14 , C07C2601/16 , C07C47/21 , C07C35/12 , C07C35/17
Abstract: PROBLEM TO BE SOLVED: To provide a method enabling to manufacture optically active menthol, desirably L-menthol and racemic menthol in a variety of quantity according to the demand without changing an enantioselective catalyst system and/or without excessively obtaining one of products for need of changing a reaction condition.SOLUTION: A method for producing menthol includes a process (a. 1) of obtaining a citronellal by catalyst-hydrogenation of a neral and/or a geranial, a process (b. 1) of obtaining an isopulegol by cyclizing citronellal in the presence of an acid catalyst, a process (c. 1) of purifying the isopulegol by crystallization, and a process (d. 1) of producing menthol by catalyst-hydrogenation of the isopulegol.
Abstract translation: 要解决的问题：提供一种能够根据需要以不需要改变对映体选择性催化剂体系，和/或不过度地获得需要的物质的产品之一来制备光学活性薄荷醇，理想的L-薄荷醇和外消旋薄荷醇， 改变反应条件。解决方案：制备薄荷醇的方法包括通过催化剂氢化和/或香草醛获得香茅醛的方法（a.1），通过环化获得异焦耳的方法（b.1） 在酸催化剂存在下的香茅醛，通过结晶纯化异焦耳的方法（c.1），以及通过异双胍的催化氢化制备薄荷醇的方法（d.1）。
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公开(公告)号：KR20180008621A
公开(公告)日：2018-01-24
申请号：KR20177035937
申请日：2016-05-09
Applicant: BASF SE
Inventor： SCHAUB THOMAS , HUGUET SUBIELA NURIA , PACIELLO ROCCO , FRIES DONATA MARIA , MANZINI SIMONE
Abstract: 알켄, 이산화탄소, 및 [O] 기에직접결합된 2급또는 3급탄소원자를갖는알콕사이드로부터α,β-에틸렌계불포화카복실산염을제조하는촉매적방법이기재된다. 중간상 분리후 알코올부산물이증류제거된다. 상기방법은최소한의노력으로순수한α,β-에틸렌계불포화카복실산염을제공한다.
Abstract translation: 描述了由链烯烃，二氧化碳和具有与[O]基团直接键合的仲或叔碳原子的醇盐制备α，β-烯键式不饱和羧酸盐的催化方法。 分离中间相后，馏出醇副产物。 该方法以最小的努力提供纯的α，β-烯键式不饱和羧酸盐。
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公开(公告)号：KR20180066076A
公开(公告)日：2018-06-18
申请号：KR20187009785
申请日：2016-10-11
Applicant: BASF SE
Inventor： SCHAUB THOMAS , PACIELLO ROCCO , ERNST MARTIN , MORMUL JAROSLAW , HOFMANN PETER , BREITENFELD JAN , TRAPP OLIVER
IPC: C07C29/16 , B01J31/22 , C07C29/74 , C07C31/20 , C07C51/305 , C07C55/14 , C07C209/26 , C07C211/12
CPC classification number: C07C209/26 , B01J31/00 , C07C29/132 , C07C51/305 , C07D317/12 , C07D319/06 , C07C211/12 , C07C55/14 , C07C31/20
Abstract: 본발명은 1,3-이중불포화탄화수소, 바람직하게는부타디엔으로부터의 1,6-이관능화된헥산유도체의제조방법이며, 여기서일산화탄소및 수소와의히드로포르밀화는적어도 2가알칸올의존재하에수행되고, 히드로포르밀화동안에온도는증가된다. 반응은 1,6-헥산디알유도체의아세탈을생성하며, 이를단리하고추가반응시켜원하는 1,6-이관능화된헥산유도체, 특히 1,6-헥산디아민, 1,6-헥산디올및 아디프산을수득하는것인방법에관한것이다.
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公开(公告)号：WO2009068444A3
公开(公告)日：2010-05-27
申请号：PCT/EP2008065503
申请日：2008-11-13
Applicant: BASF SE , HEYDRICH GUNNAR , GRALLA GABRIELE , RAULS MATTHIAS , SCHMIDT-LEITHOFF JOACHIM , EBEL KLAUS , KRAUSE WOLFGANG , OEHLENSCHLAEGER STEFFEN , JAEKEL CHRISTOPH , FRIEDRICH MARKO , BERGNER EIKE JOHANNES , KASHANI-SHIRAZI NAWID , PACIELLO ROCCO
Inventor： HEYDRICH GUNNAR , GRALLA GABRIELE , RAULS MATTHIAS , SCHMIDT-LEITHOFF JOACHIM , EBEL KLAUS , KRAUSE WOLFGANG , OEHLENSCHLAEGER STEFFEN , JAEKEL CHRISTOPH , FRIEDRICH MARKO , BERGNER EIKE JOHANNES , KASHANI-SHIRAZI NAWID , PACIELLO ROCCO
IPC: C07C29/17
CPC classification number: C07C29/56 , C07B2200/07 , C07C29/172 , C07C29/78 , C07C45/62 , C07C45/82 , C07C2601/14 , C07C2601/16 , C07C47/21 , C07C35/12 , C07C35/17
Abstract: The invention relates to a particularly economic, complete method for producing menthol, especially for the production of optically active, essentially enantiomerically and diastereomerically pure L-menthol and of racemic menthol starting from the commercially accessible, inexpensive parent material citral. The method comprises the following steps: a.1 ) catalytic hydrogenation of neral and/or geranial to form citronellal, b.1 ) cyclisation of citronellal to form isopulegol in the presence of an acidic catalyst, c.1 ) purification of isopulegol by crystallisation and d.1 ) catalytic hydrogenation of isopulegol to form menthol.
Abstract translation: 本发明涉及一种用于制备薄荷醇高度经济整个过程，特别地用于制备光学活性的，基本上对映体和非对映异构纯的L-薄荷醇和外消旋薄荷醇从在工业规模的起始材料的柠檬醛可用廉价的速率开始。 该方法包括以下步骤A.1）橙花醛的催化氢化和/或香叶到香茅醛，B.1）香茅醛在酸催化剂的存在下异胡薄荷醇，C.1）通过结晶和D.1异胡薄荷醇的纯化的环化） 胡薄荷醇的催化加氢：薄荷。
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5.发明申请
公开(公告)号：WO2008046918A3
公开(公告)日：2008-07-31
申请号：PCT/EP2007061229
申请日：2007-10-19
Applicant: BASF SE , RUDOLPH JENS , PACIELLO ROCCO , JAEKEL CHRISTOPH , HETTCHE FRANK , BOERNER ARMIN , DUBROVINA NATALIA , BIRKHOLZ MANDY-NICOLE , BREIT BERNHARD
Inventor： RUDOLPH JENS , PACIELLO ROCCO , JAEKEL CHRISTOPH , HETTCHE FRANK , BOERNER ARMIN , DUBROVINA NATALIA , BIRKHOLZ MANDY-NICOLE , BREIT BERNHARD
IPC: C07B37/02 , B01J31/18 , C07C29/16 , C07C45/50 , C07D211/76
CPC classification number: C07C45/50 , B01J31/1845 , B01J31/2409 , B01J31/2438 , B01J31/2452 , B01J31/2466 , B01J31/2471 , B01J2231/32 , B01J2231/321 , B01J2231/323 , B01J2231/325 , B01J2231/326 , B01J2231/342 , B01J2231/44 , B01J2231/52 , B01J2231/543 , B01J2231/645 , B01J2531/0266 , B01J2531/0291 , B01J2531/821 , B01J2531/822 , B01J2531/842 , B01J2531/847 , B01J2531/94 , C07B53/00 , C07B2200/07 , C07C45/505 , C07C45/72 , C07C67/303 , C07C231/12 , C07F9/65683 , C07F15/0073 , C07C69/34 , C07C233/47
Abstract: The present invention relates to a method for reacting compounds, comprising at least one carbon-carbon or carbon-heteroatom double bond, by 1,2-addition in the presence of a catalyst, comprising at least one transition metal complex having at least two ligands, which each have a pnicogen atom-containing group and at least one functional group enable to form intermolecular, non-covalent bonds, in the presence of a halogenated solvent, which has at least one heteroatom different from halogen. The present invention further relates to a method for producing chiral compounds in the presence of the above-described catalysts and solvents, and to the use of these catalysts in the presence of such solvents.
Abstract translation: 本发明涉及一种用于反应包含至少一个碳 - 碳或碳 - 杂原子双键，由1,2-加成在催化剂的存在下的化合物包含至少一种过渡金属配合物具有至少两个配位体各自具有pnicogenatomhaltige的处理 基团和至少一个能够形成分子间非共价键官能团的基团，并且在具有至少一个除卤素以外的杂原子的卤化溶剂存在下进行。 本发明进一步涉及在上述催化剂和溶剂存在下制备手性化合物的方法以及这些催化剂在这些溶剂存在下的用途。
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Patent Agency Ranking
公开(公告)号：WO2008031889A3
公开(公告)日：2009-04-16
申请号：PCT/EP2007059722
申请日：2007-09-14
Applicant: BASF SE , RUDOLPH JENS , PACIELLO ROCCO , GULYAS HENRIK , FREIXA ZORAIDA , VAN LEEUWEN PETRUS WILHELMUS NICOLAAS MARIA
Inventor： RUDOLPH JENS , PACIELLO ROCCO , GULYAS HENRIK , FREIXA ZORAIDA , VAN LEEUWEN PETRUS WILHELMUS NICOLAAS MARIA
IPC: B01J31/24 , B01J31/18 , C07B53/00 , C07C2/52 , C07C5/03 , C07C5/25 , C07C6/02 , C07C13/04 , C07C29/136 , C07C41/06 , C07C45/50 , C07C45/72 , C07C67/38 , C07C209/60 , C07C231/10 , C07C253/10 , C07F15/00 , C07F15/04
CPC classification number: B01J31/24 , B01J31/18 , B01J31/1845 , B01J31/2409 , B01J2231/32 , B01J2231/321 , B01J2231/323 , B01J2231/325 , B01J2231/326 , B01J2231/341 , B01J2231/342 , B01J2231/44 , B01J2231/52 , B01J2231/543 , B01J2231/643 , B01J2231/645 , B01J2531/0291 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07B53/00 , C07B2200/07 , C07C5/03 , C07C45/505 , C07C2531/22 , C07F9/5022 , C07F9/587 , C07F15/006 , C07F15/0073 , C07F15/0093
Abstract: The present invention relates to catalysts comprising at least one metal complex with at least two ligands which each have at least one pnicogen atom and at least one functional group capable of forming intermolecular, ionic interactions, wherein the complex has ligands which are dimerized via intermolecular ionic interactions, and also processes for reacting compounds which contain at least one carbon-carbon or carbon-heteroatom double bond by 1,2-addition in the presence of the catalysts of the invention.
Abstract translation: 本发明涉及包含至少一种金属络合物，其包含至少两个配位体各自具有至少一个pnicogen原子和形成分子间，离子相互作用的官能团能，其特征在于，通过分子间的离子相互作用复合物二聚配体，其包括至少一个，和方法的转化催化剂 含有至少一个碳 - 碳或碳 - 杂原子双键，由1,2-加成在根据本发明的催化剂的存在下的化合物。
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公开(公告)号：WO2010149507A3
公开(公告)日：2011-03-17
申请号：PCT/EP2010058208
申请日：2010-06-11
Applicant: BASF SE , SCHAUB THOMAS , PACIELLO ROCCO , MOHL KLAUS-DIETER , SCHNEIDER DANIEL , SCHAEFER MARTIN , RITTINGER STEFAN
Inventor： SCHAUB THOMAS , PACIELLO ROCCO , MOHL KLAUS-DIETER , SCHNEIDER DANIEL , SCHAEFER MARTIN , RITTINGER STEFAN
CPC classification number: C07C51/00 , B01J31/0237 , B01J31/24 , B01J31/2414 , B01J2231/625 , B01J2531/821 , C07C51/44 , Y02P20/582 , C07C53/02
Abstract: The invention relates to a method for producing formic acid by hydrogenation of carbon dioxide in the presence of a catalyst which contains an element of the 8th, 9th or 10th group of the periodic system, a tertiary amine and a polar solvent, at a pressure of 0.2 to 30 MPa abs and a temperature of 20 to 200°C, thereby producing two liquid phases, and separation of the two liquid phases. The liquid phase (B) enriched by the tertiary amine is returned to the hydrogenation reactor and the formic acid/amine addition product from the liquid phase (A) enriched by the formic acid/amine addition product and the polar solvent is thermally separated into free formic acid and free tertiary amine in a distillation unit and the tertiary amine released during separation and the polar solvent are returned to the hydrogenation reactor.
Abstract translation: 一种用于通过二氧化碳的加氢在含有从组8,9或周期表，叔胺和极性溶剂的10的元素，以0.2至30MPa（绝对）的压力下在催化剂的存在下制备甲酸处理，以及 的20〜200℃下用形成两个液相，两个液体相的分离，其中，所述与叔胺液体相（B）富集温度再循环到氢化反应器中，极性的甲酸/胺加合物与甲酸/胺加合物和 在蒸馏装置的富溶剂的液相（A）热裂解成游离甲酸和自由叔胺和在叔胺的裂解释放的，并且所述极性溶剂是再循环到氢化反应器。
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公开(公告)号：ES2382023T3
公开(公告)日：2012-06-04
申请号：ES01916952
申请日：2001-01-26
Inventor： MCATEE MICHAEL , PACIELLO ROCCO , ULBRICH MICHAEL-DIETER
IPC: C07C29/141 , C01B3/34 , C01B3/36 , C01B3/38 , C01B3/48 , C07B61/00 , C07C2/10 , C07C31/125 , C07C45/50
Abstract: Método para la producción de alcoholes de C9, en el cual a) se proporciona una corriente de hidrocarburo de C4 que contiene buteno y butano; b) se somete la corriente de hidrocarburo de C4 a una oligomerización en un catalizador de oligomerización de olefina y la mezcla de reacción obtenida se separa, en cuyo caso se obtienen una corriente que 5 contiene octenos y una corriente de hidrocarburo de C4 mermada en buteno; c) se somete la corriente de hidrocarburo de C4 mermada en buteno a un reformado con vapor o a una oxidación parcial, en cuyo caso se obtienen monóxido de carbono e hidrógeno; d) se hidroformila la corriente que contiene octenos en presencia de un catalizador de hidroformilación con monóxido de carbono e hidrógeno para producir aldehídos de C9, en cuyo caso el monóxido de carbono empleado y el hidrógeno empleado provienen en más de 80% del paso c); y e) se hidrogenan catalíticamente los aldehídos de C9 con hidrógeno, en cuyo caso el hidrógeno empleado en el paso e) proviene en más de 80% del paso c).
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公开(公告)号：EP3294701A1
公开(公告)日：2018-03-21
申请号：EP16722636
申请日：2016-05-09
Applicant: BASF SE
Inventor： SCHAUB THOMAS , HUGUET SUBIELA NURIA , PACIELLO ROCCO , FRIES DONATA MARIA , MANZINI SIMONE
IPC: C07C51/25
Abstract: A catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt from an alkene, carbon dioxide and an alkoxide having a secondary or tertiary carbon atom directly bound to a [O-] group is described. The alcohol byproduct is distilled off after an intermediate phase separation. This provides pure α,β-ethylenically unsaturated carboxylic acid salt at minimum effort.
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公开(公告)号：ES2990011T3
公开(公告)日：2024-11-28
申请号：ES20733830
申请日：2020-06-24
Applicant: BASF SE
Inventor： SCHELWIES MATHIAS , SCHWABEN JONAS , PACIELLO ROCCO
IPC: C07F9/576 , C07C29/149 , C07C31/08 , C07C31/125 , C07C31/20 , C07C31/27 , C07C33/02 , C07C33/20 , C07C33/22 , C07C33/26 , C07C41/26 , C07C43/23 , C07D213/30 , C07F15/00
Abstract: La invención se refiere a un procedimiento para la hidrogenación de un éster con hidrógeno molecular para dar los alcoholes correspondientes en presencia de un complejo de rutenio (I), en el que dicho complejo contiene un ligando tridentado L de fórmula general (II), n y m son independientemente 0 ó 1, y las líneas dobles continuas-discontinuas representan un enlace simple o un enlace doble, con la condición de que si n = 1, ambas líneas dobles continuas-discontinuas representan un enlace simple y m es 1, y si n = 0, una línea doble continua-discontinua representa un enlace simple y la otra línea doble continua-discontinua representa un enlace doble, y si hay un enlace doble en el lado que da al anillo de fenilo, m = 1, si hay un enlace doble en el lado que da al anillo de piridilo, m = 0, o ambas líneas dobles continuas-discontinuas representan un enlace simple y m es 1. (Traducción automática con Google Translate, sin valor legal)
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