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公开(公告)号：BR112012033462A2
公开(公告)日：2016-11-22
申请号：BR112012033462
申请日：2011-06-21
Applicant: BASF SE
Inventor： SCHNEIDER DANIEL , FRIES DONATA MARIA , MOHL KLAUS-DIETER , SCHAFER MARTIN , PACIELLO ROCCO , RITTINGER SETEFAN , SCHAUB THOMAS
Abstract: processo para preparar ácido fórmico. é descrito um processo para preparar ácido fórmico por reação de dióxido de carbono (1) com hidrogênio (2) em um reator de hidrogenação (1) na presença de um catalisador contendo um elemento do grupo 8,9 ou 10 da tabela periódica, de uma amita terciária contendo pelo menos 12 átomos de carbono por molécula, e de um solvente polar compreendendo um ou mais monoalcoóis selecionados de metanol, etanol, propanóis e butanóis, para formar adutos de ácido fórmico/amina intermediários, que são subsequentemente clivados termicamente, a elaboração dos produtos de saída (3) do reator de hidrogenação (i) sendo realizada com adição de água, e isto aumentando o coeficiente de divisão do caralisador entre a fase superior (4) e a fase inferior.
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公开(公告)号：ZA201305411B
公开(公告)日：2014-10-29
申请号：ZA201305411
申请日：2013-07-18
Applicant: BASF SE
Inventor： SCHAUB THOMAS , FRIES DONATA MARIA , PACIELLO ROCCO , MOHL KLAUS-DIETER , SCHAFER MARTIN , RITTINGER STEFAN , DECKERT PETRA , BASSLER PETER
IPC: C07C20060101
Abstract: The invention relates to a method for producing formic acid by reacting carbon dioxide (1) with hydrogen (2) in a hydrating reactor (I) in the presence of a catalyst comprising an element from the 8th, 9th, or 10th group of the periodic system; a tertiary amine containing at least twelve carbon atoms per molecule; and a polar solvent comprising one or more monoalcohols selected from methanol, ethanol, propanols, and butanols, forming formic acid / amine adducts as intermediate products, which are subsequently thermally split, wherein a tertiary amine having a boiling point at least 5°C higher than formic acid is used, and wherein a reaction mixture comprising the polar solvent, the formic acid / amine adducts, the tertiary amine, and the catalyst forms from the reaction in the hydrating reactor (I) and is discharged as a discharge (3) from the reactor.
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公开(公告)号：CA2838907A1
公开(公告)日：2013-01-10
申请号：CA2838907
申请日：2012-06-27
Applicant: BASF SE
Inventor： SCHAUB THOMAS , FRIES DONATA MARIA , PACIELLO ROCCO , BASSLER PETER , SCHAFER MARTIN , RITTINGER STEFAN
Abstract: Process for the preparation of formic acid by reacting carbon dioxide with hydrogen in a hydrogenation reactor in the presence of a catalyst comprising an element from the 8th, 9th or 10th group of the Periodic Table of the Elements, of a tertiary amine and of a polar solvent, with formation of formic acid-amine adducts, which are then cleaved thermally to give formic acid and tertiary amine.
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公开(公告)号：CA2821642A1
公开(公告)日：2012-06-28
申请号：CA2821642
申请日：2011-12-15
Applicant: BASF SE
Inventor： SCHAUB THOMAS , FRIES DONATA MARIA , PACIELLO ROCCO , MOHL KLAUS-DIETER , SCHAFER MARTIN , RITTINGER STEFAN , DECKERT PETRA , BASSLER PETER
Abstract: The invention relates to a method for producing formic acid by reacting carbon dioxide (1) with hydrogen (2) in a hydrating reactor (I) in the presence of a catalyst comprising an element from the 8th, 9th, or 10th group of the periodic system; a tertiary amine containing at least twelve carbon atoms per molecule; and a polar solvent comprising one or more monoalcohols selected from methanol, ethanol, propanols, and butanols, forming formic acid / amine adducts as intermediate products, which are subsequently thermally split, wherein a tertiary amine having a boiling point at least 5°C higher than formic acid is used, and wherein a reaction mixture comprising the polar solvent, the formic acid / amine adducts, the tertiary amine, and the catalyst forms from the reaction in the hydrating reactor (I) and is discharged as a discharge (3) from the reactor.
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公开(公告)号：CA2765430A1
公开(公告)日：2010-12-29
申请号：CA2765430
申请日：2010-06-11
Applicant: BASF SE
Inventor： SCHAUB THOMAS , PACIELLO ROCCO , MOHL KLAUS-DIETER , SCHNEIDER DANIEL , SCHAFER MARTIN , RITTINGER STEFAN
Abstract: The invention relates to a method for producing formic acid by hydrogenation of carbon dioxide in the presence of a catalyst which contains an element of the 8th, 9th or 10th group of the periodic system, a tertiary amine and a polar solvent, at a pressure of 0.2 to 30 MPa abs and a temperature of 20 to 200°C, thereby producing two liquid phases, and separation of the two liquid phases. The liquid phase (B) enriched by the tertiary amine is returned to the hydrogenation reactor and the formic acid/amine addition product from the liquid phase (A) enriched by the formic acid/amine addition product and the polar solvent is thermally separated into free formic acid and free tertiary amine in a distillation unit and the tertiary amine released during separation and the polar solvent are returned to the hydrogenation reactor.
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Patent Agency Ranking
公开(公告)号：UA104324C2
公开(公告)日：2014-01-27
申请号：UAA201200778
申请日：2010-06-11
Applicant: BASF SE
Inventor： SCHAUB THOMAS , PACIELLO ROCCO , MOHL KLAUS-DIETER , SCHNEIDER DANIEL , SCHAFER MARTIN , RITTINGER STEFAN
Abstract: Способполучениямуравьинойкислотыпутемгидрированиядиоксидауглеродав присутствиикатализатора, которыйсодержитэлемент 8-й, 9-йили 10-йгруппыПериодическойсистемы, третичныйамини полярныйрастворитель, поддавлениемот 0,2 до 30 МПаабс. притемпературеот 20 до 200 °C собразованиемдвухжидкихфаз, разделениеобеихжидкихфаз, причемнасыщеннуютретичнымаминомжидкуюфазу (В) возвращаютв гидрогенизатор, иаддуктмуравьинойкислотыизнасыщеннойаддуктоммуравьинойкислотыс аминоми полярнымрастворителемжидкойфазы (А) подвергаюттермическомурасщеплениюв дистилляторенасвободнуюмуравьинуюкислотуи свободныйтретичныйамин, авысвобожденныйприрасщеплениитретичныйамин, атакжеполярныйрастворительвозвращаютв гидрогенизатор.
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公开(公告)号：CA2856959A1
公开(公告)日：2013-06-27
申请号：CA2856959
申请日：2012-12-14
Applicant: BASF SE
Inventor： SCHNEIDER DANIEL , MOHL KLAUS-DIETER , SCHAFER MARTIN , FRIES DONATA MARIA , TELES JOAQUIM HENRIQUE , BASSLER PETER , RITTINGER STEFAN , SCHAUB THOMAS
Abstract: The invention relates to a method for obtaining formic acid by thermally separating a flow containing formic acid and a tertiary amine (I), wherein a liquid flow containing formic acid, tertiary amine (I), and water is produced by bringing together a tertiary amine (I) and a formic acid source in the presence of water, water and organic decomposition products of the tertiary amine (I) are removed, and formic acid is removed from the obtained liquid flow by means of distillation in a distillation device, wherein the removed flow containing water and organic decomposition products of the tertiary amine (I) is separated into two liquid phases, the upper liquid phase is removed, and the lower liquid phase containing water is fed back to the formic acid source.
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公开(公告)号：ZA201200526B
公开(公告)日：2013-03-27
申请号：ZA201200526
申请日：2012-01-23
Applicant: BASF SE
Inventor： SCHAUB THOMAS , PACIELLO ROCCO , MOHL KLAUS-DIETER , SCHNEIDER DANIEL , SCHAFER MARTIN , RITTINGER STEFAN
IPC: C07C20060101
Abstract: The invention relates to a method for producing formic acid by hydrogenation of carbon dioxide in the presence of a catalyst which contains an element of the 8th, 9th or 10th group of the periodic system, a tertiary amine and a polar solvent, at a pressure of 0.2 to 30 MPa abs and a temperature of 20 to 200°C, thereby producing two liquid phases, and separation of the two liquid phases. The liquid phase (B) enriched by the tertiary amine is returned to the hydrogenation reactor and the formic acid/amine addition product from the liquid phase (A) enriched by the formic acid/amine addition product and the polar solvent is thermally separated into free formic acid and free tertiary amine in a distillation unit and the tertiary amine released during separation and the polar solvent are returned to the hydrogenation reactor.
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公开(公告)号：CA2891452A1
公开(公告)日：2014-05-30
申请号：CA2891452
申请日：2013-11-26
Applicant: BASF SE
Inventor： SCHNEIDER DANIEL , MOHL KLAUS-DIETER , SCHAFER MARTIN , PASCHOLD JURGEN , TELES JOAQUIM HENRIQUE , RITTINGER STEFAN
Abstract: The invention relates to a method for producing methyl formate by carbonylating methanol with carbon monoxide in a carbonylation reactor in the presence of a catalyst system containing alkali formate and alkali alcoholate, thereby obtaining a reaction mixture (RG) which contains methyl formate, alkali formate, alkali alcoholate and optionally unreacted methanol and unreacted carbon monoxide and which is removed from the carbonylation reactor. The reaction mixture (RG) contains at least 0.5 wt.% alkali alcoholate, based on the total weight of the reaction mixture (RG), and the molar ratio of alkali formate to alkali alcoholate in the reaction mixture (RG) is greater than 1.
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公开(公告)号：CA2859128A1
公开(公告)日：2013-06-27
申请号：CA2859128
申请日：2012-11-29
Applicant: BASF SE
Inventor： BASSLER PETER , RITTINGER STEFAN , SCHNEIDER DANIEL , FRIES DONATA MARIA , MOHL KLAUS-DIETER , TELES JOAQUIM HENRIQUE , SCHAFER MARTIN , PASCHOLD JURGEN
Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and tertiary amine (I) is produced by combining tertiary amine (I) and a formic acid source, secondary components comprised therein are separated off, formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, where the bottom output from the distillation apparatus is separated into two liquid phases, and the upper liquid phase is recirculated to the formic acid source and the lower liquid phase is recirculated to the separation of the secondary components and/or to the distillation apparatus, wherein low boilers are removed by distillation from the upper liquid phase and recirculated to the depleted stream.
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