公开(公告)号：JPS63170305A

公开(公告)日：1988-07-14

申请号：JP246387

申请日：1987-01-08

Applicant: DAICEL CHEM

Inventor： KAGOTANI MASAHIRO ,  AIZAWA KATSUMI

IPC: A01N43/16

Abstract: PURPOSE:To obtain a termite expellent with low toxicity, containing a quaternary ammonium salt of a carboxymethyl cellulose derivative as an active ingredient and capable of sustaining effects thereof for a long period without a fear of environmental pollution. CONSTITUTION:A termite expellent containing a quaternary ammonium salt of a carboxymethyl cellulose derivative, particularly preferably hydroxyalkyl carboxymethyl cellulose, alkyl carboxymethyl cellulose as an active ingredient. The expellent is used by dissolving the active ingredient in an organic solvent such as a lower alcohol, e.g. methanol, ethanol, etc. Since the termite expellent is fixed in the form of a film on the surface or surface layer of wood and is insoluble in water, effects are sustained for a long period even in a place with a high humidity without running off by water. There is no fear of pollution by runoff. Since the above-mentioned active ingredient is insoluble in water and hydrophilic, it has affinity for wood, etc.

公开(公告)号：JPS63166810A

公开(公告)日：1988-07-11

申请号：JP31277286

申请日：1986-12-27

Applicant: DAICEL CHEM

Inventor： KAGOTANI MASAHIRO ,  YAMAMOTO MASAKO

IPC: B27K3/34 ,  A01N43/16

Abstract: PURPOSE:To obtain a termite expellent sustaining effects for a long period, having no fear of environmental pollution by washing away, comprising quaternary ammonium salt of carboxymethyl cellulose as an active ingredient. CONSTITUTION:A termite expellent comprising quaternary ammonium salt of carboxymethyl cellulose which, for example, can be readily synthesized from sodium salt of carboxymethyl cellulose and a quaternary ammonium halide as an active ingredient. The quaternary ammonium salt of CMC is fixed to the surface or the surface layer of wood as a film. Since the film is water- insoluble, it will not flow and since the quaternary ammonium salt has alginic acid as skeleton, it has hydrophilic nature and affinity for wood, penetrated, adsorbed and retained. The amount of the active ingredient used is 0.1-25wt.%.

公开(公告)号：JPS617284A

公开(公告)日：1986-01-13

申请号：JP12762184

申请日：1984-06-22

Applicant: Daicel Chem Ind Ltd

Inventor： SUTEFUAN HANESHIAN ,  KAGOTANI MASAHIRO

IPC: C07H1/00 ,  C07H13/04 ,  C07H15/04

CPC classification number: C07H13/04 ,  C07H1/00 ,  C07H15/04

Abstract: PURPOSE: To carry out the selective decetylation of acetyl derivative of a monosaccharide or oligosaccharide at a specific position in the molecule, by treating the derivative with a mixture of an aqueous solution of an alkali metal hydroxide, an aqueous solution of hydrogen peroxide and an organic solvent.
CONSTITUTION: Acetyl derivative of a monosaccharide or oligosaccharide (e.g. methyl-2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside of formula) is dissolved e.g. in THF. A mixture of an aqueous solution of an alkali metal hydroxide, aqueous solution of hydrogen peroxide and an organic solvent [preferably a mixture of lithium hydroxide equivalent to the acetyl group to be hydrolyzed, 5W20mol equivalent (based on the lithium hydroxide) of 10W50% solution of hydrogen peroxide, and THF] is added dropwise to the above solution, made to react with each other at 0W50°C, added with sodium thiosulfate, and separated and purified to obtain the objective compound. For example, the compounds of formula I and IIis hydrolyzed selectively at the 2C position and the compound of formula IIIis hydrolyzed at the 6C position.
COPYRIGHT: (C)1986,JPO&Japio

Abstract translation: 目的：在分子中特定位置进行单糖或寡糖的乙酰衍生物的选择性脱乙酰化，通过用碱金属氢氧化物水溶液，过氧化氢水溶液和有机物的混合物 溶剂。 构成：将单糖或寡糖（如式的甲基-2,3,4,6-四-O-乙酰基-α-D-吡喃葡萄糖苷）的乙酰基衍生物溶解， 在THF中。 碱金属氢氧化物的水溶液，过氧化氢水溶液和有机溶剂的混合物（优选与待水解的乙酰基相当的氢氧化锂的混合物，5-20摩尔当量（基于氢氧化锂）为10 -50％的过氧化氢和THF溶液]滴加到上述溶液中，在0-50℃下彼此反应，加入硫代硫酸钠，分离并纯化，得到目标化合物。 例如，式I和II的化合物在2C位被选择性水解，式III化合物在6C位水解。

公开(公告)号：JPS59231040A

公开(公告)日：1984-12-25

申请号：JP10546083

申请日：1983-06-13

Applicant: DAICEL CHEM

Inventor： KAGOTANI MASAHIRO ,  KOJIMA HIDETAKA

IPC: C07C51/56 ,  B01J31/00 ,  B01J31/26 ,  C07B61/00 ,  C07C51/00 ,  C07C53/08 ,  C07C53/12 ,  C07C53/122 ,  C07C67/00

Abstract: PURPOSE:To carry out the carbonylation of an O-methylated compound capable of forming methyl iodide in the reaction system, economically, under specific condition, by using a main catalyst comprising rhodium and a cocatalyst comprising a zero-valent carbonyl complex compound of a specific metal and a Lewis acid containing metallic atom. CONSTITUTION:The objective compound e.g. acetic anhydride useful industrially as an acetylation agent of the raw material for the production of acetyl cellulose, etc., is produced by the carbonylation of an O-methylated compound capable of forming methyl iodide in the reaction system, especially methyl acetate, or a mixture of said compound and methanol, with carbon monoxide in a liquid phase in the presence of rhodium catalyst and an iodine compound. In the above process, the rate of reaction of the O-methylated compound with carbon monoxide is improved using a cocatalyst consisting of a combination of (a) a zero- valent carbonyl complex compound of a metal of the VIB-group of the periodic table (Cr, Mo or W) and (b) a Lewis acid containing metallic atom.

公开(公告)号：JP2008088436A

公开(公告)日：2008-04-17

申请号：JP2007319808

申请日：2007-12-11

Applicant: Daicel Chem Ind Ltd ,  National Institute Of Advanced Industrial & Technology ,  Toru Nonami ,  Tougeda Hiroshi ,  ダイセル化学工業株式会社 ,  博史 垰田 ,  独立行政法人産業技術総合研究所 ,  野浪 亨

Inventor： TAODA HIROSHI ,  NONAMI TORU ,  FUJIWA TAKAAKI ,  KAGOTANI MASAHIRO

IPC: C09D201/00 ,  B01D53/86 ,  B01J35/02 ,  C09C1/36 ,  C09C3/06 ,  C09D5/00 ,  C09D5/02 ,  C09D7/12 ,  C09D185/00

Abstract: PROBLEM TO BE SOLVED: To provide a paint composition superior in water resistance, weather resistance and durability, and capable of maintaining beautiful appearance for a long period of time. SOLUTION: The paint composition comprises paint components, calcium phosphate and titanium oxide. As a photocatalyst, titanium oxide particles of which the surfaces are partially coated with calcium phosphate, or a porous body of which the surface is coated with a titanium oxide film and further the surface of the titanium oxide film is partially coated with calcium phosphate, is used. The crystal form of the titanium oxide is preferably anatase. As an organic paint, a vinyl synthetic resin emulsion, and as an inorganic paint, a solution containing a metal alkoxide for forming the coating film by sol-gel method and the like, are cited. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供耐水性，耐候性和耐久性优异且能够长时间保持美观的涂料组合物。

解决方案：涂料组合物包括油漆组分，磷酸钙和氧化钛。 作为光催化剂，表面被磷酸钙部分地涂覆的氧化钛粒子，或表面被氧化钛膜覆盖的多孔体，另外，氧化钛膜的表面部分被磷酸钙覆盖，是 用过的。 氧化钛的晶体形式优选为锐钛矿型。 作为有机涂料，可以使用乙烯基合成树脂乳液，作为无机涂料，使用通过溶胶 - 凝胶法形成涂膜的金属醇盐溶液等。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2000001631A

公开(公告)日：2000-01-07

申请号：JP4029699

申请日：1999-02-18

Applicant: AGENCY IND SCIENCE TECHN ,  DAICEL CHEM ,  TOUGEDA HIROSHI ,  NONAMI TORU

Inventor： TOUGETA HIROSHI ,  NONAMI TORU ,  FUJIWA TAKAAKI ,  KAGOTANI MASAHIRO

IPC: B01J27/18 ,  B01J35/02 ,  C09D5/00 ,  C09D5/02 ,  C09D5/16 ,  C09D7/12 ,  C09D133/04

Abstract: PROBLEM TO BE SOLVED: To provide a coating composition having excellent water-resistance, weather-resistance and durability and capable of keeping beautiful appearance over a long period. SOLUTION: This coating composition contains a coating component and a photo-catalyst containing calcium phosphate and titanium oxide. The photo- catalyst is titanium oxide particle partly coated its surface with calcium phosphate or a porous material surface-coated with a titanium oxide film and further coated a part of the titanium oxide film surface with calcium phosphate. The titanium oxide preferably has anatase crystal form. The composition is a vinyl- based synthetic resin emulsion as an organic coating material or a solution containing a metal alkoxide for forming a coating film by sol-gel method, etc., as an inorganic coating material.

公开(公告)号：JP2506682B2

公开(公告)日：1996-06-12

申请号：JP21345486

申请日：1986-09-09

Applicant: DAICEL CHEM

Inventor： KAGOTANI MASAHIRO

IPC: C08J9/28

公开(公告)号：JPH0269501A

公开(公告)日：1990-03-08

申请号：JP21978888

申请日：1988-09-02

Applicant: DAICEL CHEM

Inventor： KAGOTANI MASAHIRO ,  KIYOSE ATSUNOBU ,  KUWANA TAKAAKI

IPC: C08B11/04 ,  C08B37/00 ,  C08B37/02

Abstract: PURPOSE:To obtain the title compound suitable in using for chemical modification of protein such as enzyme or antibody and biochemical substance such as hormone, peptide or medicine by reacting a hydroxyl group-containing water soluble high polymer compound with aminoethyl sulfate and alkali water solution. CONSTITUTION:A water soluble high polymer compound (preferably dextrane, hydroxyethyl cellulose, hydroxypropyl cellulose or pullulan) having hydroxyl group is reacted with 2-aminoethyl sulfate in an alkali water solution, preferably at 70-120 deg.C to provide the aimed compound having 0.02-1.0 average substitution degree per glucose unit of aminoethyl group and 5000-5000000 molecular weight.

公开(公告)号：JPH0255701A

公开(公告)日：1990-02-26

申请号：JP20710388

申请日：1988-08-19

Applicant: DAICEL CHEM

Inventor： KAGOTANI MASAHIRO ,  KAINO YOSHIAKI

IPC: B01J20/281 ,  B01D15/08 ,  B01J20/26 ,  C08B3/24 ,  G01N30/88

Abstract: PURPOSE:To produce fine globular cellulose particles which can satisfy both separation performance and flow velocity properties by a allowing a specific crosslinking agent to be present when fine globular cellulose triacetate particles are subjected to alkali hydrolysis. CONSTITUTION:When fine globular cellulose triacetate particles (those having a particle size of 10-500mu is preferred, especially preference being given to those having a uniform network structure) are hydrolyzed with an alkali into fine globular cellulose particles, a compound having 2 or more functional groups in the molecule which can produce ether linkages by the reaction with the hydroxyl groups (e.g., epichlorohydrin) is added as a crosslinking agent into the reaction system. According to the process, formation of hydrogen bonds can be inhibited, shrinkage of the cellulose which is forming can be suppressed, and therefore cellulose particles which can satisfy both separation performance and flow velocity properties can be obtained. Further, by controlling the concentration of the alkali in the system, crosslinking can be effected under various swelling conditions to control the properties of cellulose particles that will be produced.

公开(公告)号：JPH01194991A

公开(公告)日：1989-08-04

申请号：JP22187788

申请日：1988-09-05

Applicant: TANABE SEIYAKU CO ,  DAICEL CHEM

Inventor： SATO TADASHI ,  WATANABE TAIZO ,  MINOBE SATOSHI ,  NISHIMURA TAKASHI ,  KAGOTANI MASAHIRO ,  ASE TOMONOBU ,  HONDA ZENJIRO ,  NAGAMATSU SHINJI

IPC: A61K9/08 ,  A61L2/02 ,  B01D15/00 ,  B01D61/14 ,  B01D61/58 ,  C02F1/28 ,  C02F1/44

Abstract: PURPOSE:To remove pyrogen (heat-generating material) efficiently from a pyrogen-contg. liquid, by using a membrane together with a pyrogen-adsorbing body. CONSTITUTION:Raw water (a) is pressure-increased by a pump (b) and filtered with an ultrafilter membrane module (c) to give a permeated water. Then, the resulting water is re-pressurized by a pump (e) and filtered through an adsorbing body (d) having a large filling capacity to remove pyrogen perfectly and give pyrogen-removed water (g).