公开(公告)号：JPH07188522A

公开(公告)日：1995-07-25

申请号：JP33126293

申请日：1993-12-27

Applicant: KAO CORP

Inventor： HOSOKAWA YASUTOKU ,  SUZUKI FUMITO ,  SATO TAKAHIRO

IPC: C08L67/02 ,  C08L67/00

Abstract: PURPOSE:To obtain a polyester resin composition excellent in impact resistance, rigidity, dimensional stability, molding processability, gloss and environmental characteristics, useful for sheets, etc., by incorporating a resin with a specific glass transition temperature in a blend of a polyester resin and a polyarylate resin. CONSTITUTION:This composition can be obtained by incorporating (A) 100 pts.wt. of a blend resin of (1) a polyester resin made up of a dicarboxylic acid component predominant in terephthalic acid and a diol component 3-80mol% of which is a diol of formula I [X is C2H4, of formula II (Y and Z are each H or a 1-3C alkyl), O or SO2; a is 0 or 1; m and n are each 1-5], a doil of formula III, or p-xylene glycol of formula IV and (2) a polyarylate resin at the weight ratio of (99:1) to (50:50) with (B) 1-30 pts.wt. of a resin

公开(公告)号：JPH07179613A

公开(公告)日：1995-07-18

申请号：JP32691293

申请日：1993-12-24

Applicant: KAO CORP

Inventor： NAKANO YUKIHIRO ,  HOSOKAWA YASUTOKU

IPC: C08J3/12 ,  C08J3/24

Abstract: PURPOSE:To coat a specific water-absorbing resin powder with a cross-linker uniformly in a short time to impart excellent water absorption rate and gel strengths to the resin by placing the powder on a specific support and immersing the powder together with the support in a soln. contg. the cross-linker. CONSTITUTION:A water-absorbing carboxylated resin powder 11 is placed on a box-shaped support having many openings smaller than the particle size of the powder, lowered together with the support in the direction of the arrow A into a soln. 11 comprising water and/or a hydrophilic org. solvent and a cross-linker, a compd. having at least two carboxyl-reactive groups. immersed in the soln. for a specified time, and pulled up together with the support in the direction of the arrow B. Thus, the powder is coated with the cross-linker in a short time, giving a water-absorbing resin improved in the balance among water-absorption capacity, water-absorption rate, and gel strengths.

公开(公告)号：JPH06211973A

公开(公告)日：1994-08-02

申请号：JP461393

申请日：1993-01-14

Applicant: KAO CORP

Inventor： SUZUKI FUMITO ,  HOSOKAWA YASUTOKU

IPC: B29C49/04 ,  B29K67/00 ,  B65D1/10 ,  C08G63/183 ,  C08G63/19 ,  C08G63/66 ,  C08G63/672

Abstract: PURPOSE:To obtain a polyester resin which is transparent and impact-resistant, can be molded by direct blow molding, and can substitute for a polyvinyl choride resin. CONSTITUTION:This polyester resin for extrusion blow molding is produced by reacting a dicarboxylic acid component mainly comprising terephthalic acid with a glycol component contg. 5-80mol% compd. of the formula (wherein (m) and (n) are each an integer of 1-5). A hollow container is made from this resin.

公开(公告)号：JPH04352646A

公开(公告)日：1992-12-07

申请号：JP11982491

申请日：1991-05-24

Applicant: KAO CORP

Inventor： TAKEI SHINOBU ,  OTANI SHOJI ,  OSAWA TETSUHIRO ,  HOSOKAWA YASUTOKU

IPC: B32B1/02 ,  B32B27/36 ,  B65D35/08

Abstract: PURPOSE:To provide a tube container which is oil-resistant, not apt to deform and swell during preservation against oily contents for instance, excellent in heat-sealing ability after change of contents, easy to squeeze the contents up to the last, and large in the jointing force to unify the shell with the head. CONSTITUTION:A tube container is made joining the shell and the head. At least the innermost layer at the shell of this tube container has the glass transfer temperature Tg of about 50 deg.C or higher and it is made of an amorphous or low crystalline polyester resin having about 0.7eta or more of intrinsic viscosity. And the head of tube container is made of polyester resin having about 40 deg.C or below glass transfer temperature Tg.

公开(公告)号：JPH04149230A

公开(公告)日：1992-05-22

申请号：JP27486190

申请日：1990-10-12

Applicant: KAO CORP

Inventor： SUZUKI FUMITO ,  HOSOKAWA YASUTOKU ,  AMIYA TSUYOSHI ,  YASUDA YUTAKA

IPC: C08G63/181 ,  C08G63/19 ,  C08G63/60

Abstract: PURPOSE:To obtain the subject resin, containing isophthalic acid as a principal component of a dicarboxylic acid component and m-xylylene glycol as a principal component of a glycol component, excellent in gas barrier properties, especially water vapor barrier properties and useful as bags, containers, etc. CONSTITUTION:The objective resin in which >=80mol% dicarboxylic acid residue constructing a polyester is isophthalic acid unit and >=75mol% glycol residue is m-xylylene glycol unit.

公开(公告)号：JPH0341162A

公开(公告)日：1991-02-21

申请号：JP17673789

申请日：1989-07-07

Applicant: KAO CORP

Inventor： HOSOKAWA YASUTOKU ,  ITO TAKASHI ,  AMIYA TSUYOSHI ,  YASUDA YUTAKA

IPC: C08L27/12 ,  C08J3/05 ,  C08J7/00 ,  C08L101/00

Abstract: PURPOSE:To obtain the title molding excellent in liquid repellency, stain resistance, releasability, etc., by adding a specified amount of a polymer having a specified perfluoroalkyl to a thermoplastic resin, molding the mixture, and heat-treating the molding. CONSTITUTION:A (meth)acrylic ester having a 5-16C perfluoroalkyl (e.g. formula I or II) is homopolymerized or copolymerized with a copolymerizable monomer (e.g. stearyl methacrylate) in the presence of a mercaptan compound of formula III (wherein (n) is 8-18). 0.1-5 pts.wt. obtained perfluoroalkylated polymer is added to 100 pts.wt. thermoplastic resin (e.g. polyethylene), and the mixture is well mixed. The obtained thermoplastic resin composition is molded and heat-treated at 70-130 deg.C to obtain a thermoplastic resin molding of excellent liquid repellency.

公开(公告)号：JPH01259009A

公开(公告)日：1989-10-16

申请号：JP8756188

申请日：1988-04-08

Applicant: KAO CORP

Inventor： INOUE SHOHEI ,  AIDA TAKUZO ,  KUROKI MASAKATSU ,  HOSOKAWA YASUTOKU

IPC: C08F4/52 ,  C08F4/42 ,  C08F12/20 ,  C08F20/00 ,  C08F20/12

Abstract: PURPOSE:To produce a polyacrylic ester with a narrow molecular-weight distribution and molecular-weight almost in agreement with the theoretical value by polymerizing an acrylate using a specified aluminum porphyrin complex as an initiator. CONSTITUTION:An acrylic ester (e.g., methyl acrylate or hexafluoroisopropyl acrylate) is polymerized normally under an inert gas such as nitrogen or helium and using, as an initiator, an aluminum porphyrin complex of the formula (R1 and R2 are H or 1-10C hydrocarbon; R3 is H or 1-20C hydrocarbon which may have functional groups such as halogen, alkoxy or ester; X is enolate or thiolate) and a solvent such as benzene or THF.

公开(公告)号：JPS63152667A

公开(公告)日：1988-06-25

申请号：JP19938487

申请日：1987-08-10

Applicant: KAO CORP

Inventor： HOSOKAWA YASUTOKU ,  KOBAYASHI TAKATOSHI

IPC: C08L33/02 ,  A61L15/60 ,  B01J20/26 ,  C08K5/00 ,  C08L33/04 ,  C08L101/00

Abstract: PURPOSE:To obtain the titled resin keeping outstanding water-absorptive performance with high gel strength when swelled and high stability with time of the swollen gel, by blending specified proportion of a water-absorptive resin and radical chain inhibitor. CONSTITUTION:The objective resin can be obtained by blending (A) a water- absorptive resin (e.g., polyacrylic acid salt crosslinked product) and (B) 0.01-30wt.% of a radical chain inhibitor (pref., with a solubility >=0.1g per 100g of water at 25 deg.C such as pyrogallol or gallic acid).