公开(公告)号：JP2000063786A

公开(公告)日：2000-02-29

申请号：JP23732598

申请日：1998-08-24

Applicant: KAO CORP

Inventor： KITAYAMA HIROAKI ,  OTANI SHOJI ,  SHIBA KENICHI

IPC: C08K5/10 ,  C09J9/00 ,  C09J11/06 ,  C09J133/06

Abstract: PROBLEM TO BE SOLVED: To efficiently and economically prevent deterioration of UV printing, etc., caused by a large amount of ultraviolet rays by adding an aromatic compound containing no phenolic hydroxyl group to an acrylic tacky agent. SOLUTION: This method for preventing ultraviolet deterioration of a tacky agent comprises adding (B) an aromatic compound containing no phenolic hydroxyl group, preferably an aromatic carboxylic acid ester (e.g. trimellitic acid trioctyl ester, etc.), to (A) an acrylic tacky agent preferably using a polymer obtained by polymerizing a monomer containing >=50 wt.% of a 9-14C alkyl group-containing acrylic acid or methacrylic acid alkyl ester-based monomer. The amount of the component B is preferably 0.1 wt.% based on the component A.

公开(公告)号：JPH11981A

公开(公告)日：1999-01-06

申请号：JP13157298

申请日：1998-05-14

Applicant: KAO CORP

Inventor： OTANI SHOJI ,  OSAWA TETSUHIRO ,  TAKITA MASANORI

IPC: B65D1/00 ,  B29C49/08 ,  B29K67/00 ,  B29L22/00 ,  B32B27/00 ,  B32B27/36 ,  B65D1/09 ,  C08J5/00 ,  C08L23/00 ,  C08L25/00 ,  C08L33/00 ,  C08L67/02

Abstract: PROBLEM TO BE SOLVED: To provide a container having very uniform and fine surface texture and depth and exhibiting soft pearl gloss. SOLUTION: This container comprises 50 to 99 pts.wt. of thermoplastic polyester resin A and 50 to 1 pts.wt. of resin B incompatible with the resin A. In this case, when a surface layer is divided into 1, inner layer is divided into 8 and an innermost layer is divided into 1 in a thickness direction of a wall of the container, the resin A preferentially exists in the surface layer, and is constituted so that mean content of the resin B incompatible with the resin A in the surface layer satisfies formulae 0.1

公开(公告)号：JPH08244833A

公开(公告)日：1996-09-24

申请号：JP4591195

申请日：1995-03-06

Applicant: KAO CORP

Inventor： IWASAKI HIROAKI ,  KATO KYOICHI ,  OTANI SHOJI

IPC: B65D65/40 ,  B32B15/08 ,  C08F255/00 ,  C08L23/26 ,  C08L67/00 ,  C09J7/02 ,  C09J123/26 ,  C09J167/00

Abstract: PURPOSE: To obtain a metallic container-sealing film superior in high-frequency sealing properties and extrusion laminating properties even in the storage of a content containing a volatile ingredient in a metallic container, free from occurrence of deterioration, such as delamination, even under a long-term storage, and capable of keeping a content with a good quality without evaporation. CONSTITUTION: A metallic container-sealing film for sealing a mouth part of a metallic container is made of a film-form laminate comprising an aluminum foil layer, a high-frequency welding layer forming a sealing surface, and a low-softening polyester layer provided between the aluminum foil layer and the high-frequency welding layer. The high-frequency welding layer is made of a resin composition composed of 5-50 pts.wt. modified polyolefin resin as a dispersion phase and 95-50 pts.wt. polyester resin as a matrix containing a crystalline polyester resin having a melting point of 120 deg.C or lower, a crystalline melt heating value of 5-30mJ/mg, and a melt flow rate of 30 or less, The low-softening polyester layer has a softening temperature of 200 deg.C or lower.

公开(公告)号：JPH08231778A

公开(公告)日：1996-09-10

申请号：JP4082495

申请日：1995-02-28

Applicant: KAO CORP

Inventor： ODAKURA SHINJI ,  SANO YASUNORI ,  OTANI SHOJI

IPC: C08J5/00 ,  C08K3/26 ,  C08L23/00 ,  C08L23/26

Abstract: PURPOSE: To obtain a plastic molded material such as a bottle generating a small quantity of combustion heat, expectable to environmental corrective action of a molding cycle improvement according to shortening of a cooling time, and having excellent strength and low cost by molding a polyolefin resin composition containing a specific inorganic material and a dispersant. CONSTITUTION: The objective molded material is obtained by molding a resin composition composed of (A1 ) 100 pts.wt. of a polyolefin, (A2 ) 3-80 pts.wt. of a carbonate as an inorganic material [e.g., calcium carbonate or (basic) magnesium carbonate] and (A3) 0.1-20 pts.wt. of a modified polyolefin having a carboxylic acid group as a dispersant [e.g., polyethylene, polypropylene or polybutene containing (meth)acrylic acid or maleic acid anhydride as a copolymerizing component].

公开(公告)号：JPH08143020A

公开(公告)日：1996-06-04

申请号：JP28696294

申请日：1994-11-21

Applicant: KAO CORP

Inventor： KATO KYOICHI ,  IWASAKI HIROAKI ,  OTANI SHOJI

IPC: B65D1/00 ,  B32B1/02 ,  B32B15/08 ,  B32B15/09 ,  B65D1/09 ,  B65D35/08 ,  B65D51/00

Abstract: PURPOSE: To provide a plastic container which is excellent as a container for storing contents including oil, fragrant ingredients and medical ingredients wherein there is no danger for harming environments, the container is excellent in resistance against oil, heat sealing ability and flexibility, and surface slip and mold release are remarkably improved and to provide a film excellent in high frequency sealing. CONSTITUTION: A plastic container comprises a container and a film-like laminated body wherein at least the innermost layer of the container is formed of a resin mixture wherein a dispersed phase is 5 to 50wt. part of acid-denatured polyolefin resin and a matrix is 95 to 50wt. part of polyester resin including crystalline polyester resin whose glass transition temperature (Tg) is 30 deg.C or lower. In a film for sealing the container for sealing a mouth of the container, a layer on at least a side of a sealing face in the film-like laminated body is formed of a resin mixture.

公开(公告)号：JPH05156144A

公开(公告)日：1993-06-22

申请号：JP9472092

申请日：1992-04-15

Applicant: KAO CORP

Inventor： TAKEI SHINOBU ,  IWASAKI HIROAKI ,  OTANI SHOJI ,  OSAWA TETSUHIRO ,  HOSOKAWA YASUTOKU

IPC: B32B1/02 ,  B32B27/34 ,  B32B27/36 ,  B65D35/08 ,  C08L67/00 ,  C08L67/02 ,  C08L77/00

Abstract: PURPOSE:To provide a resin compsn. excellent in oil resistance and flexibility and suitable as a material of a container which is neither deformed nor swollen even by the contents contg. an oil in a high proportion and excellent in squeezability, adhesion by pinch-off, and heat-sealing properties, and to provide the container. CONSTITUTION:At least one amorphous or lowly crystalline resin selected from the group consisting of polyester and polyamide resins each having a glass transition point of about 50 deg.C or higher is blended with at least one resin selected from the group consisting of polyester and polyamide resins each having a glass transition point of about 40 deg.C or lower, thereby giving the objective resin compsn.

公开(公告)号：JPH01235959A

公开(公告)日：1989-09-20

申请号：JP6294388

申请日：1988-03-16

Applicant: KAO CORP

Inventor： OTANI SHOJI ,  YAMAGUCHI TAKASHI ,  KATAYOSE MASAHIRO ,  TSUSHIMA RIKIO

IPC: G03G9/08 ,  G03G9/087 ,  G03G9/097

Abstract: PURPOSE:To improve the cleaning property of the title toner by constituting the toner of a spherical toner particle having specified mean volume particle size and atomic ratio of a fluorine atom. to a carbon atom. in the surface layer of a toner particle, respectively. CONSTITUTION:The toner is constituted of the spherical toner particle which has the mean volume particle size of 2-20mum and contains the fluorine atom. in the surface layer of the toner particle in the atomic ratio of the fluorine atom. to the carbon atom. of a range of 0.01-1.000. The toner particle is produced by a suspension polymerization method. In this case, when the atomic ratio of the fluorine atom. to the carbon atom. is =1.0, adversely, the effect of the fluorine atom. to the electrostatic charging property of the toner particle becomes large, thereby taking place an undesirable phenomenon in image quality such as a white spot and an image unsharp, etc. Thus, in case that the toner particle is produced by the suspension polymerization, the faulty cleaning property of the toner particle caused by sticking force is improved, and the toner having the good flowability and the less change of the image quality which are the characteristic of the toner particle obtd. by the suspension polymerization is obtd.

公开(公告)号：JPS63291905A

公开(公告)日：1988-11-29

申请号：JP12764187

申请日：1987-05-25

Applicant: KAO CORP

Inventor： OTANI SHOJI ,  MUROI YOSHIYUKI ,  TSUSHIMA RIKIO

IPC: C08F2/08 ,  C08F210/00 ,  C08F210/10 ,  C08F220/04 ,  C08F222/06

Abstract: PURPOSE:To obtain spherical particles useful as an adhesive and a cement mixing agent, having a particle diameter distribution of monodisperse system in high yield and as primary particles, by copolymerizing an olefin with maleic anhydride in the presence of a specific dispersant. CONSTITUTION:In copolymerizing 2-8C olefin with maleic anhydride, radical polymerization is carried out in a solvent (e.g. acetone or methyl acetate) to dissolve the monomers but not the prepared copolymer in the presence of an oil-soluble cationic copolymer consisting of an ethylenic unsaturated monomer unit containing a cationic group shown by the formula [R1, R2 and R3 are 1-22C (substituted)alkyl and two of R1, R2 and R3 together with neighboring N may form ring structure; Y is halogen or acid residue] and a lipophilic ethylenic unsaturated monomer unit.

公开(公告)号：JPS62220593A

公开(公告)日：1987-09-28

申请号：JP6282986

申请日：1986-03-20

Applicant: KAO CORP

Inventor： OTANI SHOJI ,  KOGAI MASAHIKO ,  HASHIMOTO JIRO ,  KOBAYASHI YUICHIRO ,  MURAMATSU TAKAHIRO

IPC: C10M145/14 ,  C10M149/10 ,  C10N30/02 ,  C10N30/04 ,  C10N30/08 ,  C10N40/00 ,  C10N40/25

Abstract: PURPOSE:The titled improved having improved cleaning and dispersing action and heat stability, comprising a compound obtained by radically polymerizing a nitrogen-containing monomer in the presence of a copolymer of a higher and a lower alkyl(meth)acrylates/styrene as an essential component. CONSTITUTION:(D) A viscosity index improver for lubricating oil comprising a compound obtained by radically polymerizing 2-10pts.wt. monomer containing nitrogen in the molecule polymerized in the presence of a copolymer consisting of (A) 50-95pts.wt. 8-20C higher alkyl (meth)acrylate, (B) 0-20pts.wt. 1-4C lower alkyl (meth)acrylate and (C) 3-20pts.wt. styrene as an essential component. N-Vinyl-2-pyrrolidone may be cited as the preferably example of the component D.

公开(公告)号：JPH09230791A

公开(公告)日：1997-09-05

申请号：JP3521096

申请日：1996-02-22

Applicant: KAO CORP

Inventor： ODAJIMA SHINGO ,  OSAWA TETSUHIRO ,  OTANI SHOJI

IPC: B65B61/02 ,  B29C49/04 ,  B29C49/06 ,  B29C49/24 ,  B31D1/02 ,  B32B27/32 ,  C09D123/06 ,  G09F3/04

Abstract: PROBLEM TO BE SOLVED: To obtain a thermally active label which has excellent low-temp. adhesive strength and does not cause blocking by forming an adhesive for forming an adhesive layer of a specific resin. SOLUTION: The adhesive used for the adhesive layer of the thermally active type label having a base material and the adhesive layer formed on the rear surface side of this base material is formed of an ethylene-α-olefin copolymer polymerized by using a catalyst contg. a metallocene compd. The thermally active label refers to the label which is preferably formed by printing the front surface (rear surface) of the base material with various kinds of information, exhibits tacky adhesiveness and adhesiveness (is thermally activated) by heating the label to a temp. higher than room temp. and does not exhibit the tacky adhesiveness and adhesiveness before the thermal activation, i.e., at a room temp. and may be preserved and handled even if a release paper, etc., are not used. The specific resin to be used as the adhesive is the ethylene-α-olefin copolymer (MPE) polymerized by using a catalytic system using the metallocene compd.