公开(公告)号：JP2001049298A

公开(公告)日：2001-02-20

申请号：JP22971699

申请日：1999-08-16

Applicant: KAO CORP

Inventor： ISHIKAWA AKIRA ,  FUJII YUKIKO ,  YANAGISAWA YUKI

IPC: C11D17/08 ,  C11D1/04 ,  C11D3/30 ,  C11D9/30 ,  C11D10/04

Abstract: PROBLEM TO BE SOLVED: To obtain a liquid detergent composition which exhibits detergency higher than that of a solid soap in cleaning muddy dirt on clothes, socks, etc., especially muddy dirt in the case when used for coating, and is excellent in liquid stability by compounding saturated and unsaturated fatty acids having specified numbers of carbon atoms and/or their salts with a surfactant other than the foregoing acids and/or their salts in a specified wt. ratio. SOLUTION: This composition is prepared by compounding (A) 1-30 wt.% sum of an 8-14C saturated fatty acid and/or its salt and a 14-18C unsaturated fatty acid and/or its salt with (B) 0.5-20 wt.% surfactant other than the foregoing acids and/or their salts in a wt. ratio of (A)/(B) of (1/20)-(2/3). Preferably, ingredient B mainly comprises an anionic or nonionic surfactant. The further addition of an alkanolamine in an amount of 0.5 wt.% or higher further improves the liquid stability. The alkanolamine may be added in the form of a salt of ingredient A or an anionic surfactant.

公开(公告)号：JP2000169898A

公开(公告)日：2000-06-20

申请号：JP34848298

申请日：1998-12-08

Applicant: KAO CORP

Inventor： YANAGISAWA YUKI ,  ISHIKAWA AKIRA

IPC: C11D3/50 ,  C11D17/04 ,  C11D17/08

Abstract: PROBLEM TO BE SOLVED: To obtain an article for laundry capable of effectively modulating perfume that smells during washing and remains in wearing a cloth, depending on the choice of a user by combining a product for cleaning including a detergent composition and a product including perfume prepared separately and properly using them in a washing process. SOLUTION: This article for laundry comprises a product for washing including (A) a detergent composition, and (B) a product including perfume differing from the product (A), and used only for imparting a smell. A detergent composition free from perfume or including only a small amount of perfume is preferred as the detergent used in the product (A), and the detergent composition is preferably used in a concentration of 0.01-0.2 wt.% in water in a washing vessel. The product (B) is preferably prepared so as to have a selectable perfume concentration by charging to a constant delivery pump or the like. The preferable concentration of the perfume is 7-12 wt.%. In the washing, the products (A) and (B) are thrown into a washing vessel, or throwing the product (A) in a washing vessel and the product (B) in a rinsing vessel.

公开(公告)号：JPH11131100A

公开(公告)日：1999-05-18

申请号：JP29715797

申请日：1997-10-29

Applicant: KAO CORP

Inventor： KASAI KATSUHIKO ,  YANAGISAWA YUKI ,  KAMIOKA SACHIKO ,  TAGATA HIDEJI

IPC: C11D1/14 ,  C11D1/24 ,  C11D1/28 ,  C11D1/29 ,  C11D1/52 ,  C11D11/02 ,  C11D17/06

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a highly dense granular detergent, capable of producing the detergent having a high granule strength, having excellent flowability and caking resistance, and useful for washing clothes by subjecting the particles of a specific surfactant mixture to a compact molding method or a rolling granulation method at a specific temperature. SOLUTION: This highly dense granular detergent is obtained by spraying and drying an aqueous mixture comprising (A) a non-soap anionic surfactant, (B) a polyoxyethylene higher fatty acid monoethanolamide surfactant of the formula [R is a 7-19C (un)saturated hydrocarbon group; EO is oxyethylene; (n) is an average EO addition mole number of 0.5-3], and (C) an inorganic component such as amorphous sodium silicate, and subsequently subjecting the obtained dry particles to a compact molding method and subsequently to a crushing granulation method or to a rolling granulation method at a higher temperature by >=5 deg.C than the melting point of the component B. the components A, B and C are compounded at a B/A weight ratio of 0.05-1 and at a (A+B)/C weight ratio of 0.2-1 in the aqueous mixture, and the granulation is carried out so as to give an average granule diameter of 200-1000 μm.

公开(公告)号：JPH11106800A

公开(公告)日：1999-04-20

申请号：JP31527097

申请日：1997-11-17

Applicant: KAO CORP

Inventor： TAGATA HIDEJI ,  HAGINO GENJIRO ,  KASAI KATSUHIKO ,  YANAGISAWA YUKI ,  KAMIOKA SACHIKO

IPC: C11D3/04 ,  C11D3/33 ,  C11D17/08

Abstract: PROBLEM TO BE SOLVED: To obtain a liq. detergent compsn. which is excellent in color stability even when stored for a long term by incorporating an N,N-bis(carboxymethyl) serine salt and a sulfite into the same. SOLUTION: 0.2-5 wt.% compd. of formula I (A)(wherein R is H, OH, or a 1-3C alkyl; n is 0-2; A is H, OH, or COW provided R and A are not simultaneously OH; and M is a counter ion) and 0.05-2 wt.% sulfite (B) are incorporated into a liq. detergent compsn. An N,N-bis(carboxymethyl)serine salt of formula II (wherein M is H, an alkali metal, an alkaline earth metal, ammonium. or a basic amino group), an N,N-bis(carboxymethyl)glutamate of formula III, (wherein M is the same as in formula II), and an N,N-bis(carboxymethyl) aspartate of formula IV (wherein M is the same as in formula II) are examples of ingredient A.

公开(公告)号：JPH10279996A

公开(公告)日：1998-10-20

申请号：JP8817797

申请日：1997-04-07

Applicant: KAO CORP

Inventor： TAGATA HIDEJI ,  KASAI KATSUHIKO ,  HAGINO GENJIRO ,  YANAGISAWA YUKI ,  IWAMOTO YOSHIHIRO ,  KAMIOKA SACHIKO

IPC: C11D10/02

Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition exhibiting excellent cleaning power under a low-temperature washing condition owing to the quick swelling of oily stain such as sebum by compounding a surfactant having a high permeability to fatty acid and a chelating agent having a Ca -chelate stability number of not smaller than a specific level. SOLUTION: This composition contains (A) preferably 8-50 wt.% of a surfactant having a fatty acid permeability of >=0.13 and an HLB value of >=11 and (B) preferably 10-35 wt.% of a chelating agent having a Ca -chelate stability number of >=6. The component A is preferably a nonionic surfactant of the formula I (R1 is a 7-19C straight or branched chain alkyl or alkenyl; R2 is H or a 1-3C alkyl; R, and R4 are each a 1-3C alkyl or alkenyl; (n) is 1-5), etc. The component B is e.g. a chelating agent of the formula II (M is a counter ion). The objective composition is preferably incorporated with a crystalline silicate, an aluminosilicate, etc.

公开(公告)号：JP2015059126A

公开(公告)日：2015-03-30

申请号：JP2013191474

申请日：2013-09-17

Applicant: 花王株式会社 ,  Kao Corp

Inventor： NIWANO HISASHI ,  MAKI MASATAKA ,  YANAGISAWA YUKI

IPC: C11D1/65 ,  C11D1/12 ,  C11D1/14 ,  C11D1/22 ,  C11D1/29 ,  C11D1/62

Abstract: 【課題】良好な洗浄力を有し、且つ洗浄液に含まれる菌数が多い洗浄条件下においても殺菌性に優れた衣料用洗浄剤組成物を提供する。【解決手段】(A)スルホン酸基、硫酸エステル基及びそれらの塩から選ばれる基を有するアニオン界面活性剤、並びに、(B)下記一般式(1)で表される第4級アンモニウム化合物を含有し、(A)の含有量が2質量%以上、50質量%以下であり、(A)/(B)のモル比が1以上、50以下である、衣料用洗浄剤組成物。【化1】〔式中、R1、R2及びR3は、それぞれ独立に、炭素数3以上、8以下の炭化水素基、R4は炭素数2以上、8以下の炭化水素基であり、R1、R2、R3及びR4の炭素数の合計は16以上、32以下であり、X−は陰イオンである。〕【選択図】なし

Abstract translation: 要解决的问题：提供即使在洗涤液中含有大量细菌的洗涤条件下，具有良好洗涤性和优异杀菌性的衣物用洗涤剂组合物。溶液：提供一种洗涤剂组合物，其含有（A）阴离子 具有选自磺酸基，硫酸酯基及其盐的基团的表面活性剂和（B）由通式（1）表示的季铵化合物，其含量（A）为2质量％以上且50以下 质量％以下，（A）/（B）的摩尔比为1〜50。式（1）中，R，R l R 3各自独立地为碳原子数为3〜8的烃基，R 2为具有2个 至8个碳原子，R，R，Rand Ris 16至32的碳数之和，X为阴离子。

公开(公告)号：JP2014141662A

公开(公告)日：2014-08-07

申请号：JP2013268557

申请日：2013-12-26

Applicant: Kao Corp ,  花王株式会社

Inventor： MAKI MASATAKA ,  KITA AYAKO ,  IWAMOTO YOSHIHIRO ,  YANAGISAWA YUKI

IPC: C11D3/50 ,  C11D1/04 ,  C11D1/29 ,  C11D1/72 ,  C11D3/20 ,  C11D17/08

Abstract: PROBLEM TO BE SOLVED: To provide a liquid detergent composition for clothing, which can provide the clothing with an odor of perfume more strongly even when washing time is short.SOLUTION: The provided liquid detergent composition for clothing comprises (a) a perfume compound having Log P of 3 or more but 5 or less, (b) an anionic surfactant represented by the general formula (1), (c) a carboxylic acid and/or a salt thereof having a total number of carbon atoms of 3 or more but 8 or less, and water, wherein a mass ratio of (c)/(a) is 0.1 or more but 8 or less, a total of a content of the (a) component and the (c) component is 0.5 mass% or more but 5 mass% or less, and a total of the content of the (a) component and the content of the (b) component is 3 mass% or more but 70 mass% or less. RO-[(AO)/(EO)]-SOM (1) [In the formula, R is a hydrocarbon group having 8 to 22 carbon atoms; AO is an alkyleneoxy group having 3 to 4 carbon atoms; EO is an ethyleneoxy group; p and q represent numbers of moles of average addition of 0.5 to 5 and 0 to 10, respectively; M represents a cation; and "/" means that the AO groups and the EO groups may be bonded randomly or in blocks].

Abstract translation: 要解决的问题：提供一种用于衣物的液体洗涤剂组合物，其即使在洗涤时间短的情况下也能更强烈地为衣物提供香味的气味。解决方案：所提供的用于服装的液体洗涤剂组合物包含（a）具有 对数P为3以上且5以下，（b）由通式（1）表示的阴离子表面活性剂，（c）总碳原子数为3以上的羧酸和/或其盐，但 8以下，和（c）/（a）的质量比为0.1以上且8以下的水，（a）成分和（c）成分的含量的合计为0.5质量％，或 以上且5质量％以下，（a）成分和（b）成分的含量的合计为3质量％以上且70质量％以下。 RO - [（AO）/（EO）] - SOM（1）[式中，R为碳原子数为8〜22的烃基， AO是具有3至4个碳原子的亚烷基氧基; EO是乙烯氧基; p和q分别表示平均加成摩尔数分别为0.5〜5和0〜10; M表示阳离子; 和“/”表示AO基团和EO基团可以随机或嵌段键合]。

公开(公告)号：JP2014141661A

公开(公告)日：2014-08-07

申请号：JP2013268556

申请日：2013-12-26

Applicant: Kao Corp ,  花王株式会社

Inventor： MAKI MASATAKA ,  KITA AYAKO ,  WATADA AYUMI ,  YANAGISAWA YUKI

IPC: C11D17/08 ,  C11D1/22 ,  C11D1/29 ,  C11D1/62 ,  C11D1/72 ,  D06F23/04

Abstract: PROBLEM TO BE SOLVED: To provide a liquid detergent composition for clothing, having excellent detergency against particulate stains, spot stains, and stains derived from a human body and, further, exhibiting sufficient detergency even when washing time is short.SOLUTION: The liquid detergent composition comprises (a) an alkylbenzenesulfonic acid or a salt thereof, (b) an anionic surfactant represented by the general formula (1), (c) a specific quaternary ammonium salt having a hydrocarbon group having 10 to 14 carbon atoms, (d) a specific nonionic surfactant having a hydrocarbon group having 8 or more but 18 or less carbon atoms, and water, wherein a total amount of a content of the (a) component, the content of the (b) component, and the content of the (c) component is 15 mass% or more but 70 mass% or less, a mass ratio of (c)/[(a)+(b)] is 0.02 to 0.2, and a mass ratio of (b)/(a) is 0.15 to 10. RO-[(AO)/(EO)]-SOM (1) [In the formula, R is a hydrocarbon group having 8 to 22 carbon atoms; AO is an alkyleneoxy group having 3 to 4 carbon atoms; EO is an ethyleneoxy group; p and q represent average numbers of moles of addition of 0.5 to 5 and 0 to 10, respectively; M represents a cation; and "/" means that the AO groups and the EO groups may be bound randomly or in blocks].

Abstract translation: 要解决的问题：为了提供一种用于衣服的液体洗涤剂组合物，对颗粒污渍，斑点污渍和来自人体的污渍具有优异的去污力，并且即使在洗涤时间短的情况下还显示出足够的去污力。溶液：液体洗涤剂 组合物包含（a）烷基苯磺酸或其盐，（b）由通式（1）表示的阴离子表面活性剂，（c）具有10-14个碳原子的烃基的特定季铵盐，（d） 具有8以上且18以下碳原子的烃基的特定非离子表面活性剂和水，其中（a）成分的含量的总量，（b）成分的含量和 （c）成分为（c）/ [（a）+（b）]的质量比为15质量％以上且70质量％以下，为0.02〜0.2，质量比（b）/（a ）为0.15〜10. RO - [（AO）/（EO）] -SOM（1）[式中，R为碳原子数为8〜22的烃基 女士; AO是具有3至4个碳原子的亚烷基氧基; EO是乙烯氧基; p和q分别表示平均加成摩尔数为0.5至5和0至10; M表示阳离子; 和“/”表示AO组和EO组可以随机或以块形式结合]。

公开(公告)号：JP2010189551A

公开(公告)日：2010-09-02

申请号：JP2009035429

申请日：2009-02-18

Applicant: Kao Corp ,  花王株式会社

Inventor： MIYAKE TOSHIO ,  YANAGISAWA YUKI

IPC: C11D1/72 ,  C11D1/722 ,  C11D3/43 ,  C11D17/08

Abstract: PROBLEM TO BE SOLVED: To provide a liquid detergent composition which contains a surface active agent at a high concentration, excels in detergency and storage stability, and does not deteriorate the solubility due to the gelling-formation on diluting with water.
SOLUTION: The liquid detergent composition contains (a) a specific alkoxyl-type nonionic surface active agent having a secondary alkyl group, (b) an anionic surface active agent, and (c) a water miscible organic solvent each at a specific ratio.
COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：为了提供含有高浓度的表面活性剂的液体洗涤剂组合物，洗涤力和储存稳定性优异，并且不会由于在用水稀释时的胶凝形成而使溶解性劣化。 溶液：液体洗涤剂组合物含有（a）具有仲烷基的特定烷氧基型非离子表面活性剂，（b）阴离子表面活性剂，和（c）各自在特定的 比。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2008208187A

公开(公告)日：2008-09-11

申请号：JP2007044814

申请日：2007-02-26

Applicant: Kao Corp ,  花王株式会社

Inventor： YAMADA ISAO ,  YANAGISAWA YUKI

IPC: C11D3/37 ,  C11D3/12

Abstract: PROBLEM TO BE SOLVED: To provide a detergent composition containing a specific polymer, and making reattachment of soot dirt and powder dirt difficult, in other word, preventing resoiling with dirt, and to provide a detergent composition preventing the resoiling with the dirt even when clothes, cotton towel or the like treated with a softening and finishing agent at a rinsing step. SOLUTION: The detergent composition contains a copolymer having a constituent unit derived from N-vinylpyrrolidone and a constituent unit derived from vinyl acetate, and also having 5,000-70,000 weight average molecular weight. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：为了提供含有特定聚合物的洗涤剂组合物，并且使灰尘污垢和粉末污垢难以重新附着，换句话说，防止用污垢再次吸收，并提供防止用污垢再次吸收的洗涤剂组合物 即使在漂洗步骤中用柔软整理剂处理衣物，棉毛巾等。 解决方案：洗涤剂组合物含有具有衍生自N-乙烯基吡咯烷酮的构成单元和衍生自乙酸乙烯酯的构成单元，并且还具有5,000-70,000重均分子量的共聚物。 版权所有（C）2008，JPO＆INPIT