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公开(公告)号:DE3238166A1
公开(公告)日:1983-04-28
申请号:DE3238166
申请日:1982-10-14
Applicant: OREAL
Inventor: GUILLON MICHEL , MONDET JEAN , PAPANTONIOU CHRISTOS , VANDENBOSSCHE CLAUDINE
IPC: A61K8/18 , A61K8/00 , A61K8/20 , A61K8/25 , A61K8/46 , A61K8/49 , A61K8/73 , A61K8/81 , A61K8/92 , A61Q1/00 , A61Q1/02 , A61Q1/04 , A61Q1/06 , A61Q3/00 , A61Q3/02 , A61K7/021 , A61K7/043
Abstract: A cosmetic makeup composition contains in an appropriate cosmetically acceptable vehicle or carrier a colored pigment resulting from the salification reaction of a polymer having salified primary or secondary amine functions or quaternized tertiary amine functions and an acid dye, in free acid form or as a salt thereof, the acid dye being fixed on said polymer in an amount of at least 10 weight percent of the stoichiometric quantity. The compositions include lip rouges, cheek rouges, foundation creams and nail enamels.
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公开(公告)号:DE3224808A1
公开(公告)日:1983-01-27
申请号:DE3224808
申请日:1982-07-02
Applicant: OREAL
Inventor: MAHIEU CLAUDE , PAPANTONIOU CHRISTOS
IPC: A61K8/72 , A61K8/00 , A61K8/02 , A61K8/34 , A61K8/81 , A61K8/88 , A61Q1/00 , A61Q1/10 , A61Q1/12 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/10 , A61Q17/04 , A61Q19/00 , C08G69/08 , C08G73/00 , A61K7/00 , A61K7/08 , A61K7/40 , C11D3/37 , A61K7/02 , A61K7/32 , A61K7/027 , A61K31/785 , A61K7/09 , A61K7/11 , A61K7/13
Abstract: A cosmetic composition comprises in solution in an appropriate vehicle at least one polymer having 50-100% of repeating units of the beta -alanine type having the formula (I) and 0-50% of repeating units of the acrylamide type having the formula (II) wherein R1 represents hydrogen or a member selected from the group consisting of (ii) -CH2OH, (iii) -(CH2)n-CH3 wherein n is 0 or a whole number from 1 to 11, epresent hydrogen or alkyl having 1-3 carbon atoms, (v) -CHOH-COOH, (vi) -CH2-SO3Na, wherein m ranges from 1 to 10, and R2 and R3 represent hydrogen or methyl.
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公开(公告)号:DE3115549A1
公开(公告)日:1982-06-16
申请号:DE3115549
申请日:1981-04-16
Applicant: OREAL
Inventor: GUILLON MICHEL , MONDET JEAN , PAPANTONIOU CHRISTOS , VANDENBOSSCHE CLAUDINE
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公开(公告)号:DE3112888A1
公开(公告)日:1982-02-04
申请号:DE3112888
申请日:1981-03-31
Applicant: OREAL
Inventor: GUILLON MICHEL , MONDET JEAN , PAPANTONIOU CHRISTOS , VANDENBOSSCHE CLAUDINE
Abstract: Anhydrous nail varnishes are disclosed which contain a copolymer of: (1) at least one unsaturated polar monomer of the formula: (I) in which: R1 represents H, -CH3 or -CH2COOH; such that if R1 represents H, R2 represents either (a) H, in which case R3 represents: (i) -COOH (ii) -SO3H +R1, (iii) (iv) (v) or (vi) -COOR4, R4 representing a glycidyl radical, a mono- or di-hydroxy-alkyl radical, the alkyl radical having from 2 to 4 carbon atoms, or the radical -(CH2-CH2-C)l-R', R' representing a methyl or ethyl radical and l representing 3 or 4, or (b) -COOH, in which case R3 represents: (vii) -CO2R5 or (viii) -CONHR5 R5 representing H or an alkyl radical having from 1 to 4 carbon atoms; and if R1 represents -CH3 or -CH2COOH, R2 represents H and R3 represents -COOH or -COOR4; (2) at least one methacrylate monomer of the formula: (II) in which: R6 represents a linear or branched alkyl radical having up to 18 carbon atoms, or the radical and (3) at least one acrylate monomer of the formula: CH2=CH-COOR7 (III) in which: R7 represents a linear or branched alkyl radical having up to 18 carbon atoms, or a quaternary derivative thereof.
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公开(公告)号:CH620115A5
公开(公告)日:1980-11-14
申请号:CH1302876
申请日:1976-10-14
Applicant: OREAL
Inventor: JACQUET BERNARD , MONDET JEAN , PAPANTONIOU CHRISTOS
IPC: A61K8/72 , A61K8/00 , A61K8/02 , A61K8/34 , A61K8/39 , A61K8/60 , A61K8/65 , A61K8/73 , A61K8/81 , A61K8/86 , A61K8/89 , A61K8/90 , A61K8/91 , A61Q1/00 , A61Q1/02 , A61Q1/12 , A61Q3/02 , A61Q5/02 , A61Q5/06 , A61Q5/10 , A61Q19/00 , C11D3/37 , A61K7/00
Abstract: A polymer is prepared by polymerisation of an unsaturated monomer with a compound bearing at least one OH function, this polymerisation being performed in an aqueous medium in the presence of cerium ions, and the polymer thereby obtained is incorporated in a cosmetic vehicle. These compositions may be used in various fields, and especially for hair setting products and lacquers, and for creams, gels and nail varnishes.
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公开(公告)号:CA1087989A
公开(公告)日:1980-10-21
申请号:CA278214
申请日:1977-05-12
Applicant: OREAL
Inventor: BOULOGNE JEAN , PAPANTONIOU CHRISTOS
Abstract: L'invention se rapporte à de nouveaux vernis à ongles, présentant une bonne adhésion, une bonne tenue dans le temps et une excellente brillance. Ces nouveaux vernis qui comprennent une résine, un agent plastifiant, un système de solvant et, le cas échéant, un agent filmogène, sont caractérisés par le fait que la résine est un copolymère de méthacrylate de méthyle et de méthacrylate d'hexyle.
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公开(公告)号:FR2424293A1
公开(公告)日:1979-11-23
申请号:FR7812517
申请日:1978-04-27
Applicant: OREAL
Inventor: JACQUET BERNARD , PAPANTONIOU CHRISTOS , LANG GERARD , FORESTIER SERGE
IPC: A61K8/81 , A61K8/88 , A61Q5/02 , A61Q5/06 , A61Q5/10 , A61Q5/12 , A61Q19/00 , C08G69/00 , C08G69/42 , C08G73/06 , C08G73/10
Abstract: Prodn. of polydehydroaspartic acid (I) comprises heating aspartic acid (II) in presence of high b.pt. solvent (esp. diphenyl ether) and of a strongly-acid ion-exchange resin at 200-230 degrees C and normal pressure for 2-4 hr. (I) is an intermediate for mixed amide derivs. of polyaspartic acid (see FR 2424292) which are useful as adjuvants in cosmetics. Process gives practically quantitative yields of good coloured prod. and use of diphenyl ether instead of the conventional tetralin reduces reaction time. Solid catalyst makes prod. sepn. easy and the solvent and catalyst can be recycled (up to 5 times without purifcn.).
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48.
公开(公告)号:CA1062161A
公开(公告)日:1979-09-11
申请号:CA242664
申请日:1975-12-29
Applicant: OREAL
Inventor: PAPANTONIOU CHRISTOS , GAETANI QUINTINO
Abstract: La présente invention a pour objet à titre de produit industriel nouveau une composition cosmétique capillaire en particulier pour laques et lotions de mises en plis caractérisée par le fait qu'elle contient dans un véhicule cosmétique approprié au moins un copolymère bi ou tri-séquencé comportant d'une part au moins une séquence (A) correspondant à la formule suivante : dans laquelle : Y représente une chaîne hydrocarbonée, saturée de 2 à 4 atomes de carbone ou une chaîné hydrocarbonée de 2 à 4 atomes de carbone interrompue par des hétéroatomes tels que le soufre ou l'oxygène; R1 et R2 identiques ou différents représentent un radical alcoyle de 1 à 4 atomes de carbone; n est 0 ou 1 et HX représente un acide minéral ou organique pris dans le groupe constitué par l'acide chlorhydrique, l'acide bromhydrique, l'acide lactique et l'acide acétique; et d'autre part au moins une séquence (B) résultant de la polymérisation d'un monomère polymérisable par voie anionique.
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公开(公告)号:FR2403076A1
公开(公告)日:1979-04-13
申请号:FR7727769
申请日:1977-09-14
Applicant: OREAL
Inventor: JACQUET BERNARD , PAPANTONIOU CHRISTOS , LANG GERARD , FORESTIER SERGE
Abstract: Cosmetic compsns. contain as additive a polymer(s) of formula (I): In (I) R is H or lower alkyl; b is 2-6; X is -NR3R4 or -N + R3R4R5 Z incircled negative; R3,R4,R5 are H, 1-18C alkyl or is not >18C alkenyl, or R3 and R4 together form with the N to which they are attached a 6-membered ring contg. another heteroatom, and Z incircled negative in an (in)organic anion; Y is O, -CH2-, -N incircled positive (R6)(R7)Z1 incircled negative; R6 and R7 are H, 1-18C alkyl or is not >18C alkenyl and Z1 incircled negative is an (in)organic anion; R1 is H hydroxy alkyl, hydroxyalkyloxyalkyl, 1-18C alkyl or is not >18C alkenyl; R2 is H, hydroxyalkyl or lower alkyl; M is H, alkali metal, or 1/2 alkaline earth metal atom, or M + is an ammonium derive from an amine: HN(R)-(CH2)bX, m,p,q and r are integers including o, such that m+p+q+r is 15-500; m and p cannot both be zero except when (a) q is is not = o and R1 is hydroxyalkyl; or (b) q is o. (I) is partic. used in shampoo, creams, dyeing compsns., imparting gloss, smoothness, suppleness, etc.
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公开(公告)号:CH610338A5
公开(公告)日:1979-04-12
申请号:CH747977
申请日:1977-06-17
Applicant: OREAL
Inventor: JACQUET BERNARD , PAPANTONIOU CHRISTOS , DUFAURE PIERRE , MAHIEUX CLAUDE
IPC: C07D249/20 , A61K8/00 , A61K8/34 , A61K8/81 , A61Q17/04 , C07D235/18 , C08F20/00 , C08F20/10 , C08F20/34 , C08F20/52 , C08F20/60 , C08F26/00 , C08F26/12 , C08F218/00 , C08F218/02 , C08F218/04 , A61K7/42
Abstract: Homopolymers or copolymers are prepared from acrylamide N-substituted by a radical which has one of the formulae (A) and (B) below. These polymers are incorporated into sunscreen creams and oils. They absorb not only the radiations in the "erithematous region" (between 280 and 315 nm) but also the radiations responsible for tanning (up to 350 nm), which makes it possible to obtain total protection both against sunburn and against the effect of the UV rays between 280 and 350 nm.
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