公开(公告)号：DE2634790A1

公开(公告)日：1977-07-07

申请号：DE2634790

申请日：1976-08-03

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J27/18 ,  B01J21/16 ,  B01J23/16 ,  B01J23/88 ,  B01J27/00 ,  B01J27/186 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/04 ,  C07C57/055 ,  C07C67/00

Abstract: Catalysts containing the oxides of molybdenum and phosphorus promoted with rubidium and at least one element selected from the group consisting of As, Cd, In, Sn, Tl, K, Ca, V, U, Ce, W, Ni, Zr, Ba, Fe, Rh, Mn, Re, Ru, Co, and Cu have been found to be especially desirable in the vapor phase oxidation of acrolein and methacrolein with molecular oxygen to yield acrylic acid and methacrylic acid respectively. The reaction of methacrolein gives an especially pure product in high yields and selectivities of methacrylic acid.

公开(公告)号：DE2634791A1

公开(公告)日：1977-03-03

申请号：DE2634791

申请日：1976-08-03

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J23/24 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04

公开(公告)号：CA1151136A

公开(公告)日：1983-08-02

申请号：CA364511

申请日：1980-11-12

Applicant: STANDARD OIL CO OHIO

Inventor： FARRINGTON DIANE G ,  WHITE JAMES F

IPC: B01J27/28

Abstract: The present invention relates to a method for the activation, and reactivation of PMA based catalysts by treating the catalyst precursor with a nitrogen-containing compound such as an oxide of nitrogen gas or a nitrogen acid such as nitric or nitrous at a temperature of from about 100.degree.C to about 400.degree.C. The method can be employed for activation in a reactor by loading the catalyst precursor, adjusting the reactor temperature to one suitable for activation and optionally sweeping the reactor with an inert gas followed by the treating step. The method can be employed for catalyst reactivation in the reactor by terminating the feed of reactant to the reactor, adjusting the reactor temperature as may be necessary to one suitable for reactivation and sweeping the reactor with a gas. Alternatively, the catalyst can be removed from the reactor for reactivation.

公开(公告)号：RO81263A

公开(公告)日：1983-02-15

申请号：RO9187577

申请日：1977-10-18

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  SHAW WILFRIS G ,  APPLEQUIST MICHAEL D

IPC: B01J23/28 ,  B01J23/54 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/19 ,  B01J27/198 ,  B01J27/199 ,  B01J27/24 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04

公开(公告)号：RO72506A

公开(公告)日：1980-12-30

申请号：RO9187477

申请日：1977-10-18

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  SHAW WILFRID G

IPC: C07C57/04 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  B01J23/28

Abstract: Coated catalysts having an inert support material with an outer surface and a coating of active catalyst containing molybdenum, phosphorus, arsenic, copper and oxygen have been found to be especially effective catalysts for the production of unsaturated acids from the corresponding unsaturated aldehydes, for example, methacrolein is oxidized to methacrylic acid using these catalysts. The catalysts give a very low exotherm, very high single pass yields of the desired acid and reduce the undesirable byproducts.

公开(公告)号：CS200229B2

公开(公告)日：1980-08-29

申请号：CS769578

申请日：1978-11-23

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  SHAW WILFRID G ,  APPLEQUIST MICHAEL D

IPC: B01J23/16 ,  C07C57/04

公开(公告)号：CS199275B2

公开(公告)日：1980-07-31

申请号：CS198276

申请日：1976-03-26

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R ,  GRAESSELLI ROBERT K ,  SURESH DEV DHANARAJ

IPC: B01J27/198 ,  B01J23/30 ,  B01J23/34 ,  B01J23/652 ,  B01J23/68 ,  B01J23/88 ,  B01J23/888 ,  B01J27/00 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04

公开(公告)号：CA1072072A

公开(公告)日：1980-02-19

申请号：CA258778

申请日：1976-08-10

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J27/18 ,  B01J21/16 ,  B01J23/16 ,  B01J23/88 ,  B01J27/00 ,  B01J27/186 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/04 ,  C07C57/055 ,  C07C67/00 ,  B01J23/00

Abstract: Catalysts containing the oxides of molybdenum and phosphorus promoted with rubidium and at least one element selected from the group consisting of As, Cd, In, Sn, Tl, K, Ca, V, U, Ce, W, Ni, Zr, Ba, Fe, Rh, Mn, Re, Ru, Co, and Cu have been found to be especially desirable in the vapor phase oxidation of acrolein and methacrolein with molecular oxygen to yield acrylic acid and methacrylic acid respectively. The reaction of methacrolein gives an especially pure product in high yields and selectivities of methacrylic acid.

公开(公告)号：ATA583076A

公开(公告)日：1979-12-15

申请号：AT583076

申请日：1976-08-05

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J27/18 ,  B01J21/16 ,  B01J23/16 ,  B01J23/88 ,  B01J27/00 ,  B01J27/186 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/04 ,  C07C57/055 ,  C07C67/00

Abstract: Catalysts containing the oxides of molybdenum and phosphorus promoted with rubidium and at least one element selected from the group consisting of As, Cd, In, Sn, Tl, K, Ca, V, U, Ce, W, Ni, Zr, Ba, Fe, Rh, Mn, Re, Ru, Co, and Cu have been found to be especially desirable in the vapor phase oxidation of acrolein and methacrolein with molecular oxygen to yield acrylic acid and methacrylic acid respectively. The reaction of methacrolein gives an especially pure product in high yields and selectivities of methacrylic acid.

公开(公告)号：CA1065340A

公开(公告)日：1979-10-30

申请号：CA246949

申请日：1976-03-02

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R ,  GRASSELLI ROBERT K ,  SURESH DEV D

IPC: B01J27/198 ,  B01J23/30 ,  B01J23/34 ,  B01J23/652 ,  B01J23/68 ,  B01J23/88 ,  B01J23/888 ,  B01J27/00 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04

Abstract: PROCESS FOR THE PREPARATION OF ACRYLIC ACID AND METHACRYLIC ACID FROM THE CORRESPONDING ALDEHYDES Catalysts containing tungsten, phosphorus, vanadium and molybdenum have been round to be especially effective for the oxidation of unsaturated aldehydes to form the corresponding unsaturated acid. These catalysts may optionally contain one or more of tin, antimony, arsenic, copper, cerium, boron, chromium, iron, nickel, cobalt, uranium, manganese, strontium, silver, rubidium, rhodium, cadmium, bismuth, indium, zinc, lanthanum.