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公开(公告)号：JPH10286438A
公开(公告)日：1998-10-27
申请号：JP9715197
申请日：1997-04-15
Applicant: UBE INDUSTRIES
Inventor： ATOKUCHI TAKASHI , YADA HIROHIDE , SUGIMOTO TSUNEMI , MATSUZAKI TOKUO
IPC: A62D3/00 , B01D53/86 , B01J27/053 , B01J27/16
Abstract: PROBLEM TO BE SOLVED: To enable continuous decomposition of a fluorine-contg. compd., especially a perfluorocompd. by bringing a gaseous fluorine-contg. compd. into contact with molecular oxygen and water in the presence of a catalyst prepared by depositing inorg. acid on a carrier. SOLUTION: When a gaseous fluorine-contg. compd. (such as perfluoro compds. and fluorinated hydrocarbons) is to be decomposed, the fluorine-contg. compd. is brought into contact with molecular oxygen and water in the presence of a catalyst which is prepared by depositing an inorg. acid on a carrier. As for the inorg. acid, sulfuric acid, phosphoric acid, and as for the carrier, for example, a alumina such as γ-alumina are preferably used. The shape of the alumina is not limited and properly selected according to the reactor and the reaction method. The inorg. acid is deposited on the carrier, for example, by 0.01 to 20 wt.% of the carrier, and especially preferably 0.1 to 10 wt.%. As for the molecular oxygen, a gas prepared by diluting oxygen gas with inert gas such as nitrogen can be used, however, air is preferably used.
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公开(公告)号：JPH1087611A
公开(公告)日：1998-04-07
申请号：JP24191196
申请日：1996-09-12
Applicant: UBE INDUSTRIES
Inventor： TATSUMI TAKASHI , TAI RENKIN , MATSUZAKI TOKUO , SUGIMOTO TSUNEMI , FUKUSHIMA HIROYUKI
IPC: C07D201/04 , B01J29/08 , B01J29/18 , B01J29/40 , C07B61/00
Abstract: PROBLEM TO BE SOLVED: To produce ε-caprolactam useful as a material for nylon at a high conversion rate and with high selectivity by a catalytic gas-phase conversion of cyclohexanone oxime in the presence of a specific alcohol by the use of a specific zeolite as a catalyst. SOLUTION: This ε-caprolactam is produced easily using an inexpensive catalyst without decrease in the conversion rate by a catalytic gas-phase conversion of cyclohexanone oxime by the use of ZSM-5 type zeolite having an atomic Si/Al ratio smaller than 100, preferably ZSM-5 type zeolite having an atomic Si/Al ratio of 1-50, as a catalyst, in the presence of a 7C or higher aliphatic alcohol, preferably 1-heptanol, 1-octanol, 1-nonanol, etc., specifically 1-octanol. As a catalyst, mordenite type and Y type of zeolite whose Si/Al ratio is 50 or less, preferably 1-30, may be used.
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公开(公告)号：JPH09295959A
公开(公告)日：1997-11-18
申请号：JP11137296
申请日：1996-05-02
Applicant: UBE INDUSTRIES
Inventor： YAMAMOTO YOSHIFUMI , SUGIMOTO TSUNEMI , KURATO TOSHIO
Abstract: PROBLEM TO BE SOLVED: To safely obtain a diaryl carbonate useful as a raw material for polycarbonate from a diaryl oxalate in high reaction rate and selectivity without using highly toxic phosgene. SOLUTION: A diaryl carbonate of formula II is produced by the decarbonylation reaction of a diaryl oxalate of formula I by heating the diaryl oxalate in vapor phase in the presence of an alkaline earth metal oxide while adding an aromatic hydroxy compound to the reaction system. The aromatic hydroxy compound is preferably added in an amount of 0.1-50mol based on 1mol of the diaryl oxalate. The diaryl oxalate is especially preferably diphenyl oxalate and the aromatic hydroxy compound is especially preferably phenol. The alkaline earth metal oxide is e.g. magnesium oxide or calcium oxide.
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公开(公告)号：JPH08283205A
公开(公告)日：1996-10-29
申请号：JP8214695
申请日：1995-04-07
Applicant: UBE INDUSTRIES
Inventor： YAMAMOTO YOSHIFUMI , SUGIMOTO TSUNEMI , ODAN KYOJI
Abstract: PURPOSE: To obtain a carbonate useful as a raw material for polycarbonates, without chlorine loss, in high conversion and selectivity in an industrially advantageous way, in such a manner as to facilitate catalyst separation, by reaction between a chloroformic ester and an organic hydroxy compound in the presence of a specific catalyst. CONSTITUTION: This carbonate is obtained by reaction between (B) a chloroformic ester and (C) an organic hydroxy compound such as a compound of formula I [A is a single bond, O, S, a group of formula II (R and R are each a 1-8C alkyl, 5-8C chcloalkyl or 7-8C aralkyl), group of formula III (R -R are each the same as R ), etc.] in the presence of (A) a catalyst, i.e., a metal element belonging to platinum metals or primary transition metal group or its compound (for example, prepared by the following method: a palladium tetramine complex, acetylacetonato complex or high-valence phosphine complex, or tetrachloropalladium acid salt is reduced by hydrogen into the corresponding metal, which is then carried on a carrier such as alumina, silica or active carbon).
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公开(公告)号：JPH0280306A
公开(公告)日：1990-03-20
申请号：JP9300889
申请日：1989-04-14
Applicant: UBE INDUSTRIES
Inventor： SUGIMOTO TSUNEMI , FUJII KAZUHIRO , DAIMON HIROSHI
IPC: H01L39/24 , C01B13/22 , C01G1/00 , C23C16/30 , C30B25/02 , C30B29/22 , H01B12/00 , H01B13/00 , H01F6/06
Abstract: PURPOSE:To obtain a superconducting thin film having improved forming velocity and superior characteristics by irradiating a metal complex of a specified org. compd. contg. an F-contg. lower alkyl group with light having a specified wavelength, and forming a crystalline thin film basing on an organometallic vapor growth process. CONSTITUTION:An aimed thin film is obtd. by irradiating a metal complex of an org. compd. expressed by the formula (wherein R is a 1-4C F-contg. lower alkyl group) with light having 150-600nm wavelength in a stage for prepg. a crystalline oxide high temp. superconducting thin film basing on an organometallic vapor growth process. The decomposition of the organometal complex as the starting material on a base plate is prompted by the irradiation with the light and a crystalline thin film having satisfactory crystalline property can be formed. The thin film can be also formed by maintaining the temp. of the base plate at a relatively low temp. as low as
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Patent Agency Ranking
公开(公告)号：JPH0280305A
公开(公告)日：1990-03-20
申请号：JP9300789
申请日：1989-04-14
Applicant: UBE INDUSTRIES
Inventor： SUGIMOTO TSUNEMI , IGAI SHIGERU
IPC: H01L39/24 , C01B13/14 , C01G1/00 , C04B35/00 , C04B35/45 , C23C16/40 , C30B25/02 , C30B29/22 , H01B12/06 , H01B13/00
Abstract: PURPOSE:To obtain a high temp. superconducting thin film having satisfactory crystalline property by prepg. the crystalline thin film basing on an organometallic vapor growth process while supplying ozone as at least a part of oxidizing gas. CONSTITUTION:A crystalline thin film of an oxide high temp. superconducting material is prepd. by supplying ozone as at least a part of oxidizing gas in a stage of prepg. the crystalline oxide high temp. superconducting thin film basing on an organometallic vapor growth process. It is desirable to irradiate a base plate with light having 150-600nm wavelength in order to prepare a thin film having satisfactory crystalline property on a base plate at a relatively low temp. Examples for the crystalline oxide high temp. superconducting thin film prepd. by the organometallic vapor growth are those comprising Bi-alkaline earth element-Cu-O type superconducting ceramic, or rare earth element-alkaline earth element Cu-O type superconducting ceramic, etc.
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公开(公告)号：JP2013014535A
公开(公告)日：2013-01-24
申请号：JP2011147917
申请日：2011-07-04
Applicant: Yamaguchi Univ , 国立大学法人山口大学 , Ube Industries Ltd , 宇部興産株式会社
Inventor： YAMAMOTO TOSHIKI , SUGIMOTO TSUNEMI
IPC: C07C45/33 , C07B61/00 , C07C49/303
Abstract: PROBLEM TO BE SOLVED: To provide a method of producing cyclohexanone, by which the cyclohexanone can be manufactured with high efficiency and good selectivity when cyclohexane is oxidized by using a cobalt catalyst.SOLUTION: The method of producing the cyclohexanone includes: bringing the cyclohexane into contact with oxygen or an oxygen-containing gas; and oxidizing a cobalt compound as a catalyst. The oxidation is conducted without a solvent.
Abstract translation: 待解决的问题：提供一种环己酮的制备方法，当环己烷通过使用钴催化剂氧化时，可以高效率和高选择性制备环己酮。 解决方案：制备环己酮的方法包括：使环己烷与氧或含氧气体接触; 氧化作为催化剂的钴化合物。 无溶剂进行氧化。 版权所有（C）2013，JPO＆INPIT
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公开(公告)号：JP2011173814A
公开(公告)日：2011-09-08
申请号：JP2010037662
申请日：2010-02-23
Applicant: Ube Industries Ltd , Yamaguchi Univ , 国立大学法人山口大学 , 宇部興産株式会社
Inventor： YAMAMOTO TOSHIKI , HORI KENJI , SUMIMOTO MICHINORI , SUGIMOTO TSUNEMI
IPC: C07D201/04 , C07B61/00 , C07D223/10
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an amide compound, which suppresses formation of a by-product and produces an amide compound in a high yield. SOLUTION: In the method for producing an amide compound by a Beckmann rearrangement reaction of an oxime compound, the Beckmann rearrangement reaction is carried out in the presence of a first catalyst of at least one or more of an acidic chloride, an acid anhydride and a Lewis acid and a second catalyst (except a compound specifically selected in the first catalyst) composed of a compound that has an interaction with the nitrogen atom of the oxime compound. COPYRIGHT: (C)2011,JPO&INPIT
Abstract translation: 待解决的问题：提供抑制副产物形成并以高产率产生酰胺化合物的酰胺化合物的制备方法。 解决方案：在通过肟化合物的贝克曼重排反应制备酰胺化合物的方法中，贝克曼重排反应在酸性氯化物，酸的至少一种或多种的第一催化剂的存在下进行 酸酐和路易斯酸以及由与肟化合物的氮原子相互作用的化合物构成的第二催化剂（除了在第一催化剂中特别选择的化合物）。 版权所有（C）2011，JPO＆INPIT
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公开(公告)号：JPH10286465A
公开(公告)日：1998-10-27
申请号：JP9714897
申请日：1997-04-15
Applicant: UBE INDUSTRIES
Inventor： MATSUZAKI TOKUO , SUGIMOTO TSUNEMI , NAKAMURA YASUO , MANABE TAKUMI
IPC: B01J27/186 , C07B61/00 , C07C41/09 , C07C43/23
Abstract: PROBLEM TO BE SOLVED: To provide a new catalyst for dehydration reaction that is further improved in activity and the at a high level in mechanical strength in a vapor dehydration reaction such as vapor phase etherification and vapor phase esterification, and to provide a method capable of producing 2-valent phenol monoalkyl ether at a high conversion and high selectivity in the vapor phase dehydration reaction of 2-valent phenol and lower alcohol. SOLUTION: The catalyst for dehydration reaction consists of aluminum, phosphorus, titanium, silicon, antimony of bismuth and oxygen having the atomic ratios of phosphorus of 1.0-1.9 atoms, titanium of 0.05-0.5 atoms, silicon of 0.05-0.2 atoms, antimony or bismuth of 0.01-0.3 atoms and oxygen of 4.2-8.4 atoms per aluminum of 1 atomic ratio and 2-valent phenol and lower alcohol are dehydrated in a gas phase and in the presence of the catalyst.
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公开(公告)号：JPH1087612A
公开(公告)日：1998-04-07
申请号：JP24191296
申请日：1996-09-12
Applicant: UBE INDUSTRIES
Inventor： TATSUMI TAKASHI , TAI RENKIN , MATSUZAKI TOKUO , SUGIMOTO TSUNEMI , FUKUSHIMA HIROYUKI
IPC: C07D201/04 , B01J29/50 , B01J29/60 , C07B61/00
Abstract: PROBLEM TO BE SOLVED: To produce ε-caprolactam useful as a material for nylon at a high conversion rate and with high selectivity by a catalytic gas-phase conversion of cyclohexanone oxime in the presence of an aliphatic alcohol by the use of a specific zeolite as a catalyst. SOLUTION: This ε-caprolactam is produced without decrease in the conversion rate by a catalytic gas-phase conversion of cyclohexanone oxime by the use of L-type zeolite having an atomic Si/Al ratio smaller than 5, preferably an atomic Si/Al ratio of 0.1 or more and less than 5, as a catalyst, in the presence of an aliphatic alcohol, for example, 1-butanol, 1-pentanol, 1-hexanol, 1- heptanol, etc. This type of catalyst can be easily produced at a low cost, and has no structural problem.
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