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    NOVEL NITROGEN-CONTAINING PERFLUOROALKYL IODIDE AND ITS PRODUCTION
    52.
    发明专利
    NOVEL NITROGEN-CONTAINING PERFLUOROALKYL IODIDE AND ITS PRODUCTION 失效

    公开(公告)号：JPH02262539A

    公开(公告)日：1990-10-25

    申请号：JP8272789

    申请日：1989-03-31

    Applicant: AGENCY IND SCIENCE TECHN

    Inventor： ABE TAKASHI ,  HAYASHI EIJI ,  FUKAYA HARUHIKO

    IPC: C07D223/04 ,  C07C209/74 ,  C07C211/15 ,  C07D207/10 ,  C07D211/38 ,  C07D265/30

    Abstract: NEW MATERIAL:A cyclic nitrogen-containing perfluoroalkyl iodide expressed by formula I (X is O or methylene; (m) is 0 is 1; (n) is 1 to 3). EXAMPLE:Perfluoro[1-(pyrrolidino)ethyl iodide]. USE:Useful as a synthetic raw material for fluorine-containing products, such as surfactants, agricultural chemicals or medicaments. Furthermore, the exemplified compound in the above-mentioned compounds has the ultraviolet absorption maximum shifted to the side of longer wave lengths and can be utilized as iodine optical dissociation laser (solar pumped laser). PREPARATION:A compound expressed by formula II (R f and R f are 1 to 5C perfluoroalkyl group and both may directly link, through O or N or, together with N to which both are bonded, form a heterocyclic ring; (n) is 1 to 3) is reacted with lithium iodide at 150 to 400 deg.C to afford a novel compound expressed by formula III.

    PRODUCTION OF IODINE-CONTAINING PERFLUORO COMPOUND
    53.
    发明专利
    PRODUCTION OF IODINE-CONTAINING PERFLUORO COMPOUND 失效

    公开(公告)号：JPH02262529A

    公开(公告)日：1990-10-25

    申请号：JP8272689

    申请日：1989-03-31

    Applicant: AGENCY IND SCIENCE TECHN

    Inventor： ABE TAKASHI ,  HAYASHI EIJI ,  FUKAYA HARUHIKO

    IPC: C07C41/22 ,  C07B39/00 ,  C07C19/08 ,  C07C19/16 ,  C07C43/12 ,  C07C51/58 ,  C07C53/50 ,  C07C17/33

    Abstract: PURPOSE:To economically obtain the subject substance useful as a synthetic intermediate, etc., for surfactants, agricultural chemicals, medicaments, etc., from readily available raw materials in high yield by thermally reacting a perfluorocarboxylic acid fluoride with LiI. CONSTITUTION:A compound expressed by formula I (Rf is perfluorohydrocarbon group; (n) is 1-3) is reacted with LiI at 150 to 400 deg.C (preferably 180 to 230 deg.C) to afford a compound expressed by formula II ((m) is 1 to 3 and (n)>=(m)). The LiI is preferably anhydrous and the amount thereof used is selected from the range of 1.2 to 1.5mol if the compound expressed by formula I is a monobasic acid, 2.5 to 3.0mol in the case of a dibasic acid and 3.5 to 4.0mol in the case of a tribasic acid. In the case of the dibasic and tribasic acids, only a part of the fluorocarbonyl groups can be substituted with I by selecting the molar ratio to the LiI.

    PRODUCTION OF PERFLUORO(3-DIALKYLAMINOPROPIONIC ACID FLUORIDE)
    54.
    发明专利
    PRODUCTION OF PERFLUORO(3-DIALKYLAMINOPROPIONIC ACID FLUORIDE) 失效

    公开(公告)号：JPH01259188A

    公开(公告)日：1989-10-16

    申请号：JP8783488

    申请日：1988-04-08

    Applicant: AGENCY IND SCIENCE TECHN

    Inventor： ABE TAKASHI ,  HAYASHI EIJI

    IPC: C25B3/08

    Abstract: PURPOSE:To simply produce perfluoro(3-dialkylaminopropionic acid fluoride) in a high yield by electrolyzing 3-dialkylaminopropionic ester in liq. hydrogen fluoride. CONSTITUTION:3-Dialkylaminopropionic ester represented by general formula I (where each of R1 and R2 is alkyl, R1 and R2 may be different from each other and R is alkyl) is electrolyzed in liq. hydrogen fluoride. The alkyl groups of the compd. are converted into perfluoroalkyl groups and perfluoro(3- dialkylaminopropionic acid fluoride) represented by formula II (where each or R'1 and R'2 is perfluoroalkyl and R'1 and R'2 may be different from each other) is obtd. This product is useful as an intermediate for synthesizing a fluorine-contg. product such as a surfactant, agricultural chemicals or pharmaceuticals or as a monomer for a fluorine-contg. high molecular compd.

    NOVEL NITROGEN-CONTAINING PERFLUOROPROPENES AND PRODUCTION THEREOF
    55.
    发明专利
    NOVEL NITROGEN-CONTAINING PERFLUOROPROPENES AND PRODUCTION THEREOF 失效

    公开(公告)号：JPS6470443A

    公开(公告)日：1989-03-15

    申请号：JP22746987

    申请日：1987-09-10

    Applicant: AGENCY IND SCIENCE TECHN

    Inventor： ABE TAKASHI

    IPC: C07D211/38 ,  C07C67/00 ,  C07C209/00 ,  C07C209/68 ,  C07C211/24 ,  C07D207/10 ,  C07D223/04 ,  C07D241/16 ,  C07D265/30 ,  C08F26/02

    Abstract: NEW MATERIAL:The compound of formula I (R1 and R2 are 1-5C perfluoroalkyl or together with N form a 5-7-membered heterocyclic group). EXAMPLE:Perfluoro(2-dimethylaminopropene). USE:A synthetic intermediate for a florine-containing product such as surfactants, agricultural chemicals and pharmaceuticals, a monomer for polymer, etc. PREPARATION:The compound of formula I can be produced by heating a perfluoro-(3-dialkylamino-n-butyric acid) derivative of formula II [X is F or OM (M is alkali metal or alkaline-earth metal corresponding to one valent)] at 100-500 deg.C, preferably 200-300 deg.C. The objective compound can be produced from an easily available raw material with an extremely simple process in high yield.

    PERFLUORO(N-VINYLHEXAMETHYLENIMINE) AND ITS PREPARATION
    56.
    发明专利
    PERFLUORO(N-VINYLHEXAMETHYLENIMINE) AND ITS PREPARATION 失效

    公开(公告)号：JPS6322564A

    公开(公告)日：1988-01-30

    申请号：JP16688986

    申请日：1986-07-15

    Applicant: AGENCY IND SCIENCE TECHN

    Inventor： ABE TAKASHI

    IPC: C07D223/04 ,  C08F26/00 ,  C08F26/06

    Abstract: NEW MATERIAL:Perfluoro(N-vinylhexamethylenimine) of formula I. USE:A synthetic intermediate of surfactants, agricultural chemicals or medicines containing fluorine. A monomer for polymers. PREPARATION:A perfluoro-compound of formula II [R is F, OM (M is monovalent ion of alkali or alkaline earth metal), formula IV] is heated at a temperature ranging from 100 to 500 deg.C to give perfluoro(N-vinylhexamethylenimine) of formula I.

    FLUORINE-CONTAINING OLIGOMER TYPE SURFACE-ACTIVE COMPOUND AND ITS PRODUCTION
    58.
    发明专利
    FLUORINE-CONTAINING OLIGOMER TYPE SURFACE-ACTIVE COMPOUND AND ITS PRODUCTION 失效

    公开(公告)号：JP2000072735A

    公开(公告)日：2000-03-07

    申请号：JP24356898

    申请日：1998-08-28

    Applicant: AGENCY IND SCIENCE TECHN ,  TOHKEM PRODUCTS KK

    Inventor： HAYASHI EIJI ,  ABE TAKASHI ,  WATANABE MASAO ,  SATO YUKIO ,  OMORI KOTA

    IPC: C07D265/30 ,  B01F17/00 ,  C07C231/02 ,  C07C237/10 ,  C07D207/10 ,  C08G73/04 ,  C11D1/52

    Abstract: PROBLEM TO BE SOLVED: To produce the subject compound having high surface activity and good solubility and useful as a surfactant by composing the compound of an ethyleneimine-based oligomer (salt) having specific two kinds of recurring units. SOLUTION: This compound is produced by composing the compound of an ethyleneimine-based oligomer (salt) having (A) a recurring unit represented by formula I [Rf1 and Rf2 are each a 1-5C perfluoroalkyl and may be directly connected or connected through O or N to form a heterocyclic ring with N to which Rf1 and Rf2 are bound; (n) is 1 or 2] and (B) a recurring unit represented by formula II in preferably (0.1:99.9) to (10:90), more preferably (0.5:99.5) to (5:95) molar ratio of the components A to B and having preferably 100-3,000, more preferably 200-2,000 degree of polymerization. The compound is produced by reacting, e.g. a nitrogen-containing perfluorocarboxylic acid halide represented by formula III (X is a halogen) with a polyethyleneimine and then, as necessary, reacting an acid therewith.

    EXTINGUISHING OF FIRE
    59.
    发明专利
    EXTINGUISHING OF FIRE 失效

    公开(公告)号：JP2000070400A

    公开(公告)日：2000-03-07

    申请号：JP24387098

    申请日：1998-08-28

    Applicant: AGENCY IND SCIENCE TECHN ,  RES INST INNOVATIVE TECH EARTH

    Inventor： INOMATA TADAAKI ,  ABE TAKASHI ,  AKIYAMA MINORU ,  TAKUBO SEIJI ,  SEKIYA AKIRA

    IPC: A62D1/06

    Abstract: PROBLEM TO BE SOLVED: To produce an extinguishing chemical by using easily available materials, eliminate possibility of disrupting the ozonosphere, and safely use it, by using a hydropolyfluoro tertiary amine represented by a specific formula as a main component of gas-system extinguishing chemical. SOLUTION: When fire is effectively extinguished by using a hydropolyfluoro tertiary amine that is gaseous at room temperature, as the alternative of gas- system halon fire extinguishing chemical, the hydropolyfluoro tertiary amine represented by the formula (CF3)2NCH2CHmF3-m ((m) is an integer of 0-3) is used as a main component of the gas-system extinguishing chemical. As the hydropolyfluoro tertiary amine represented by the formula, preferably, bis(trifluoromethyl)-2-fluoroethylamine[(CF3)2NCH2CH2F] or bis (trifluoromethyl) ethylamine[(CF3)2NCH2CH3] is cited.

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