公开(公告)号：JPS62243609A

公开(公告)日：1987-10-24

申请号：JP8755086

申请日：1986-04-16

Applicant: AGENCY IND SCIENCE TECHN

Inventor： ITO SHOJI ,  MIZOGUCHI KENSAKU ,  SUDA MASAO

IPC: C08F20/56 ,  C08F20/52 ,  C08F120/56

Abstract: PURPOSE:To produce the titled polymer having thermal reversibility to become hydrophobic at high temperature and reversibly convertible between a water-soluble state at low temperature and water-insoluble state at high temperature, in high efficiency, by the radical polymerization of N-methyl-N-n- propylacrylamide. CONSTITUTION:The objective polymer of formula II is produced by the radical polymerization of N-methyl-N-n-propylacrylamide of formula I usually in the form of a 1-80wt% solution under radiation of actinic ray, heating in the presence of radical polymerization initiator or radiation of light in the presence of a photo-sensitizer, etc. USE:Light-shielding material for greenhouse or chemical laboratory, etc., temperature sensor, toys, interior goods, mechanochemical element material, etc.

公开(公告)号：JPS62242655A

公开(公告)日：1987-10-23

申请号：JP8755286

申请日：1986-04-16

Applicant: AGENCY IND SCIENCE TECHN

Inventor： ITO SHOJI ,  MIZOGUCHI KENSAKU ,  SUDA MASAO

IPC: C08F20/56 ,  C07C233/09 ,  C08F20/00 ,  C08F20/52

Abstract: NEW MATERIAL:N-Methyl-N-n-propylacrylamide shown by the formula. USE:Useful as a raw material monomer for hydrophilic-hydrophobic heat reversible high polymer compound usable for glare protecting material, temperature sensor, adsorbent, toy, interior, printing agent, display, separating membrane, mechano-chemical element material, etc. PREPARATION:Acrylic acid chloride is reacted with methyl-n-propylamine and triethylamine in a solvent such as benzene at 0-10 deg.C to give a vinyl compound shown by the formula.

公开(公告)号：JPS62129107A

公开(公告)日：1987-06-11

申请号：JP26995385

申请日：1985-11-29

Applicant: AGENCY IND SCIENCE TECHN

Inventor： HIROTSU TOSHIHIRO ,  ICHIMURA KUNIHIRO ,  MIZOGUCHI KENSAKU ,  NAKAMURA EIICHIRO

IPC: B01D61/36 ,  B01D67/00 ,  B01D69/12 ,  B01D71/38

Abstract: PURPOSE:To prepare a water selective and permeable separating membrane having such practical performances as superb separability, mechanical strength of membrane, etc. by utilizing photo-crosslinked photosensitive polyvinyl alcohol derivative to apply the porous high-molecular membrane. CONSTITUTION:The water solution of water soluble photosensitive resin such as polyvinyl alcohol or partial saponifiable vinyl acetate, etc. shown in the formula is applied on the porous high-molecular membrane such as cellulose acetate porous membrane, exposed to the interior light and the like after air-drying, sensitized and crosslinked with water soluble photosensitive resin to render the said membrane insoluble. By utilizing the composite membrane thus prepared, pervaporation is carried out to separate the water-ethanol mixing solution and the like.

公开(公告)号：JPS61225160A

公开(公告)日：1986-10-06

申请号：JP6461685

申请日：1985-03-28

Applicant: AGENCY IND SCIENCE TECHN

Inventor： FURUYA SETSUKO ,  MIZOGUCHI KENSAKU

IPC: C08F12/00 ,  C07C67/00 ,  C07C301/00 ,  C07C303/38 ,  C07C311/21 ,  C08F12/30 ,  C09K3/00

Abstract: NEW MATERIAL:2-(4'-Styrenesulfonylamino)aniline expressed by the formula. USE:A raw material for producing a polymer useful as a metal-trapping agent. PREPARATION:o-Phenylenediamine is reacted with a 4-styrenesulfonyl halide in a basic solvent (example; pyridine or trimethylamine) under cooling at

公开(公告)号：JPS61225157A

公开(公告)日：1986-10-06

申请号：JP6773485

申请日：1985-03-29

Applicant: AGENCY IND SCIENCE TECHN

Inventor： ITO SHOJI ,  MIZOGUCHI KENSAKU ,  SUDA MASAO

IPC: C08F20/00 ,  C07C233/20 ,  C08F20/52 ,  C08F20/58

Abstract: NEW MATERIAL:A compound expressed by formula I (R1 represents H or methyl; R2 represents lower alkyl). EXAMPLE:N-Methoxypropylacrylamide. USE:Useful as a raw material monomer for hydrophilic-hydrophobic thermoreversible high polymers. PREPARATION:For example, acryloyl chloride or methacryloyl chloride expressed by formula II is reacted with a 3-alkoxypropylamine expressed by formula III and triethylamine expressed by formula IV in a solvent preferably at 0-10 deg.C to obtain the compound expressed by formula I. A polymer prepared from the compound expressed by formula I is a thermoreversible derivative, which dissolves in water at low temperatures, reversibly becomes insoluble in water at high temperatures and is useable for a light shield, thermosensor, adsorbent, toy, etc.