Pure 1-aminoanthraquinone prepn - from catalytic hydrogenation of 1-nitroanthraquinone

    公开(公告)号:DE2200071A1

    公开(公告)日:1973-07-19

    申请号:DE2200071

    申请日:1972-01-03

    Applicant: BASF AG

    Abstract: Title cpd is produced from a nitroanthraquinone mixt. contg. >=50 pref. 65-85 wt.% of 1-nitroanthraquinone. The mixt. is in soln in a solvent such as a N,N-dialkylamine carboxylic acid N methylpyrrolidone or their mixts in which is suspended a noble metal or Raney Ni which act as the catalyst. After removal of the catalyst, the reaction mixt. is oxidised, pref. using air, and 1-aminoanthraquinone is precipitated out using a diluting agent, pref. water, in sufficient quantities to obtain an amt equiv. to 40-65% of the nitroanthraquinone. The amt. of solvent in the original mixts is 5-20 times. the nitroanthraquinone mixt. Pure products suitable for use in production of dyestuffs are obtd. without sulphonating anthraquinone in the presence of Hg.

    Anthraquinone dyes for synthetic polyamides - and polyesters

    公开(公告)号:DE1949295A1

    公开(公告)日:1971-04-01

    申请号:DE1949295

    申请日:1969-09-30

    Applicant: BASF AG

    Abstract: Anthraquinone dyes containing 1,2,4-oxdiazol groups especially blue dye of formula (where X is (1-3C alkyl) amino, Y is H, Hal, NH3, 1-6C alkylamino or alkylmercapto in which the alkyl is opt. substd. by Hal, OH or alkoxy, phenyl amino or phenyl-mercapto, the phenyl opt. substd. by Hal, Me Et or MeO and R1 is aliphatic hydrocarbon residue containing aromatic ether group or aliphatic thioether-, sulphone-or polyether group) are suitable as dispersion dyes for dyeing polyester and polyamide textiles, and can also be used as pigment dyestuffs for bulk dyeing of thermoplastic materials and for spinning dyeing of polyester and polyamides.

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