51.
    发明专利
    未知

    公开(公告)号:ES2146082T3

    公开(公告)日:2000-07-16

    申请号:ES97904422

    申请日:1997-02-12

    Applicant: BASF AG

    Abstract: A process for the preparation of aldehydes or aldehydes and alcohols by hydroformylation of olefins containing more than 3 carbon atoms, comprising a hydroformylation stage, in which the olefin is hydroformylated under a pressure of form 50 to 1000 bar and at a temperature of from 50° to 180° C. by means of a rhodium catalyst dissolved in a homogenous reaction medium and a catalyst recovery stage comprising extraction of the rhodium catalyst with an aqueous solution of chelating agent, isolation of alcohols and/or aldehyde from the extracted hydroformylation product steam, precarbonylation of the aqueous rhodium-containing extract in the presence of carbon monoxide, synthesis gas as, or a gas mixture containing carbon monoxide under a pressure of from 50 to 1000 bar and at a temperature of from 50° to 180° C., separation of the effluent of the precarbonylation stage into an organic phase containing the major portion of the rhodium and an aqueous phase containing the chelating agent and recycling of the organic phase to the hydroformylation stage, where the rhodium catalyst is extracted from the effluent of the hydroformylation stage using an aqueous solution of a sulfonic acid group-free, water-soluble polymer capable of chelating rhodium.

    53.
    发明专利
    未知

    公开(公告)号:BR9711485A

    公开(公告)日:1999-08-24

    申请号:BR9711485

    申请日:1997-08-29

    Applicant: BASF AG

    Abstract: In a process for producing n-butylalkyl ethers, (a) 1,3-butadiene or a butadiene-containing hydrocarbon mixture is reacted with an alcohol of formula ROH (I), in which the radical R is a C2-C20 alkyl or alkenyl group substituted or not with 1 to 2 C1-C10 alkoxy or hydroxy groups, a C6-C10 aryl or C7-C11 aralkyl group or a methyl group, at an increased temperature and pressure in the presence of a Brönsted acid or in the presence of a complex of an element of groups Ib, VIIb or VIIIb of the periodic table of elements with a phosphorus- or nitrogen-containing ligand, yielding a mixture of addition products of formulas (II) and (III); (b) the isomers are separated; (c) addition product III is isomerised into addition product II; (d) addition product II is hydrogenated in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous, transition metal element-containing catalyst in the gas phase, yielding n-butylalkyl ether of formula (IV).

    PROCESS FOR PREPARING 6-AMINOCAPROIC ACID NITRILE

    公开(公告)号:CZ36199A3

    公开(公告)日:1999-04-14

    申请号:CZ36199

    申请日:1997-07-23

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/03987 Sec. 371 Date Feb. 1, 1999 Sec. 102(e) Date Feb. 1, 1999 PCT Filed Jul. 23, 1997 PCT Pub. No. WO98/05631 PCT Pub. Date Feb. 12, 1998The invention concerns a process for the preparation of 6-aminocapronitrile or 6-aminocapronitrile-hexamethylene diamine mixtures by: a) reacting 5-formylvaleronitrile with ammonia and hydrogen in the presence of hydrogenation catalysts selected from the group consisting of metals or metal compounds rhenium, copper and elements of group VIII of the periodic table of elements, a hydrogenation discharge product being obtained; and b) extracting from the hydrogenation discharge product 6-aminocapronitrile and optionally hexamethylene diamine, provided that the hydrogenation catalyst does not contain copper, nickel or copper and nickel as it's only components.

    56.
    发明专利
    未知

    公开(公告)号:ID17978A

    公开(公告)日:1998-02-12

    申请号:ID972699

    申请日:1997-08-04

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/03988 Sec. 371 Date Feb. 1, 1999 Sec. 102(e) Date Feb. 1, 1999 PCT Filed Jul. 23, 1997 PCT Pub. No. WO98/05632 PCT Pub. Date Feb. 12, 1998Manufacture of 6-aminocapronitrile or 6-aminocapronitrile/hexamethylene diamine mixtures, involving a) the reaction of at least one pentennitrile, selected from the group consisting of 2,3 and 4-pentennitrile with carbon monoxide and hydrogen in the presence of catalysts, which contain at least one element of the eighth subgroup as active components, obtaining a hydrogenation formylating discharge (I), b) the optional separation of carbon monoxide, hydrogen and the catalyst from the hydrogenation formylating discharge (I), obtaining a hydrogenation formylating discharge (II), c) the separation of 5-formyl valeronitrile from the hydrogenation formylating discharge (I) or (II), d) the reaction of separated 5-formyl valeronitrile with ammonia and hydrogen in the presence of hydrogenating catalysts, selected from the group consisting of rhenium, copper and its compounds as well as metals and metallic compounds of the eighth group, obtaining a hydrogenation discharge, and e) obtaining 6-aminocapronitrile and if necessary hexamethylene diamine.

    57.
    发明专利
    未知

    公开(公告)号:ID17636A

    公开(公告)日:1998-01-15

    申请号:ID972700

    申请日:1997-08-04

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/03987 Sec. 371 Date Feb. 1, 1999 Sec. 102(e) Date Feb. 1, 1999 PCT Filed Jul. 23, 1997 PCT Pub. No. WO98/05631 PCT Pub. Date Feb. 12, 1998The invention concerns a process for the preparation of 6-aminocapronitrile or 6-aminocapronitrile-hexamethylene diamine mixtures by: a) reacting 5-formylvaleronitrile with ammonia and hydrogen in the presence of hydrogenation catalysts selected from the group consisting of metals or metal compounds rhenium, copper and elements of group VIII of the periodic table of elements, a hydrogenation discharge product being obtained; and b) extracting from the hydrogenation discharge product 6-aminocapronitrile and optionally hexamethylene diamine, provided that the hydrogenation catalyst does not contain copper, nickel or copper and nickel as it's only components.

    58.
    发明专利
    未知

    公开(公告)号:ES2097056T3

    公开(公告)日:1997-03-16

    申请号:ES94921615

    申请日:1994-06-20

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/01999 Sec. 371 Date Aug. 7, 1995 Sec. 102(e) Date Aug. 7, 1995 PCT Filed Jun. 20, 1994 PCT Pub. No. WO95/00525 PCT Pub. Date Jan. 5, 1995Phosphorus-containing calixarenes of the general formula I I and a process for their preparation are described. Additionally, a process for the preparation of aldehydes by the hydroformylation of C3-C20-olefins by means of rhodium or ruthenium carbonyl complexes, in which the phosphorus-containing calixarenes of the formula I are used as ligands, is described.

    SISTEMA CATALIZADOR Y PROCEDIMIENTO PARA EL CARBONILADO.

    公开(公告)号:ES2261484T3

    公开(公告)日:2006-11-16

    申请号:ES01978386

    申请日:2001-09-25

    Applicant: BASF AG

    Abstract: Sistema catalizador para el carbonilado de compuestos con insaturación olefínica o acetilénica con monóxido de carbono y un compuesto nucleófilo, que contiene (a) paladio; (b) una fosfina; y (c) una polietilenimina acilada disuelta de manera homogénea o al menos en distribución coloidal en la mezcla de reacción, que presenta unidades de la fórmula general (I) o isómeros ramificados de las mismas (Ver fórmula) en la que la suma de m+n asciende al menos a 10, y R, independientemente entre sí, significa hidrógeno, restos alquilo, cicloalquilo, arilo, aralquilo, acilo con hasta 30 átomos de carbono o restos hidroxialquil(poli)oxialquileno con hasta 500 unidades alquilenoxi, presentando la polietilenimina (I) los siguientes elementos estructurales (II) o isómeros ramificados de los mismos (Ver fórmulas) en las que R¿ significa, independientemente entre sí, alquilo con 1 a 29 átomos de carbono, y cuyo grado de amidación asciende a un 1 hasta casi un 100%, referido a los grupos amino amidables.

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