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公开(公告)号:ES2140963T3
公开(公告)日:2000-03-01
申请号:ES97905112
申请日:1997-02-27
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , WALTER MARC , SCHWAB EKKEHARD , MULLER HANS-JOACHIM , KONS GERMAIN , DILLING STEPHAN
IPC: B01J23/755 , C10G45/36 , C10G67/02
Abstract: PCT No. PCT/EP97/00960 Sec. 371 Date Sep. 3, 1998 Sec. 102(e) Date Sep. 3, 1998 PCT Filed Feb. 27, 1997 PCT Pub. No. WO97/32944 PCT Pub. Date Sep. 12, 1997In the process for the selective hydrogenation of dienes in diene-containing feed streams, a diene-containing feed stream is hydrogenated over a nickel-containing precipitated catalyst at from 40 to 100 DEG C., a pressure of from 3 to 20 bar and a WHSV (weight hourly space velocity) of from 1 to 10 kg/(lxh) in the presence of free hydrogen.
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公开(公告)号:BR9709564A
公开(公告)日:1999-08-10
申请号:BR9709564
申请日:1997-06-10
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , SCHWAB EKKHARD , WALTER MARC , MASSEN SIEGMAR
Abstract: Low-sulfur aliphatic compounds are obtained from olefin-rich starting materials contaminated with organic sulfur compounds.
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公开(公告)号:DE59407191D1
公开(公告)日:1998-12-03
申请号:DE59407191
申请日:1994-11-21
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , POLANEK PETER
IPC: C07C2/10 , C07C11/02 , C08F4/26 , B01J23/78 , C08F4/64 , C08F4/70 , C08F4/80 , C08F10/00 , C10G50/00
Abstract: PCT No. PCT/EP94/03838 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 21, 1994 PCT Pub. No. WO95/14647 PCT Pub. Date Jun. 1, 1995Straight-chain C2-C6-olefins are oligomerized to their dimers, trimers and tetramers by means of a fixed-bed catalyst, at superatmospheric pressure and at room temperature or elevated temperatures, by a process in which the catalyst used is one which contains, as active components, after deduction of the loss on ignition following heating at 900 DEG C., from 10 to 70% by weight of nickel oxide, calculated as NiO, from 5 to 30% by weight of titanium dioxide or zirconium dioxide, from 0 to 20% by weight of alumina, from 20 to 40% by weight of silica and from 0.01 to 1% by weight of an alkali metal oxide, with the proviso that the contents of the individual components in the catalyst sum to 100% by weight.
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公开(公告)号:AU696503B2
公开(公告)日:1998-09-10
申请号:AU4386696
申请日:1995-12-16
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , FLICK KLEMENS , MELDER JOHANN-PETER , SCHNURR WERNER , WULFF-DOERING JOACHIM
IPC: B01J25/00 , B01J25/02 , B01J37/00 , C07B31/00 , C07C253/30
Abstract: A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.
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公开(公告)号:PL321062A1
公开(公告)日:1997-11-24
申请号:PL32106295
申请日:1995-12-16
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , FLICK KLEMENS , MELDER JOHANN-PETER , SCHNURR WERNER , WULFF-DOERING JOACHIM
IPC: B01J25/00 , B01J25/02 , B01J37/00 , C07B31/00 , C07C253/30
Abstract: A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.
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公开(公告)号:NO972998A
公开(公告)日:1997-06-26
申请号:NO972998
申请日:1997-06-26
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , FLICK KLEMENS , MELDER JOHANN-PETER , SCHNURR WERNER , WULFF-DOERING JOACHIM
IPC: B01J25/00 , B01J25/02 , B01J37/00 , C07B31/00 , C07C253/30
CPC classification number: B01J37/0009 , B01J25/00 , B01J25/02 , B01J37/0018 , C07B31/00 , C07C253/30
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公开(公告)号:DE4446907A1
公开(公告)日:1996-07-04
申请号:DE4446907
申请日:1994-12-27
Applicant: BASF AG
Inventor: VICARI MAXIMILIAN , WULFF-DOERING JOACHIM , FLICK KLEMENS , SCHNURR WERNER , MELDER JOHANN-PETER
Abstract: The invention concerns the production of a hydrogenation catalyser based on an aluminium/transition metal alloy. The proposed method involves producing a kneadable material from the alloy and an auxiliary agent, moulding the kneadable material into moulded articles, calcinating these articles and then treating them with an alkali metal hydroxide, using (a) polyvinyl alcohol and water or (b) stearic acid as the auxiliary agent. The invention also concerns methods of hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha , omega -dinitriles to alpha , omega -aminonitriles; and the use of the catalysers thus produced for hydrogenation and hydrogenolysis.
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公开(公告)号:CA2208720A1
公开(公告)日:1996-07-04
申请号:CA2208720
申请日:1995-12-16
Applicant: BASF AG
Inventor: WULFF-DOERING JOACHIM , FLICK KLEMENS , VICARI MAXIMILIAN , MELDER JOHANN-PETER , SCHNURR WERNER
IPC: B01J25/00 , B01J25/02 , B01J37/00 , C07B31/00 , C07C253/30 , C07C255/24
Abstract: The invention concerns the production of a hydrogenation catalyser based on an aluminium/transition metal alloy. The proposed method involves producing a kneadable material from the alloy and an auxiliary agent, moulding the kneadable material into moulded articles, calcinating these articles and then treating them with an alkali metal hydroxide, using (a) polyvinyl alcohol and water or (b) stearic acid as the auxiliary agent. The invention also concerns methods of hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic .alpha.,.omega.-dinitriles to .alpha.,.omega.aminonitriles; and the use of the catalysers thus produced for hydrogenation and hydrogenolysis.
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公开(公告)号:NO327885B1
公开(公告)日:2009-10-12
申请号:NO20020349
申请日:2002-01-23
Applicant: BASF AG
Inventor: AUER HEINZ , DAHLHAUS JUERGEN , FISCHER KARL , HAMMER HANS , KELLENBENZ JOCHEN , SCHULZ MICHAEL , THIEL JOACHIM , VICARI MAXIMILIAN
IPC: B01D3/00 , B01J3/00 , C07C67/36 , B01J3/02 , B01J19/00 , C07B61/00 , C07C29/80 , C07C31/04 , C07C69/06
Abstract: A description is given of a process for preparing methyl formate by reacting excess methanol with carbon monoxide under superatmospheric pressure and at elevated temperature in the presence of alkali metal methoxide or alkaline earth metal methoxide as catalyst in a pressure-rated reactor, in which the use of at least two reactor elements, preferably operated in countercurrent, at about 100° C. and a pressure of about 100 bar in combination with a solids-free desalting of the reaction product makes possible very economical, largely trouble-free production of methyl formate in any desired quality and with a very good production capacity. Furthermore, the process for solids-free desalting and apparatuses for carrying out this process are described.
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公开(公告)号:NO327827B1
公开(公告)日:2009-10-05
申请号:NO20023514
申请日:2002-07-23
Applicant: BASF AG
Inventor: AUER HEINZ , HAMMER HANS , BESSLING BERND , HASSE HANS , SAUER FRIEDRICH , ADRIAN TILL , VICARI MAXIMILIAN
Abstract: The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid, in which firstly aqueous formic acid is produced by hydrolysis of methyl formate, with the methanol content in the methyl formate having been reduced in advance. The process according to the invention has the special feature that-before the hydrolysis of the methyl formate-the methanol content of the methanol-containing methyl formate is reduced in a distillation column, this distillation column simultaneously being employed for other separation functions during work-up of the formic acid.
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