公开(公告)号：EP3487845A1

公开(公告)日：2019-05-29

申请号：EP17740755.8

申请日：2017-07-19

Applicant: BASF SE

Inventor： TELES, Joaquim Henrique ,  KRAMP, Marvin ,  MUELLER, Christian ,  WOERZ, Nicolai Tonio ,  METZEN, Bernd ,  KELLER, Tobias ,  RIEDEL, Dominic ,  WEBER, Markus ,  URBANCZYK, Daniel ,  PARVULESCU, Andrei-Nicolae ,  WEGERLE, Ulrike ,  MUELLER, Ulrich

IPC: C07D301/32 ,  C07D303/02

Abstract: Disclosed herein is a process for purifying propylene oxide, including the steps of: (i) providing a stream S0 containing propylene oxide, acetonitrile, water, and an organic compound containing a carbonyl group —C(═O)—; and (ii) separating propylene oxide from the stream S0 by subjecting the stream S0 to distillation conditions in a distillation column to obtain a gaseous top stream S1c which is enriched in propylene oxide compared to the stream S0, a liquid bottoms stream S1a which is enriched in acetonitrile and water compared to the stream S0, and a side stream S1b containing propylene oxide which is enriched in the carbonyl compound compared to the stream S0.

公开(公告)号：EP3487844A1

公开(公告)日：2019-05-29

申请号：EP17748672.7

申请日：2017-07-19

Applicant: BASF SE ,  Dow Global Technologies, LLC

Inventor： TELES, Joaquim Henrique ,  KRAMP, Marvin ,  MUELLER, Christian ,  WOERZ, Nicolai Tonio ,  METZEN, Bernd ,  KELLER, Tobias ,  RIEDEL, Dominic ,  SCHELLING, Heiner ,  WEBER, Markus ,  URBANCZYK, Daniel ,  PARVULESCU, Andrei-Nicolae ,  WEGERLE, Ulrike ,  MUELLER, Ulrich ,  WEIDENBACH, Meinolf ,  WITZL, Werner ,  LUECKE, Karsten

IPC: C07D301/12 ,  B01D3/00 ,  B01J29/89 ,  C07D303/04

Abstract: The present invention is related to a process for preparing propylene oxide, comprising (i) providing a stream comprising propene, hydrogen peroxide or a source of hydrogen peroxide, water, and an organic solvent; (ii) passing the liquid feed stream provided in (i) into an epoxidation zone comprising an epoxidation catalyst comprising a titanium zeolite, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propene, propylene oxide, water, and the organic solvent; (iii) removing an effluent stream from the epoxidation zone, the effluent stream comprising propylene oxide, water, organic solvent, and propene; (iv) separating propene from the effluent stream by distillation, comprising (iv.1) subjecting the effluent stream to distillation conditions in a distillation unit, obtaining a gaseous top stream S0 enriched in propene compared to the effluent stream subjected to distillation conditions, and a liquid bottoms stream S01 enriched in propylene oxide, water and organic solvent compared to the effluent stream subjected to distillation conditions; (iv.2) returning a condensed portion of the stream S0 to an upper part of the distillation unit.

公开(公告)号：EP2945923B1

公开(公告)日：2017-03-15

申请号：EP14700646.4

申请日：2014-01-15

Applicant: BASF SE

Inventor： JOSCH, Jan Pablo ,  WECK, Alexander ,  GIESA, Sonja ,  BÜTEHORN, Steffen ,  BALEGEDDE RAMACHANDRAN, Ragavendra Prasad ,  BENFER, Regina ,  WEBER, Markus

IPC: C07C5/48 ,  C07C7/00 ,  C07C7/08 ,  C07C7/11 ,  C07C7/05 ,  C07C11/167

CPC classification number: C07C5/48 ,  C07C7/005 ,  C07C7/05 ,  C07C7/08 ,  C07C7/11 ,  C07C2523/887 ,  C07C11/167

公开(公告)号：EP3024581A1

公开(公告)日：2016-06-01

申请号：EP14741571.5

申请日：2014-07-16

Applicant: BASF SE ,  Dow Global Technologies LLC

Inventor： PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  TELES, Joaquim Henrique ,  SEELIG, Bianca ,  KAMPE, Philip ,  WEBER, Markus ,  RESCH, Peter ,  BARTOSCH, Christian ,  RIEDEL, Dominic ,  URBANCZYK, Daniel ,  SCHRÖDER, Alexander ,  WEGERLE, Ulrike

IPC: B01J29/90 ,  B01J29/89 ,  B01J37/06 ,  C07D301/12 ,  C07D303/04 ,  B01J38/48 ,  B01J37/10 ,  B01J29/70 ,  B01J35/00 ,  B01J37/00 ,  B01J37/02

CPC classification number: B01J29/90 ,  B01J29/7088 ,  B01J29/89 ,  B01J35/00 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  B01J37/30 ,  B01J38/02 ,  B01J38/06 ,  B01J38/48 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/42 ,  C07D301/12 ,  C07D303/04 ,  Y02P20/584

Abstract: The present invention relates to a process for the regeneration of a catalyst comprising a titanium-containing zeolite, said catalyst having been used in a process for the preparation of an olefin oxide and having phosphate deposited thereon, said process for the regeneration comprising the steps: (a) separating the reaction mixture from the catalyst, (b) washing the catalyst obtained from (a) with liquid aqueous system; (c) optionally drying the catalyst obtained from (b) in a gas stream comprising an inert gas at a temperature of less than 300° C.; (d) calcining the catalyst obtained from (c) in a gas stream comprising oxygen at a temperature of at least 300° C.

公开(公告)号：EP2991970A1

公开(公告)日：2016-03-09

申请号：EP14719778.4

申请日：2014-04-28

Applicant: BASF SE ,  Dow Global Technologies LLC

Inventor： TELES, Joaquim Henrique ,  RIEDEL, Dominic ,  SEELIG, Bianca ,  KAMPE, Philip ,  URBANCZYK, Daniel ,  WEBER, Markus ,  SCHRÖDER, Alexander ,  PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  WEIDENBACH, Meinolf ,  WITZL, Werner ,  BÄR, Holger

IPC: C07D301/12

CPC classification number: C07D301/12 ,  B01D3/143 ,  C07D301/32

Abstract: A continuous process for the preparation of propylene oxide, comprising(a) reacting propene, optionally admixed with propane, with hydrogen peroxide in a reaction apparatus in the presence of acetonitrile as solvent, obtaining a stream S0 containing propylene oxide, acetonitrile, water, at least one further component B, optionally propene and optionally propane, wherein the normal boiling point of the at least one component B is higher than the normal boiling point of acetonitrile and wherein the decadic logarithm of the octanol-water partition coefficient (log K
ow ) of the at least one component B is greater than zero; (b) separating propylene oxidefrom S0, obtaining a stream S1 containing acetonitrile, water and the at least one further component B; (c) dividing S1 into two streams S2 and S3;(d) subjecting S3 to a vapor-liquid fractionation in a fractionation unit, obtaining a vapor fraction stream S4 being depleted of the at least one component B; (e) recycling at least a portion of S4, optionally after work-up, to (a).

Abstract translation: 一种用于制备环氧丙烷的连续方法，包括（a）在乙腈作为溶剂的存在下，在反应装置中将丙烯任选与丙烷一起与过氧化氢反应，得到含有环氧丙烷，乙腈，水的流S0 至少一种另外的组分B，任选的丙烯和任选的丙烷，其中至少一种组分B的标准沸点高于乙腈的标准沸点，其中辛醇 - 水分配系数（log Kow）的十进制对数 所述至少一个组分B大于零; （b）从S0分离环氧丙烷，得到含有乙腈，水和至少一种其它组分B的料流S1; （c）将S1划分成两个流S2和S3; （d）使S3在分馏装置中进行汽 - 液分馏，得到耗尽至少一种B成分的蒸汽馏分流S4; （e）将至少一部分S4，任选地在后处理之后再循环至（a）。

公开(公告)号：EP2496348B1

公开(公告)日：2016-01-06

申请号：EP10771128.5

申请日：2010-10-28

Applicant: BASF SE

Inventor： STEINER, Jochen ,  BAY, Kerem ,  WERNER, Vera ,  AMANN, Jürgen ,  BUNZEL, Stefan ,  MOßBACHER, Claudia ,  MÜLLER, Joachim ,  SCHWAB, Ekkehard ,  WEBER, Markus

IPC: B01J23/889 ,  B01J23/00 ,  B01J37/08 ,  C07C1/04

CPC classification number: B01J23/8892 ,  B01J23/002 ,  B01J23/005 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/086 ,  B01J37/14 ,  B01J37/18 ,  B01J2523/00 ,  C10G2/332 ,  C10G2400/20 ,  B01J2523/72 ,  B01J2523/842

公开(公告)号：EP2681178A1

公开(公告)日：2014-01-08

申请号：EP12706605.8

申请日：2012-03-02

Applicant: BASF SE

Inventor： KOSTOVA, Albena ,  BENFER, Regina ,  GÖTZ, Jochen ,  REZAI, Alireza ,  MORILLO, Aristides ,  OLBERT, Gerhard ,  PFAB, Peter ,  KOLIOS, Grigorios ,  WEBER, Markus ,  WECK, Alexander

IPC: C07C7/04 ,  C07C7/08 ,  C07C7/11 ,  C07C11/08 ,  C07C11/167 ,  C07C9/10

CPC classification number: B01D3/40 ,  C07C7/04 ,  C07C7/08 ,  C07C7/11 ,  C07C11/16 ,  C07C11/167

Abstract: The invention relates to a process for workup of a stream (1) comprising butene and/or butadiene, butane, hydrogen and/or nitrogen and carbon dioxide, comprising the following steps: (a) absorption of the stream (1) comprising butene and/or butadiene, butane, hydrogen and/or nitrogen, with or without carbon dioxide, with a mixture (5) comprising 80 to 97% by weight of N-methylpyrrolidone and 3 to 20% by weight of water to obtain a stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, and a stream (7) comprising hydrogen and/or nitrogen and butane, (b) extractive distillation of the stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, with a stream (13) comprising 80 to 97% by weight of N-methylpyrrolidone and 3 to 20% by weight of water to separate the stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, into a stream (17) comprising N-methylpyrrolidone, water, butene and/or butadiene, and a stream (15) comprising essentially butane, with or without carbon dioxide, (c) distillation of the stream (17) comprising N-methylpyrrolidone, water, butene and/or butadiene into a stream (23) comprising essentially N-methylpyrrolidone and water, and a stream (21) comprising butene and/or butadiene.

Abstract translation: 本发明涉及包含丁烯和/或丁二烯，丁烷，氢气和/或氮气和二氧化碳的物流（1）的处理方法，其包括以下步骤：（a）将包含丁烯和 （5）包含80-97重量％的N-甲基吡咯烷酮和3-20重量％的水以获得流（9），所述混合物（5）包含具有或不具有二氧化碳的丁二烯，丁烷，氢和/ ）包含N-甲基吡咯烷酮，水，丁烯和/或丁二烯和丁烷（含有或不含二氧化碳）以及包含氢和/或氮和丁烷的物流（7），（b）物流（9）的萃取蒸馏包含 （13）包含80-97重量％的N-甲基吡咯烷酮和3-20重量％的水以分离含有或不含二氧化碳的N-甲基吡咯烷酮，水，丁烯和/或丁二烯和丁烷， 包含N-甲基吡咯烷酮，水，丁烯和/或丁二烯和丁烷的物流（9），有或没有汽车 （17），包含N-甲基吡咯烷酮，水，丁烯和/或丁二烯，以及基本上包含丁烷的物流（15），其中含有或不含有二氧化碳，（c）蒸馏包含N （23）和包含丁烯和/或丁二烯的物流（21），所述物流（23）基本上包含N-甲基吡咯烷酮和水。