公开(公告)号：JPS61252219A

公开(公告)日：1986-11-10

申请号：JP9409385

申请日：1985-05-01

Applicant: KAO CORP

Inventor： MORII MASAYOSHI ,  MAMADA AKIRA

IPC: C08G18/00 ,  C08G18/18

Abstract: PURPOSE:A catalyst for producing polyurethane which is odorless and has a moderate activity and excellent skin formability, comprising a dimethylethanolamine/ethylene oxide adduct. CONSTITUTION:The compound of the formula (wherein n is 3-4) is used as a catalyst for producing polyurethane. The amount of the catalyst used is preferably in the range of about 0.01-4pts.wt. per 100pts.wt. polyol used in the production of polyurethane. This catalyst may be used in combination with triethylenediamine or an organotin compound which is usually used in the production of polyurethane. The compound of the formula can be easily produced by an addition reaction between 1mol of dimethylethanolamine and 2-3mol of ethylene oxide.

公开(公告)号：JP2002179756A

公开(公告)日：2002-06-26

申请号：JP2000378779

申请日：2000-12-13

Applicant: KAO CORP

Inventor： ISHIKAWA ATSUSHI ,  SAKAI MITSURU ,  MORII MASAYOSHI

IPC: C08G18/18 ,  C08G18/00 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a low density polyurethane foam of 20 kg/m3 or lower density, having good adhesion with an adherend without shrinking of the foam or formation of voids inside for a formulation using abundant water as a foaming agent, capable of producing the polyurethane foam in good conditions of working environment reducing bad smell due to a catalyst for producing polyurethane. SOLUTION: This method for producing a polyurethane foam having 20 kg/m3 or lower density comprises reacting a polyol component with an isocyanate component in the presence of a catalyst for producing polyurethane, a foaming agent and a foam stabilizer, wherein the catalyst comprises a tertiary amine expressed by the formula (I) (where n is an integer of 2 to 4) and an imidazole compound expressed by the formula (II) (where R1 represents a C1-6 linear or branched alkyl group or a C1-6 linear or branched hydroxyalkyl group; and R2 represents a hydrogen atom, a C1-6 linear or branched alkyl group or a C1-6 linear or branched hydroxyalkyl group).

公开(公告)号：JP2001247643A

公开(公告)日：2001-09-11

申请号：JP2000062614

申请日：2000-03-07

Applicant: KAO CORP

Inventor： ISHIKAWA ATSUSHI ,  SAKAI MITSURU ,  MORII MASAYOSHI

IPC: C08G18/20 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an odorless polyurethane foam which keeps the inherent properties of an N-substituted imidazole and is reduced in an offensive odor based on the N-substituted imidabzoles, allowing a good producing environment. SOLUTION: The method for producing an odorless polyurethane foam comprises a reaction of the polyol component with the isocyanate component in the presence of a low-odored catalyst and a foaming agent, wherein said catalyst comprises an imidazole compound represented by the formula (I) (Wherein R1 is a 1-4C alkyl group, R2 is hydrogen or methyl, and n is 1 or 2).

公开(公告)号：JP2001172351A

公开(公告)日：2001-06-26

申请号：JP35982099

申请日：1999-12-17

Applicant: KAO CORP

Inventor： ISHIKAWA ATSUSHI ,  SAKAI MITSURU ,  MORII MASAYOSHI

IPC: C09K3/10 ,  C08G18/18 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To produce a catalyst for producing a polyurethane of a low odor, and to provide a process for producing a polyurethane excellent in vinyl stain resistance, fogging resistance and heat resistance by using the catalyst for producing the polyurethane. SOLUTION: There are provided a catalyst for producing a polyurethane comprising a dialkylaminoalkyl alcohol represented by formula (I): R1R2N-(CH2)n- OH (I) (wherein R1 and R2 are each independently a 1-4C alkyl group; and (n) is an integer of 9-12), and a process for producing a polyurethane comprising reacting a polyol component with an isocyanate component in the presence of the catalyst for producing a polyurethane.

公开(公告)号：JP2001048947A

公开(公告)日：2001-02-20

申请号：JP22568599

申请日：1999-08-09

Applicant: KAO CORP

Inventor： ISHIKAWA ATSUSHI ,  SAKAI MITSURU ,  MORII MASAYOSHI

IPC: C08G18/18 ,  C08G18/00 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing the subject thermal insulation material, favorable in foam fluidity during molding process, excellent in demoldability after the molding process, and capable of giving the polyurethane foam with high compressive strength and thermal conductivity retention. SOLUTION: This method for producing the objective polyurethane foam as thermal insulation material comprises reaction between a polyol component and an isocyanate component in the presence of (A) a catalyst comprising a quaternary ammonium salt and at least one compound selected from N,N,N',N'- tetramethyl-1,6-hexanediamine, N,N-dimethylcyclohexylamine and N-(2- dimethylaminoethyl)-N'-methylpiperazine, (B) a foaming agent composed of water and cyclopentane and (C) a foam stabilizer.

公开(公告)号：JP2999314B2

公开(公告)日：2000-01-17

申请号：JP31248591

申请日：1991-11-27

Applicant: KAO CORP

Inventor： ISAYAMA YASUTOSHI ,  FUKUSHIMA TETSURO ,  KITAGAWA HIROSHI ,  MORII MASAYOSHI ,  HARADA SHOICHIRO

IPC: C08G18/28 ,  C08G18/30 ,  C08G18/32 ,  C08G18/50 ,  C08G101/00 ,  C08J9/02 ,  C08L75/04

公开(公告)号：JP2994823B2

公开(公告)日：1999-12-27

申请号：JP31248391

申请日：1991-11-27

Applicant: KAO CORP

Inventor： ISAYAMA YASUTOSHI ,  FUKUSHIMA TETSURO ,  KITAGAWA HIROSHI ,  MORII MASAYOSHI ,  HARADA SHOICHIRO

IPC: C08G18/28 ,  C08G18/00 ,  C08G18/30 ,  C08G18/32 ,  C08G18/50 ,  C08G18/64 ,  C08G18/65 ,  C08G18/66 ,  C08G101/00 ,  C08J9/02 ,  C08L75/04

公开(公告)号：JPH10182818A

公开(公告)日：1998-07-07

申请号：JP34811596

申请日：1996-12-26

Applicant: KAO CORP

Inventor： OKUBO MAKOTO ,  NOMURA TAKAYUKI ,  MORII MASAYOSHI ,  ITOI AKITO

IPC: C08G65/34 ,  C08G73/00

Abstract: PROBLEM TO BE SOLVED: To obtain a cross-linked resin excellent in properties such as strengths and stability against various solvents by cross-linking a polymer having tert. amino groups in the molecular skeleton and having hydroxyl groups at both molecular terminals with a hydrocarbon having an anionic leaving group in the molecule. SOLUTION: A polymer of a compound represented by formula I (wherein R1 is a 1-24C alkyl or an aralkyl; m is 3-50 on the weight average; R2 is a 2-20C alkylene, an alicyclic alkylene, an aralkylene or the like) is cross-linked with a compound represented by the formula: R3 (-X)n (wherein R3 is an n-valent hydrocarbon group; X is an anionic leaving group; and n is an integer of 2 or greater) (e.g. 1,6-dibromohexane). The tert. alcohol is obtained by for example reacting a dihydric alcohol with a prim. amine. The dihydric alcohol is exemplified by 1,3-butanediol, and the prim. amine is exemplified by methylamine.

公开(公告)号：JPH08302383A

公开(公告)日：1996-11-19

申请号：JP13605695

申请日：1995-05-09

Applicant: KAO CORP

Inventor： ISHIDA HIROHIKO ,  MORII MASAYOSHI

IPC: A61L9/01 ,  C08G18/18 ,  C11B9/00

Abstract: PURPOSE: To obtain a perfume compsn. which reduces the irritating odor of a tert. amine compd. esp. the irritating odor of a tert. amine compd. used as an amine catalyst for producing a polyurethane, without detriment to the catalyst activity of the compd. CONSTITUTION: This perfume compsn. contains a 6-16C aliph. aldehyde perfume compd. and/or an ester perfume compd. wherein the number of hydrogen atoms bonded to two carbon atoms directly bonded to both sides of the ester group is 3 or lower.

公开(公告)号：JPH0625371A

公开(公告)日：1994-02-01

申请号：JP15939092

申请日：1992-06-18

Applicant: KAO CORP

Inventor： HARADA SHOICHIRO ,  FUKUSHIMA TETSURO ,  KITAGAWA HIROSHI ,  MORII MASAYOSHI ,  ISAYAMA YASUTOSHI

IPC: C08J9/14 ,  C08G18/28 ,  C08G18/32 ,  C08G18/64 ,  C08G101/00

Abstract: PURPOSE:To obtain a polyurethane foam having excellent packing properties, heat insulating properties and low-temperature dimensional stability by using a specific polyol component and a fluorocarbon substitute as a blowing agent without utilizing a catalyst having strong irritating odor such as tertiary amine. CONSTITUTION:(A) A polyisocyanate compound, (B) a polyol component at least partially composed of a tertiary amino alcohol of the formula (R1 is 3-4C straight-chain alkylene, arylene, etc.; R2 is 1-9C straight-chain alkylene ; R3 and R4 are 1-4C straight-chain alkyl; (n) is average degree of polymerization and is 2-50) and (C) a blowing agent selected from chlorodifluoromethane, 1,1,1- trichlorodifluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,2,2,2-pentafluoroethane and 1,1-difluoroethane are used to give the objective product. The compound of the formula is preferably obtained by reacting a diol such as 1,3-butanediol with a primary amine such as methylamine in the presence of a catalyst consisting essentially of copper-noble metal.